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NANOTECHNOLOGY
IN BUILDING CONSTRUCTION MATERIAL




           By: GAURAV JAIN
           B-TECH (Final yr.)
CONTENTS

•   Introduction
•   What nanotechnology is?
•   Introduction to Nanomaterials
•   Application of Nanotechnology
•   Barriers
•   Conclusion
INTRODUCTION

• We are very familiar with the concept of getting raw materials,
  bringing them together in an organized way and then putting them
  together into a recognizable form.
• This is our role in society and we have performed it well for hundreds
  or thousands of years. So we can say construction is definitely not a
  new science or technology and yet it has undergone great changes
  over its history.
• In the same vein, nanotechnology is not a new science and it is not a
  new technology either. It is rather an extension of the sciences and
  technologies that have already been in development for many years
What is Nanotechnology ?

• Nanotechnology is the use of very small pieces of material by
  themselves or their manipulation to create new large scale
  materials.
• At the Nano-scale material properties are altered from that of larger
  scales.
• The Nano-scale is the size range from approximately 1nm to
  100nm.
• Nanotechnology is an enabling technology that allows us to develop
  materials with improved or totally new properties.
Introduction to Nano-materials


                    Nano-particles:-
                    • It is defined as a particle with at
                      least one dimension less than
                      200nm. Nano-particles made of
                      semiconducting material(Ex-
                      Silicon)
                    Nano-composites:-
                    • It is produced by adding Nano-
                      particle to bulk material in order to
                      improve its bulk properties
Carbon Nano-tubes:-
• They are the form of carbon that was
  first discovered in 1952 in Russia and
  then re-discovered in the 1990’s in
  Japan.
• They are cylindrical in shape with
  Nano-meter diameter.
• Production cost of Nano-tubes is
  high and the price ranges from 20€
  to 1000€ per gram depending on
  quality.
• Types of Nano-tubes:-
   Single-walled carbon Nano-tubes
Multi-walled carbon Nano-tubes
Titanium Dioxide (TiO2)

• Titanium dioxide is a widely used white pigment.
• It can also oxidize oxygen or organic materials, therefore, it is
  added to paints, cements, windows, tiles etc.
• As TiO2 is exposed to UV light, it becomes increasingly
  hydrophilic (attractive to water), thus it can be used for anti-
  fogging coatings or self cleaning windows.
Applications of
        Nano-technology

 Nanotechnology is widely used in construction material as:
• In Concrete
• In Steel
• In Wood
• In Glass
• In Coating
• In photovoltaic
Nanotechnology in
         concrete
Concrete:- It is a mixture of cement, sand
coarse aggregate and water, The mechanical
behavior of concrete material depends on the
phenomenon that occurs on a micro and Nano
scale.
Nanotechnology can modify the structure of
concrete material and finally improves in
properties of materials as-
• Bulk density
• Mechanical performance
• Volume stability
• Durability
• Sustainability of concrete
Nanotechnology in
         concrete
• Exploring and modifying these Nano
  scale pores can result in improved
  concrete
• These addition could compensate for
  its weakness in tension and result in
  concrete with greatly improved
  stress-strain behavior
• The addition of Nano scale silica fume
  operates at a Nano scale and can
  improve durability of concrete
  structures exposed to de-icing salts.
Nanotechnology in
           concrete
CNT in CONCRETE:-
• The addition of small amount (1%) of CNT improves the
  mechanical property of concrete
• Oxidized MWNTs shows the best improvements in both
  compressive(+25N/mm2) and flexural
  strength(+8N/mm2).

 Research into haematite (Fe2O3) nanoparticles added
  to concrete has shown that they also increase strength
  as well as offering the benefit of monitoring stress
  levels through the measurement of section electrical
  resistance.
Nanotechnology in
           Steel
Need of nanotechnology in steel:-

• Fatigue is a significant issue that can lead to
  the structural failure of steel subject to cyclic
  loading, such as in bridges or towers.

• Stress risers are responsible for initiating
  cracks from which fatigue failure results.

• Addition of copper nanoparticles reduces
  the surface unevenness of steel which then
  limits the number of stress risers
Nanotechnology in
           Steel
Temperature restriction:-
• Above 750 F, steel starts to loose
  its structural integrity, and at 1000
  F, steel loses 50 % of its strength
• Infusion of steel with Nano scale
  copper particles could maintain
  structural integrity up to 1000 F
• New infused steel allows ultra high
  strength, corrosion resistance and
  have good surface finish.
Nanotechnology in
               Steel
High strength steel cables:-

•   Current research into refinement of cementite
    phase of steel to a Nano size has produced
    stronger cables
•   A stronger cable material reduce the costs and
    period of construction, especially in bridges
•   Sustainability is also enhanced by the use of
    higher cable strength as this leads to a more
    efficient use of material
•   High rise structures require high strength joints
    and this leads to the need of high strength bolts.
Nanotechnology in
          Steel
Bolted connection:-
• The capacity of high strength bolts is realized
   generally through quenching and tempering           CONNECTIONS
• Vanadium and molybdenum nanoparticles
   delays the problems associated with high
   strength bolts and also improving the steel’s
   micro- structure
                                                     BOLTED
Welding connection:-
• The addition of nanoparticles of magnesium
  and calcium makes the HAZ(Heat Affected                     WELDED
  Zone) grains finer in plate steel and this leads
  to an increase in weld toughness.
Nanotechnology in
             Steel
There are two international product:-

• Sandvik Nanoflex has both the desirable qualities of a high Young’s
  Modulus and high strength and it is also resistant to corrosion due to
  the presence of very hard nanometer-sized particles in the steel
  matrix.

• MMFX2 steel, while having the mechanical properties of
  conventional steel, has a modified Nano-structure that makes it
  corrosion resistant and it is an alternative to conventional stainless
  steel, but at a lower cost.
Nanotechnology in
           Wood
• Wood is also composed of nanotubes
  or “Nano fibrils”; namely,
  lignocellulose (woody tissue)
  elements which are twice as strong as
  steel.
• Researchers have developed a highly
  water repellent coating based on the
  actions of the lotus leaf as a result of
  the incorporation of silica and alumina
  nanoparticles and hydrophobic
  polymers.
Nanotechnology in
             Glass
•   Most of the glass used on the exterior
    surface of buildings to control light and heat
    in order to control the building environment
    and contribute to sustainability.
•   Titanium dioxide (TiO2) is used as
    nanoparticle form to coat glazing since it
    has sterilizing and anti-fouling properties.




               conventional   self-cleaning
                   glass           glass
Self cleaning of Glass
Nanotechnology in
           Glass

• Glass incorporating this self cleaning
  technology is available on the market
  today.

• Fire-protective glass is another
  application of nanotechnology. This is
  achieved by using a layer sandwiched
  between glass panels (an interlayer)
  formed of fumed silica (SiO2)
  nanoparticles which turns into a rigid
  and opaque fire shield when heated.
Nanotechnology in
            Coatings
• Coating is an area of significant research
  in nanotechnology
• Nanotechnology is being applied to
  paints and insulating properties,
  produced by the addition of Nano-sized
  cells, pores and particles.
• The TiO2 will break down and
  disintegrate organic dirt through
  powerful catalytic reaction.
• This research opens up the intriguing
  possibility of putting roads to good
  environmental use.
Nanotechnology in
         Fire-Resistance

• This is achieved by the mixing of
  carbon nanotubes with the
  cementious material to fabricate
  fibre composites that can inherit
  some of the outstanding properties
• Polypropylene fibres are also being
  considered as a material for
  increasing fire resistance and this is a
  cheaper option than conventional
  insulation.
Nanotechnology in
         Photovoltaic
• Predominant photovoltaic
  material is silicon, but an
  emerging technology involves
  the use of dye-sensitized nano-
  TiO2.
• Large surface area of Nano
  TiO2 greatly increases
  photovoltaic efficiency.
• Also has potential for lower
  material and processing costs
  relative to conventional solar
  cells.
Barriers

   Regulatory, legal, political and ethical issues.
   Competition with established micro scale technologies.
   License of proof-of-concept Nano tools, and delivery
    system.
   Safety and toxicity.
   Implementation cost of plant.
Barriers cont…

                                1. FABRICATION
                                   2. HEALTH
                               3. ENVIRONMENT
                                    4. COST



• 1. FABRICATION
      Current efforts in the field of nanotechnology are focussed on the fabrication,
characterization and use of these materials on a Nano scale.
• 2. HEALTH
      Nanotechnology based construction products might be harmful to health. example, the
nanotubes might cause lung problems to the workers.
Barriers cont..

• 3. ENVIRONMENT
    The effect of various nanomaterials on the natural environment is hotly
debated in nanotechnology and environmental research.
    Moreover it will create a new category of Nano-waste which has to be 
extracted and treated.
• 4. COST
     The cost of most nanotechnology materials and equipment are relatively
high. In comparison to traditional method.

It’s a challenge for construction engineer to provide a facility to the general
public at a reasonable cost.
Real life Examples…


                      • Building made by using
                        self-cleaning concrete
                        (Church ‘‘Dives in
    
                        Misericordia”, Rome, Italy)

                      • TiO2 coating on roads for
                        pollution reduction
Real life Examples…

  Nano house , Australia:-
  University of Technology ,Sydney
  (UTS) have developed a model
  house that shows how new
  materials, products and processes
  that are emerging from
  nanotechnology research and
  development might be applied to
  our living environment.
CONCLUSION

• Present day we are in great search for alternate
  materials this can effectively be achieved through
  the emerging field of Nanotechnology.
• Nanotechnology is not exactly a new technology,
  rather it is an extrapolation of current ones to a
  new scale.
• The main limitation is the high costs of
  nanotechnology, also concerns with the
  environmental and health effects.
• There is wide scope of research for application of
  nanotechnology in the building industry and it
  shall help in conserving the material resources.
References

   Journals.iop.org
   Nanoarchitecture.net
   Nanoforum.org
   Wikipedia.org
references

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Nanotechnology in building construction materials

  • 1. NANOTECHNOLOGY IN BUILDING CONSTRUCTION MATERIAL By: GAURAV JAIN B-TECH (Final yr.)
  • 2. CONTENTS • Introduction • What nanotechnology is? • Introduction to Nanomaterials • Application of Nanotechnology • Barriers • Conclusion
  • 3. INTRODUCTION • We are very familiar with the concept of getting raw materials, bringing them together in an organized way and then putting them together into a recognizable form. • This is our role in society and we have performed it well for hundreds or thousands of years. So we can say construction is definitely not a new science or technology and yet it has undergone great changes over its history. • In the same vein, nanotechnology is not a new science and it is not a new technology either. It is rather an extension of the sciences and technologies that have already been in development for many years
  • 4. What is Nanotechnology ? • Nanotechnology is the use of very small pieces of material by themselves or their manipulation to create new large scale materials. • At the Nano-scale material properties are altered from that of larger scales. • The Nano-scale is the size range from approximately 1nm to 100nm. • Nanotechnology is an enabling technology that allows us to develop materials with improved or totally new properties.
  • 5. Introduction to Nano-materials Nano-particles:- • It is defined as a particle with at least one dimension less than 200nm. Nano-particles made of semiconducting material(Ex- Silicon) Nano-composites:- • It is produced by adding Nano- particle to bulk material in order to improve its bulk properties
  • 6. Carbon Nano-tubes:- • They are the form of carbon that was first discovered in 1952 in Russia and then re-discovered in the 1990’s in Japan. • They are cylindrical in shape with Nano-meter diameter. • Production cost of Nano-tubes is high and the price ranges from 20€ to 1000€ per gram depending on quality. • Types of Nano-tubes:- Single-walled carbon Nano-tubes Multi-walled carbon Nano-tubes
  • 7. Titanium Dioxide (TiO2) • Titanium dioxide is a widely used white pigment. • It can also oxidize oxygen or organic materials, therefore, it is added to paints, cements, windows, tiles etc. • As TiO2 is exposed to UV light, it becomes increasingly hydrophilic (attractive to water), thus it can be used for anti- fogging coatings or self cleaning windows.
  • 8. Applications of Nano-technology Nanotechnology is widely used in construction material as: • In Concrete • In Steel • In Wood • In Glass • In Coating • In photovoltaic
  • 9. Nanotechnology in concrete Concrete:- It is a mixture of cement, sand coarse aggregate and water, The mechanical behavior of concrete material depends on the phenomenon that occurs on a micro and Nano scale. Nanotechnology can modify the structure of concrete material and finally improves in properties of materials as- • Bulk density • Mechanical performance • Volume stability • Durability • Sustainability of concrete
  • 10. Nanotechnology in concrete • Exploring and modifying these Nano scale pores can result in improved concrete • These addition could compensate for its weakness in tension and result in concrete with greatly improved stress-strain behavior • The addition of Nano scale silica fume operates at a Nano scale and can improve durability of concrete structures exposed to de-icing salts.
  • 11. Nanotechnology in concrete CNT in CONCRETE:- • The addition of small amount (1%) of CNT improves the mechanical property of concrete • Oxidized MWNTs shows the best improvements in both compressive(+25N/mm2) and flexural strength(+8N/mm2).  Research into haematite (Fe2O3) nanoparticles added to concrete has shown that they also increase strength as well as offering the benefit of monitoring stress levels through the measurement of section electrical resistance.
  • 12. Nanotechnology in Steel Need of nanotechnology in steel:- • Fatigue is a significant issue that can lead to the structural failure of steel subject to cyclic loading, such as in bridges or towers. • Stress risers are responsible for initiating cracks from which fatigue failure results. • Addition of copper nanoparticles reduces the surface unevenness of steel which then limits the number of stress risers
  • 13. Nanotechnology in Steel Temperature restriction:- • Above 750 F, steel starts to loose its structural integrity, and at 1000 F, steel loses 50 % of its strength • Infusion of steel with Nano scale copper particles could maintain structural integrity up to 1000 F • New infused steel allows ultra high strength, corrosion resistance and have good surface finish.
  • 14. Nanotechnology in Steel High strength steel cables:- • Current research into refinement of cementite phase of steel to a Nano size has produced stronger cables • A stronger cable material reduce the costs and period of construction, especially in bridges • Sustainability is also enhanced by the use of higher cable strength as this leads to a more efficient use of material • High rise structures require high strength joints and this leads to the need of high strength bolts.
  • 15. Nanotechnology in Steel Bolted connection:- • The capacity of high strength bolts is realized generally through quenching and tempering CONNECTIONS • Vanadium and molybdenum nanoparticles delays the problems associated with high strength bolts and also improving the steel’s micro- structure BOLTED Welding connection:- • The addition of nanoparticles of magnesium and calcium makes the HAZ(Heat Affected WELDED Zone) grains finer in plate steel and this leads to an increase in weld toughness.
  • 16. Nanotechnology in Steel There are two international product:- • Sandvik Nanoflex has both the desirable qualities of a high Young’s Modulus and high strength and it is also resistant to corrosion due to the presence of very hard nanometer-sized particles in the steel matrix. • MMFX2 steel, while having the mechanical properties of conventional steel, has a modified Nano-structure that makes it corrosion resistant and it is an alternative to conventional stainless steel, but at a lower cost.
  • 17. Nanotechnology in Wood • Wood is also composed of nanotubes or “Nano fibrils”; namely, lignocellulose (woody tissue) elements which are twice as strong as steel. • Researchers have developed a highly water repellent coating based on the actions of the lotus leaf as a result of the incorporation of silica and alumina nanoparticles and hydrophobic polymers.
  • 18. Nanotechnology in Glass • Most of the glass used on the exterior surface of buildings to control light and heat in order to control the building environment and contribute to sustainability. • Titanium dioxide (TiO2) is used as nanoparticle form to coat glazing since it has sterilizing and anti-fouling properties. conventional self-cleaning glass glass
  • 20. Nanotechnology in Glass • Glass incorporating this self cleaning technology is available on the market today. • Fire-protective glass is another application of nanotechnology. This is achieved by using a layer sandwiched between glass panels (an interlayer) formed of fumed silica (SiO2) nanoparticles which turns into a rigid and opaque fire shield when heated.
  • 21. Nanotechnology in Coatings • Coating is an area of significant research in nanotechnology • Nanotechnology is being applied to paints and insulating properties, produced by the addition of Nano-sized cells, pores and particles. • The TiO2 will break down and disintegrate organic dirt through powerful catalytic reaction. • This research opens up the intriguing possibility of putting roads to good environmental use.
  • 22. Nanotechnology in Fire-Resistance • This is achieved by the mixing of carbon nanotubes with the cementious material to fabricate fibre composites that can inherit some of the outstanding properties • Polypropylene fibres are also being considered as a material for increasing fire resistance and this is a cheaper option than conventional insulation.
  • 23. Nanotechnology in Photovoltaic • Predominant photovoltaic material is silicon, but an emerging technology involves the use of dye-sensitized nano- TiO2. • Large surface area of Nano TiO2 greatly increases photovoltaic efficiency. • Also has potential for lower material and processing costs relative to conventional solar cells.
  • 24. Barriers  Regulatory, legal, political and ethical issues.  Competition with established micro scale technologies.  License of proof-of-concept Nano tools, and delivery system.  Safety and toxicity.  Implementation cost of plant.
  • 25. Barriers cont… 1. FABRICATION 2. HEALTH 3. ENVIRONMENT 4. COST • 1. FABRICATION       Current efforts in the field of nanotechnology are focussed on the fabrication, characterization and use of these materials on a Nano scale. • 2. HEALTH  Nanotechnology based construction products might be harmful to health. example, the nanotubes might cause lung problems to the workers.
  • 26. Barriers cont.. • 3. ENVIRONMENT The effect of various nanomaterials on the natural environment is hotly debated in nanotechnology and environmental research. Moreover it will create a new category of Nano-waste which has to be  extracted and treated. • 4. COST The cost of most nanotechnology materials and equipment are relatively high. In comparison to traditional method. It’s a challenge for construction engineer to provide a facility to the general public at a reasonable cost.
  • 27. Real life Examples… • Building made by using self-cleaning concrete (Church ‘‘Dives in   Misericordia”, Rome, Italy) • TiO2 coating on roads for pollution reduction
  • 28. Real life Examples… Nano house , Australia:- University of Technology ,Sydney (UTS) have developed a model house that shows how new materials, products and processes that are emerging from nanotechnology research and development might be applied to our living environment.
  • 29. CONCLUSION • Present day we are in great search for alternate materials this can effectively be achieved through the emerging field of Nanotechnology. • Nanotechnology is not exactly a new technology, rather it is an extrapolation of current ones to a new scale. • The main limitation is the high costs of nanotechnology, also concerns with the environmental and health effects. • There is wide scope of research for application of nanotechnology in the building industry and it shall help in conserving the material resources.
  • 30. References  Journals.iop.org  Nanoarchitecture.net  Nanoforum.org  Wikipedia.org