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All-Ceramics
&
Recent advances
contents
1.INTRODUCTION
2.EVOLUTION & HISTORY
3.METHODS TO STRENGTHEN PORCELAIN
4.ALLUMINOUS CORE PORCELAIN
5.IN-CERAM
6.CASTABLE CERAMICS
7.MACHINABLE CERAMICS
8.SCOPE OF ALL CERAMICS
9.CONCLUSION
10.REFERENCES
INTRODUCTION
DEFINITIONS
Ceramics : compounds of one or more metals with a non metallic element(usually
silicon,boron,oxygen) that may be used as a single structural component or as one of
the several layers that are used in the fabrication of a ceramic based prosthesis .
(G.P.T 7, Anusavice)
Porcelain : a ceramic material formed of infusible elements joined by lower fusing
materials.Most dental porcelains are glasses and are used in fabrication of teeth for
dentures, pontics & facings, crowns, inlays, onlays and other restorations. (G.P.T 7)
Ceramic is derived from Sanskrit word meaning Burnt earth
5
 Formulated to provide:
 Castability,
 Moldability,
 Injectability,
 Color, Opacity, Translucency,
 Machinability,
 Abrasion resistance,
 Strength,
 Toughness.
HISTORY
&
EVOLUTION OF
CERAMICS
Denture teeth
&
Dentures -Duchateau 1774
Ceramic paintings and Vases
1887 PJC – CH. Land (platinum foil technique)
1962 PFM – Weinstein
1965 McLean and Hughes aluminium core porcelain
1957 Vines and Sommelman – Vaccum firing
1940 with advent of acrylics PJC lost popularity.
Evolution of all ceramic restorations :
 1887 – CH. Land gave porcelain jacket crown
 1965 - McLean and hughes aluminous core porcelain
 1980 - in ceram-slip casting, castable ceramics
 Latest 1990’s - machinable ceramics(CADCAM)
10
CLASSIFICATION OF DENTAL
CERAMICS
1) USE/INDICATION: Anterior, Posterior, crowns,
veneers, post and cores, stain and glaze ceramic.
2) COMPOSITION: pure alumina, pure zirconia,
silica glass, leucite based glass, Lithia based
glass.
3) PROCESSING METHOD: sintering, partial
sintering, glass infiltration, CAD-CAM, copy
milling, condensation, heat pressing, casting, slip-
casting.
11
4) FIRING TEMPERATURE:
HIGH FUSING : 1300 C
MEDIUM FUSING : 1101-1300 C
LOW FUSING : 850-1100 C
ULTRA LOW FUSING: < 850 C
5) MICROSTRUCTURE: glass, crystalline, crystal-
containing glass
12
6) TRANSLUCENCY:
Opaque, Translucent, Transparent
7) FRACTURE RESISTANCE
8) ABRASIVENESS
13
 Three main divisions of ceramics:
1. Predominantly glassy materials,
2. Particle filled glasses---- Glass ceramics
3. Polycrystalline ceramics.
 Esthetic dental ceramics : Glassy
 Substructure dental ceramics: Crystalline
14
 Best mimic the optical properties of enamel and
dentine: Glassy material
 Glasses: 3D network of atoms having no regular
pattern to the spacing between nearest
atoms, thus they are amorphous or without form.
 Derived principally from a group of mined
minerals called FELDSPAR: based on silica and
alumina: Aluminosilicate glasses.
 Resistant to crystallization during firing, long
firing ranges, biocompatible.
15
 Filler particles are added to the base glass
composition to improve mechanical properties
and to control optical effects like
Opalescence, Color, Opacity.
 Fillers: Crystalline/Higher melting glass
 Leucite: first fillers to be used, crystalline mineral
 Feldspar forms crystalline mineral Leucite, when
mixed with metal oxides & fired to high
temperature
 Leucite is potassium-aluminum-silicate mineral
with large coefficient of thermal expansion.
16
 This filler was added to create porcelains that
could be successfully fired on metal susbstruct.
 Adding 17-25% Leucite filler to base glass
creates porcelains that are thermally compatible
with dental alloys.
- Index of refraction close to feldspar,
- “Selective etching”
 Moderate strength increases can also be
achieved with appropriate fillers added and
uniformly dispersed: “Dispersion Strengthening”
17
 Special subset of particle-filled glass
 The crystalline filler particles are grown inside
the glass object (pellet/prosthesis) by a special
heat treatment that causes the precipitation
within the glass.
 This crystal nucleation and crystal growth
process is called “Ceramming”.
 E.g. Dicor: crystalline mica: 55 vol%
 Empress 2: lithium disilicate : 70 vol%
18
 No glassy components, atoms are densely
packed, regular network: Crack propagation
difficult.
 Tougher and stronger than glassy ceramics.
 Difficult to process, CAD-CAM.
 Relatively opaque, core substructure.
 E.g. Aluminum oxide, partially stabilized Zirconia.
 Procera, Cercon, Lava.
COMPOSITION OF DENTAL
PORCELAINS:
Composition (Percentage) Use
- Feldspar 60-80% Basic glass
former
- Quartz 15-25% Filler
- Oxide 9-15% Fluxes
- Alumina 8-20% Glass former &
fluxes
-Metallic
pigments
1% Color matching
- Kaolin 3-5% Binder
High Fusing Porcelains:
Feldspar - 70-90%
Quartz - 11-18%
Kaolin - 1-10%
Medium Fusing Low Fusing
Silica dioxide 69.4% 64.2%
Boric oxide 7.5% 2.8%
Calcium oxide 1.9%
Potassium oxide 8.3% 8.2%
Aluminium oxide 4.8% 1.9%
Lithium oxide - 2.1%
Magnesium
oxide
0.5%
Medium & low fusing porcelain
Individual Components
Potash feldspar - K2O Al2O36SiO2
Soda feldspar - Na2O Al2O3 6 SiO2
Silica – SiO2
Crystalline quartz
Crystalline cristobalite
Crystalline tridymite
Non-crystalline fused silica- it acts as a
refractory skeleton provides strength and
hardness.
Glass modifiers: Boric oxide B2O3
Function:
•Lowers fusion temperature
•Increases flow of porcelain
•Removes impurities
•Help to produce dental porcelain with
different firing temperature
•Acts as a flux, by interrupting the
integrity of the silica network.
Kaolin:
•Acts as a binder
•Also imparts opacity
Alumina: Forms a network in conjunction with silica.
Alters softening viscosity.
Metallic Pigments: Pigment oxides
•Help to obtain various shades needed to stimulate natural
teeth.
Brown - Iron or nickel oxide
Green - Copper oxide
Yellow brown - Titanium oxide
Blue - Cobalt oxide
Pink - Chromium tin or chroma
•Opacity is achieved by addition of :-
Cerium oxide
Zirconium oxide
Titanium oxide
Tin oxide
24
 Excellent Flexural Strength,
- Glazed : 141.1 MPa - Unglazed: 75.8 MPa
 Compressive strength: 331 MPa
 Tensile strength: 34 MPa
 Shear strength: 110 MPa
 Modulus of elasticity: 69 GPa
 Surface hardness: 460 KHN
25
 Corrosion
Resistance,
 Chemical
corrosion.
26
 Less Reactivity ; Chemical Inertness
 Brittle Fracture, Low fracture toughness,
 Biocompatibility, Color Stability,
 Refractory Nature, High Hardness,
 Low Thermal Conductivity, Diffusibility and
Electrical Conductivity.
Advantages of porcelain
•High abrasion resistance
•Chemical inertness
•Excellent thermal and electrical insulators
•Excellent esthetic qualités
•Translucency
•Color stability
•Capacity of pigmentation
•Stain resistance
•Enhanced polishability
•High durable
Disadvantages of porcelain
•Highly brittle
•Excessive wear of opposing teeth
•High firing shrinkage
Methods used to overcome the deficiencies of
ceramics fall under 2 categories:-
•Methods of strengthening brittle materials
•Methods of designing components to minimize
stress concentration and tensile stress
METHODS
TO
STRENGTHEN
PORCELAIN
Griffiths Flaw Crack Growth
Sintering Process
Why are Ceramics weak ?
On moisture exposure crack growth is accelerated
1. Brittle – Covalent bonds
2. Inherent flaws
3. > # in moist environment
Methods of Strengthening:-
•Development of residual compressive stresses within the
surface of the material.
•Interruption of crack propagation.
•Minimizing tensile stresses
•Avoiding stress concentration
1) Development of residual stresses:
Strengthening is gained by virtue of fact that these residual
stresses must be first be negated by developing tensile
stresses before any net tensile stress develops.
. Principle:
Strengthening is gained by the fact that the residual
stresses must be first negated by the developing tensile
stress before any net tensile stress develops.
E.g. Normal tensile strength : + 60 MPa
Residual comp. stress : - 40 MPa
Total tensile stress to induce fracture: + 100 MP
Methods:
1) Ion-exchange: (Chemical Tempering)
Involves exchange of large potassium ions for the
smaller sodium ions.
•Sodium containing glass articles is placed in a bath of
molten potassium nitrate.
•The potassium ion is 35% larger than sodium ion.
•Squeezing of the potassium ions into the place of sodium
ions creates a large residual compressive stress
2.Thermal Tempering:-
Most common methods.
•Thermal tempering creates residual stresses by rapidly
cooling (quenching). The surface of object while it is hot
and in the softened (molten) state.
•This rapid cooling produces a skin of rigid glass
surrounding a soft (molten core).
•As molten core solidifies it tends to shrink, creates
residual tensile stresses within the outer surface.
Mismatch Coefficient of Thermal Expansion:-
•The metal and the porcelain used for the restoration are
designed with slight mismatch in their co-efficient of
thermal expansion.
•The coefficient of thermal expansion for metals is more
than porcelain thus the metal contacts more than the
porcelain on cooling provides additional strength.
Interruption of Crack Propagation:
Methods: Dispersion a crystalline phase
•Aluminous Porcelains (PJC): Alumina which is
a tough crystalline material is added to a glass
in the particulate form, the glass is toughened
as the cracks cannot penetrate the alumina
particles.
•Dicor Castable Glass Ceramics): Dicor utilizes
inhibition of crack prepagation by the growth of
mica crystals in the ceramic as a result of heat
treatment of the ceramic. Mica crystals in situ
interrupt crack propagation their by
strengthening the restoration.
.
Transformation Toughening:
•New technique of strengthening glasses. Strengthening
glasses involves the incorporation of crystalline material
that is capable of undergoing a change in crystal
structure when placed under stress.
•The crystalline material partially stabilized Zirconia.
The energy required for the transformation of is taken
from the energy that allows to crack to propagate
•Involves transformation of ZrO2 from a TETRAGONAL
phase to a MONOCLINIC phase at the tips of cracks that
are in the region of tensile stress.
36
 Designed in such a way to overcome weakness.
 To avoid exposure of the ceramic to high tensile
stresses.
 To avoid stress concentration at sharp angles.
 Minimizing Tensile Stresses:
 High tensile stresses
 Posterior segment of mouth
 Deep overbite in the anterior region
 A ductile metal coping prevents the formation of Tensile
stresses in the porcelain and prevents it failure.
Reducing Stress Raisers:
 Stress raisers are discontinuities in ceramic
structures and in the brittle materials that cause stress
concentration.
Methods of strengthening brittle materials
1.Ion exchange
2.Thermal tempering
3.Thermal compatiability
Minimise stress concentration
1. Reducing stress raisers
2. Minimise tensile stresses
Residual compressive
stresses
Interruption of crack
propagation
Addition of
dispersion phase
Change in crystalline
structure
Particle stabilized
zirconia
Toughness of
particle
Al, dicor
Processing procedure
2 Options
1. Strong Core ( Unaesthetic )
Layered with Veneering Porcelain
2. Esthetic as well as
strong Core
 Coping are prepared by
 Electrodeposition of metal on duplicate die
 Burnishing & heat treating metal foil on a die
 Cad – cam
 Casting pure metal by lost wax tecnique
 Bonding of metal to ceramic, the ceramic must
have :
 Fusion temp well above its sintering temp
 Co efficient of thermal contraction closely matched to
that of the alloys.
 Metal oxide on the metal is necessary for bonding
Porcelain condensation
 Careful cleaning metal frame work and thin layer of
opaque porcelain is applied and baked.
 Dentin porcelain powder in the shade selected for
body/dentine portion.
 Porcelain is supplied in powder & mixed with water and
condensed into desired.
 To achieve thorough condensation, 3 methods are used
 Mild vibration
 Cleaned excess water by tissue paper
 Use brush to add dry powder to absorb excess water.
Firing/ Sintering of porcelain
 Porcelain restoration are fired either by temperature
control alone or temperature or time control.
 Sintering is defined as a process of heating without
melting closely packed particles to form a cohert mass
by inter-particle bonding and sufficient diffusion to
decrease the surface area and increase the density of
the structure.
 The aim of glazing is to seal the open pores in the
surface of a fired porcelain. Dental glazes are composed
of colorless glass powder, applied to the fired crown
surface, so as to produce a glossy surface.
 Porcelain is cleaned and necessary stains applied.
 Glazing is short, when glazing temperature is reached,
on thin glassy film (glaze) is formed by viscous flow on
the porcelain surface.
 Fracture resistance of glazed porcelain is greater than
unglazed porcelain
Metal reinforced systems
CAPTEK SYSTEM : ( capillary casting technique)
Duplicated refractory die
Metal
impregnated
wax sheet
Final coping
Porcelain veneering
CAPTEK is the answer for the most challenging situation because of
its strength and excellent esthetics
Captek G-97.5 gold,
2.5 silver
Pt-pd
(HELIO FORM HF 600 SYSTEM)
Equipment Polyurethane dies
Completed restorations
ELECTRO FORMED
1965 Mc lean and Hughes
40 t0 50 wt% of Al2O3
Flexural strength 131 Mpa
Platinum foil technique
ALUMINOUS CORE PORCELAIN
Finished CoresMaster model
with dies Platinum foil
adapted to die
(Hi-Ceram)
Unsintered CrownsDentin Ceramic
additions
Finished Crowns on dies
Post-Cementation
Mc lean 1979 Five year failure rate 2% for anteriors 15% for posteriors
Large sintering shrinkage
Seiber et al 1981 :light reflection better than porcelain fused to metal
IN-CERAM
A process used to form green ceramic shape by applying a
slurry of ceramic particles and water or a special liquid to a porous
substrate Such as a die material, there by allowing capillary action
to remove water and densify the mass of deposited particles
Flexural
strength
350 MPa 500 MPa 700 MPa
In-ceram
Alumina
In-ceram
Spinell
In-ceram
Zirconia
Crack deflection is the main Phenomenon
( Slip casting technique )
Saadoun 1989
Al2O3 slip Glass infiltration
Vita Inceramat3
Giordono 1995 : Al2O3 Core glass infiltrated Ceramic > Strength than
Hi-Ceram, Di-Cor & Feldspathic Porcelain
Vaccumat 4000 Premium
Duplication
In-Ceram
refractory dies
In-Ceram
application
Al2O3 slip
10 hrs 1120 c- 2hrs
vita inceramat
Working model
Glass infiltration
4hrs 1100cShrinkage of dies
Application of body
and incisal porcelain
Postoperative veiw of
In-Ceram crowns
Finished In-Ceram
copings
(Air abraded)
Finished crowns
Preoperative veiw
Probster et al : Strength of In-Ceram > IPS Empress < PFM
CASTABLE CERAMICS
CASTABLE CERAMICS
A glass ceramic material that combines the properties of a
restorative material for function with the capability to be cast
using the lost wax process
 Di-Cor
 Cerestore
 IPS Empress
 New types
Cera pearl
Canasite glass ceramic
Optimal pressable ceramic
Olympus castable ceramics
Castable phosphate glass ceramic
1968 Mc Culloch
DI-COR
Non porous, homogenous, microstructure with uniform
crystal size which is derived from the controlled growth of crystals
within an amorphous matrix of glass.
Ancestry Fredrick carter corning glass works
Composition : SiO2, K2O and MgO, MgF2, Al2O3, ZrO2 and
flourescing agent – TETRA SILICIC FLUOROMICA GLASS
CERAMIC.
Mica crystals Feldspathic porcelain
Wax pattern
Spruing
Investing
Burnout
Divesting
Cast glass coping
Ceramming
1750 for 12hr
450 for 12 hr
Centrifugal casting
2600 f
Ceramming Ceramming oven Crystallised glass coping
Conventional porcelain application & Firing Finished crown
Cerramming done from room temparature- 1900 f for 1½ hrs and
sustained for 6hrs inorder to form tetra silicic flouro mica crystals
Properties :
Flexural strength 81 6.8 Mpa
Marginal adaptation :
Weaver et al 1988 – conducted a study on 10 dicor crowns
Marginal opening – 57 9 µm
Due to less seating pressure, increase in density of ceramic
after ceramming.
Biocompatibility :
Less bacterial counts
Reason : smooth surface, low surface tension, flouride content,
Low thermal conductivity
Esthetics :
Gross man and adiar : Hue and chroma of metal ceramics
and castable ceramics matched natural teeth.
Value of only castable ceramics matched natural teeth.
Presence of mica crystals scatter light similar to enamel rods.
Cementation :
zinc phosphate, light activated urethane resin
Bailey&Bennet 1988 etching with ammonium biflouride for 2 min
Survival rate :
Kenneth et al 1999 14yr study
Crowns 82%
Cores 100%
Inlay and onlay 90%
Partial coverage 92%
Posterior 70% anterior 82.7% Expenstein et al 2000
CERESTORE
(SHRINK FREE CERAMICS)
Chemistry :
Binder silicone SiO SiO2
Unfired cerestore core :
Al2O3
MgO
Glass frit
Silicone resin
Fillers
Al2O3 + MgO MgAl2O4 + Corrundum
Strength
160-1800C
Fired cerestore core :
- Al2O3 (Corundun)
MgAl2O4 (Spinel)
Ba Mg2Al3 (Si9Al2O30) – Barium
osumilite
TECHNIQUE :
Tooth preparation :
1.25 – 1.5 mm (Labial-lingual,interproximal)
1.5 – 2.mm (occlusal)
900 (full shoulder ) Conventional wax-up on
heat stable Epoxy dies
Investing Ceramic pellet in flask for pressing
160 c
Ceramic injected into mold
Plaster removal from
pressed coping
Refining green state
coping
Coping on master die fired
at 1300 c
Tooth preparation and impression
Cerestore epoxy die
Wax up and invest with master die
Boil out
Heat flask to 1800C
Transfer mould ceramic into lost wax
cavity directly on master die
Retrieve master die
Refine coping, add veneer porcelain
Properties :
• Flexural strength : 225 Mpa
• Fit : exceptional fit because of direct moulding process.
• Low thermal conductivity
• Radio density similar to enamel
• Biocompatible
IPS-EMPRESS
(PRESSABLE CERAMIC)
Hot pressed ceramics
Leucite reinforced
K2O – Al2O3 – 4 SiO2
Lithium Disilicate reinforced
SiO2 – LiO2 – P2O5 – ZrO2
2 types
IPS Empress IPS Empress 2
LEUCITE REINFORCED IPS EMPRESS
Feldspar Leucite + glass phase
In congruent
Melting
Resistance to crack propagation
Pre cerammed Ingots
Processing :
Wax pattern
Ceramic ingot &
Al plunger
Investing
Pressing under vaccum
11500C
Sprue removal
Edward B Goldin 2005 compared leucite IPS Empress with PFM
Mean marginal discrepancy 94 + 41 PFM
81 +25 IPS
Burn out 8500 C
26 min hold
Properties :
Flexural strength : 117.3 - 167 Mpa
Ion exchange method used to strengthen IPS empress (KnO3)
204 Mpa 11 hr immersion
Esthetics : high esthetic value
Clinical survival : Deniz G in 2002
95% survival 2-4 years
Marginal adaptation : Shearer et al in 1996 : better marginal adaptation
with hot pressed ceramics than aluminous core material.
LITHIUM DISILICATE REINFORCED
Base glass Melted with raw materials1400 to 16000C
Poured into water
Glass grains 20-30 microns Cylindrical ingots obtained
Pressed into mold at 9000Cin
Vaccum for 10 minute
Automatic molding cycle 200
to 300 N
Manufacturing :
Mainly for post and core purposes Flexural strength :164+26 Mpa
Cosmo glass Ceramic
Full contouring Cut back
Sprued pattern
Investing Ingot pressing
CERAPEARL
CaO – P2O5 – MgO – SiO2 – Hobo and Kyocera bioceram group 1985
Crystalline microstructure similar to natural enamel
Mechanical properties superior to enamel
Laboratory steps :
Tooth preparation, die preparation
Wax patterns
2 stage burn out (8000C final temperature)
Melted ceramic at 14600C casted under vaccum
(special ring liners required {1.2mm} )
Reheating -870 c – Crystalline oxy apatite - moisture exposure – hydroxy apatite
Clinical success : Nahara Y et al (1991)
2 year success rate – 100%
Burn out chamber Centrifugal casting machine
Ceramming unit and shading
A) Pretreatment
B) 3 months after
cementation
C) 2 yrs post-
cementation
Mainly indicated for inlays and full crowns
FLUORCANASITE
Multiple chain silicate glass ceramic that exhibits high strength
and fracture toughness.
Al2O3 – CaO – F – K2O – SiO2
CaF2 Nucleating agent
Procedure :
Wax pattern invested in Crystoballite investment
Burn out at 7000C Heat soak for 0.5 hours
Temperature drop to 5900C
Centrifugal casting machine used at 12000C
Direct ceramming Heat soaking
5200C
Heating at
8600C CANASITE
Properties :
Flexural strength : 116 12 MPa
Johnson et al in 2000 : Biaxial flexural strength 280.4 Mpa
Fracture toughness : 660 Mpa
OLYMPUS CASTABLE CERAMIC
It consists of glass phase of LiO2 – Na2O – ZnO – Al2O3 –
TiO2 – SiO2 and crystalline phase of Na Mg3 (SiO3AlO10) F2 and
Li2OAl2O3 – 4SiO2
Procedure :
Burn out 3000C 30 min 8000C for 30 min
Casting at 5500C Ceramming at 7500C for 2 hrs.
Shimida et al 2000 : prior to cementation : Silane coupling agent +Primer
increases bond strength
OPTIMAL PRESSABLE CERAMIC
1996 Janeric Pentron Company
Optimally pressable
ceramic system
Glass ceramic with leucite phase
Crystalline compacted ceramic
on heating
Die fabrication Wax pattern
Sprued wax patterns ready for
investing
Paper casting ring is closed from top
as the material sets
Paper casting ring is peeled Investment placed in burnout furnace
850 c -90min
Colored pellets
used for casting
Hot mold placed in optimal
auto press machine
Pressed molds cooled
to room temperature
mold is scored and broken apart Recovering of casting
Removal of remaining investment
1150 c -20min hold
CASTABLE PHOSPHATE GLASS CERAMIC
Contains :
Natural phosphate as natural teeth
Marketed as ‘Crys-Cera’
MACHINABLE
CERAMICS
Luthy et al 1991
Kelly et al 1991
Strength > Laboratory fabricated Ceramic
CEREC SYSTEMS
Materials involved :
Vita mart II, Dicor MGC and Pro Cad
Sanidine
KAlSi3O8
Mica
crystals 70%
Leucite containing
ceramic
CERamic REConstruction,
Optical scanning
The compact, mobile unit consists of three components: a
small camera, a computer screen and a three – axis – of – rotation
milling machine.
The cad/cam cerec system has evolved from the: cerec-
1,which fabricated only marginally fitting single and dual surface
ceramic inlays.
Cerec-2,which showed advances in computing, upgraded
software and expanded form of grinding technique.
Cerec-3 that can design well-fitting inlays, onlays, crowns,
veneers etc., in a single visit.
3D cerec
Scanning and designing
3 dimensional viewing Milling
CELAY SYSTEM
Uses copy milling technique
Resin pattern fabricated directly on master die and pattern is used
for milling porcelain restorations
Jacot et al 1998 : in ceram blanks in celay system.
Inlay pattern mounted
(copy side)
Copy milling pattern out
of ceramic material
(milling side)
Sorenson 1994 : marginal fit of CELAY > CEREC
PROCERA SYSTEM
Dies are enlarged to compensate for sintering shrinkage.
Scanning
Milling machine
Shape on computer screen
Contact scanner
Processing method
Procera restorations
Tooth color gradation reproducibility : CCM ( computer color matching )
Shigemi Ishikawa et al 2005
Scope of All-Ceramic
Anterior Crowns
Posterior Crowns
Ceramic inserts
Inlays & Onlays
Porcelain laminate veneers
Laminate : Is an extremely thin shell of porcelain applied directly to tooth structure
1930-1940 Charles Pincus used thin porcelain shells, denture adhesives were used
1970-1980 Composite resin laminate veneers Monochromatic appearance
Staining
Loss of luster
1980s Bonding porcelain to etched surfaces
Hsu et al 1985 - Mechanical retention increased by etching porcelain
Shear bond strength of etched 4 > Unetched
Calamia et al 1984 - Application of silane coupling agent-
Improved bond strength
*min thickness of laminate: 0.3 – 0.5 mm
All ceramic F P D
Two part build up Bulk in lingual connector region
Pre (PFM)
Post (All Ceramic)3 unit FPD
DC – ZIRKON technique : Vult von steyern et al in 2004
< 5% flaws, flexural strength : 900 Mpa
Used for posterior FPD’s
DC-Zirkon Blocks Milled Block
Tried on Working Cast
All ceramic Resin bonded fixed partial dentures
Introduced 1986-1988 Ibsen et al and Garber et al
Matthias kern 2005 :Cantilever resin bonded FPD
Ceramic veneer F P D
Ceramic inlay metal reinforced F P D
Ceramic veneer / Composite substructure F P D
All ceramic Posts
1993 Luthy et al – Post made of TZP-ZrO2
High flexural strength 1400 Mpa
1994 Sandhaus – Zirconia post with composite core
1995 Akagawa et al - Castable ceramic attached to zirconia post
1997 Ivoclar – introduced Ceramic core directly pressed onto Zirconia post
IPS Empress Cosmo ingot
Direct method
Indirect method
CONCLUSION
One who works with his hands is a labourer
One who works with his hands & mind is a craftsman
One who works with his hands , mind & heart is an artist
1.CONTEMPORARY FIXED PROSTHODONTICS
-ROSENSTIEL
2.PHILLIPS SCINCE OF DENTAL MATERIALS
-ANUSAVICE
3.FUNDAMENTALS OF FIXED PROSTHODONTICS
-SCHILLINGBURG
4.CONTEMPORARY ESTHETIC DENTISTRY:
-BRUCE J.CRISPIN
5.ESTHETIC DENTISTRY: AN ARTISTS SCIENCE
-RATNADEEP PATIL
6.JPD 1996;75:18-32
7.JPD 2004;91:136-43
8.OPERATIVE DENTISTRY 1990;15:61-70
9.QUINT INT 1991;22:257-262
10.QUINT INT 2005;36:141-147
REFERENCES
11.INT J PERIODONT REST DENT 1998;18:587-593
12.JOR 2005;32:180-187
13.JPD 2002;87:133-135
14.DENT MATER 2000;16:226-233
15.JPD 2000;83:530-534
16.QUINT INT 1985;3:135-141
17.JPD 1991;66:754-758
18.DENT MATER 2002;18:380-388
19.JPD 1991;66:747-753
20.J DENT 1990;18:227-235
REFERENCES
21.QUINT INT 1998;29:285
22.INT J PROSTHOD 1997;10:478
23.J PROSTHET DENT 1999;81:277
24.QUINT INT 1991;22:257-262
25.INT J PROSTHOD 1992;5:9-16
REFERENCES
Thought for the Day
THERE ARE TWO KINDS OF FAILURES
ONE WHO THOUGHT AND NEVER DID
ONE WHO DID BUT NEVER THOUGHT

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Ceramics

  • 2. contents 1.INTRODUCTION 2.EVOLUTION & HISTORY 3.METHODS TO STRENGTHEN PORCELAIN 4.ALLUMINOUS CORE PORCELAIN 5.IN-CERAM 6.CASTABLE CERAMICS 7.MACHINABLE CERAMICS 8.SCOPE OF ALL CERAMICS 9.CONCLUSION 10.REFERENCES
  • 4. DEFINITIONS Ceramics : compounds of one or more metals with a non metallic element(usually silicon,boron,oxygen) that may be used as a single structural component or as one of the several layers that are used in the fabrication of a ceramic based prosthesis . (G.P.T 7, Anusavice) Porcelain : a ceramic material formed of infusible elements joined by lower fusing materials.Most dental porcelains are glasses and are used in fabrication of teeth for dentures, pontics & facings, crowns, inlays, onlays and other restorations. (G.P.T 7) Ceramic is derived from Sanskrit word meaning Burnt earth
  • 5. 5  Formulated to provide:  Castability,  Moldability,  Injectability,  Color, Opacity, Translucency,  Machinability,  Abrasion resistance,  Strength,  Toughness.
  • 7. Denture teeth & Dentures -Duchateau 1774 Ceramic paintings and Vases
  • 8. 1887 PJC – CH. Land (platinum foil technique) 1962 PFM – Weinstein 1965 McLean and Hughes aluminium core porcelain 1957 Vines and Sommelman – Vaccum firing 1940 with advent of acrylics PJC lost popularity.
  • 9. Evolution of all ceramic restorations :  1887 – CH. Land gave porcelain jacket crown  1965 - McLean and hughes aluminous core porcelain  1980 - in ceram-slip casting, castable ceramics  Latest 1990’s - machinable ceramics(CADCAM)
  • 10. 10 CLASSIFICATION OF DENTAL CERAMICS 1) USE/INDICATION: Anterior, Posterior, crowns, veneers, post and cores, stain and glaze ceramic. 2) COMPOSITION: pure alumina, pure zirconia, silica glass, leucite based glass, Lithia based glass. 3) PROCESSING METHOD: sintering, partial sintering, glass infiltration, CAD-CAM, copy milling, condensation, heat pressing, casting, slip- casting.
  • 11. 11 4) FIRING TEMPERATURE: HIGH FUSING : 1300 C MEDIUM FUSING : 1101-1300 C LOW FUSING : 850-1100 C ULTRA LOW FUSING: < 850 C 5) MICROSTRUCTURE: glass, crystalline, crystal- containing glass
  • 12. 12 6) TRANSLUCENCY: Opaque, Translucent, Transparent 7) FRACTURE RESISTANCE 8) ABRASIVENESS
  • 13. 13  Three main divisions of ceramics: 1. Predominantly glassy materials, 2. Particle filled glasses---- Glass ceramics 3. Polycrystalline ceramics.  Esthetic dental ceramics : Glassy  Substructure dental ceramics: Crystalline
  • 14. 14  Best mimic the optical properties of enamel and dentine: Glassy material  Glasses: 3D network of atoms having no regular pattern to the spacing between nearest atoms, thus they are amorphous or without form.  Derived principally from a group of mined minerals called FELDSPAR: based on silica and alumina: Aluminosilicate glasses.  Resistant to crystallization during firing, long firing ranges, biocompatible.
  • 15. 15  Filler particles are added to the base glass composition to improve mechanical properties and to control optical effects like Opalescence, Color, Opacity.  Fillers: Crystalline/Higher melting glass  Leucite: first fillers to be used, crystalline mineral  Feldspar forms crystalline mineral Leucite, when mixed with metal oxides & fired to high temperature  Leucite is potassium-aluminum-silicate mineral with large coefficient of thermal expansion.
  • 16. 16  This filler was added to create porcelains that could be successfully fired on metal susbstruct.  Adding 17-25% Leucite filler to base glass creates porcelains that are thermally compatible with dental alloys. - Index of refraction close to feldspar, - “Selective etching”  Moderate strength increases can also be achieved with appropriate fillers added and uniformly dispersed: “Dispersion Strengthening”
  • 17. 17  Special subset of particle-filled glass  The crystalline filler particles are grown inside the glass object (pellet/prosthesis) by a special heat treatment that causes the precipitation within the glass.  This crystal nucleation and crystal growth process is called “Ceramming”.  E.g. Dicor: crystalline mica: 55 vol%  Empress 2: lithium disilicate : 70 vol%
  • 18. 18  No glassy components, atoms are densely packed, regular network: Crack propagation difficult.  Tougher and stronger than glassy ceramics.  Difficult to process, CAD-CAM.  Relatively opaque, core substructure.  E.g. Aluminum oxide, partially stabilized Zirconia.  Procera, Cercon, Lava.
  • 19. COMPOSITION OF DENTAL PORCELAINS: Composition (Percentage) Use - Feldspar 60-80% Basic glass former - Quartz 15-25% Filler - Oxide 9-15% Fluxes - Alumina 8-20% Glass former & fluxes -Metallic pigments 1% Color matching - Kaolin 3-5% Binder
  • 20. High Fusing Porcelains: Feldspar - 70-90% Quartz - 11-18% Kaolin - 1-10% Medium Fusing Low Fusing Silica dioxide 69.4% 64.2% Boric oxide 7.5% 2.8% Calcium oxide 1.9% Potassium oxide 8.3% 8.2% Aluminium oxide 4.8% 1.9% Lithium oxide - 2.1% Magnesium oxide 0.5% Medium & low fusing porcelain
  • 21. Individual Components Potash feldspar - K2O Al2O36SiO2 Soda feldspar - Na2O Al2O3 6 SiO2 Silica – SiO2 Crystalline quartz Crystalline cristobalite Crystalline tridymite Non-crystalline fused silica- it acts as a refractory skeleton provides strength and hardness.
  • 22. Glass modifiers: Boric oxide B2O3 Function: •Lowers fusion temperature •Increases flow of porcelain •Removes impurities •Help to produce dental porcelain with different firing temperature •Acts as a flux, by interrupting the integrity of the silica network.
  • 23. Kaolin: •Acts as a binder •Also imparts opacity Alumina: Forms a network in conjunction with silica. Alters softening viscosity. Metallic Pigments: Pigment oxides •Help to obtain various shades needed to stimulate natural teeth. Brown - Iron or nickel oxide Green - Copper oxide Yellow brown - Titanium oxide Blue - Cobalt oxide Pink - Chromium tin or chroma •Opacity is achieved by addition of :- Cerium oxide Zirconium oxide Titanium oxide Tin oxide
  • 24. 24  Excellent Flexural Strength, - Glazed : 141.1 MPa - Unglazed: 75.8 MPa  Compressive strength: 331 MPa  Tensile strength: 34 MPa  Shear strength: 110 MPa  Modulus of elasticity: 69 GPa  Surface hardness: 460 KHN
  • 26. 26  Less Reactivity ; Chemical Inertness  Brittle Fracture, Low fracture toughness,  Biocompatibility, Color Stability,  Refractory Nature, High Hardness,  Low Thermal Conductivity, Diffusibility and Electrical Conductivity.
  • 27. Advantages of porcelain •High abrasion resistance •Chemical inertness •Excellent thermal and electrical insulators •Excellent esthetic qualités •Translucency •Color stability •Capacity of pigmentation •Stain resistance •Enhanced polishability •High durable
  • 28. Disadvantages of porcelain •Highly brittle •Excessive wear of opposing teeth •High firing shrinkage Methods used to overcome the deficiencies of ceramics fall under 2 categories:- •Methods of strengthening brittle materials •Methods of designing components to minimize stress concentration and tensile stress
  • 30. Griffiths Flaw Crack Growth Sintering Process Why are Ceramics weak ? On moisture exposure crack growth is accelerated 1. Brittle – Covalent bonds 2. Inherent flaws 3. > # in moist environment
  • 31. Methods of Strengthening:- •Development of residual compressive stresses within the surface of the material. •Interruption of crack propagation. •Minimizing tensile stresses •Avoiding stress concentration 1) Development of residual stresses: Strengthening is gained by virtue of fact that these residual stresses must be first be negated by developing tensile stresses before any net tensile stress develops. . Principle: Strengthening is gained by the fact that the residual stresses must be first negated by the developing tensile stress before any net tensile stress develops. E.g. Normal tensile strength : + 60 MPa Residual comp. stress : - 40 MPa Total tensile stress to induce fracture: + 100 MP
  • 32. Methods: 1) Ion-exchange: (Chemical Tempering) Involves exchange of large potassium ions for the smaller sodium ions. •Sodium containing glass articles is placed in a bath of molten potassium nitrate. •The potassium ion is 35% larger than sodium ion. •Squeezing of the potassium ions into the place of sodium ions creates a large residual compressive stress
  • 33. 2.Thermal Tempering:- Most common methods. •Thermal tempering creates residual stresses by rapidly cooling (quenching). The surface of object while it is hot and in the softened (molten) state. •This rapid cooling produces a skin of rigid glass surrounding a soft (molten core). •As molten core solidifies it tends to shrink, creates residual tensile stresses within the outer surface. Mismatch Coefficient of Thermal Expansion:- •The metal and the porcelain used for the restoration are designed with slight mismatch in their co-efficient of thermal expansion. •The coefficient of thermal expansion for metals is more than porcelain thus the metal contacts more than the porcelain on cooling provides additional strength.
  • 34. Interruption of Crack Propagation: Methods: Dispersion a crystalline phase •Aluminous Porcelains (PJC): Alumina which is a tough crystalline material is added to a glass in the particulate form, the glass is toughened as the cracks cannot penetrate the alumina particles. •Dicor Castable Glass Ceramics): Dicor utilizes inhibition of crack prepagation by the growth of mica crystals in the ceramic as a result of heat treatment of the ceramic. Mica crystals in situ interrupt crack propagation their by strengthening the restoration. .
  • 35. Transformation Toughening: •New technique of strengthening glasses. Strengthening glasses involves the incorporation of crystalline material that is capable of undergoing a change in crystal structure when placed under stress. •The crystalline material partially stabilized Zirconia. The energy required for the transformation of is taken from the energy that allows to crack to propagate •Involves transformation of ZrO2 from a TETRAGONAL phase to a MONOCLINIC phase at the tips of cracks that are in the region of tensile stress.
  • 36. 36
  • 37.  Designed in such a way to overcome weakness.  To avoid exposure of the ceramic to high tensile stresses.  To avoid stress concentration at sharp angles.  Minimizing Tensile Stresses:  High tensile stresses  Posterior segment of mouth  Deep overbite in the anterior region  A ductile metal coping prevents the formation of Tensile stresses in the porcelain and prevents it failure. Reducing Stress Raisers:  Stress raisers are discontinuities in ceramic structures and in the brittle materials that cause stress concentration.
  • 38. Methods of strengthening brittle materials 1.Ion exchange 2.Thermal tempering 3.Thermal compatiability Minimise stress concentration 1. Reducing stress raisers 2. Minimise tensile stresses Residual compressive stresses Interruption of crack propagation Addition of dispersion phase Change in crystalline structure Particle stabilized zirconia Toughness of particle Al, dicor
  • 40. 2 Options 1. Strong Core ( Unaesthetic ) Layered with Veneering Porcelain 2. Esthetic as well as strong Core
  • 41.  Coping are prepared by  Electrodeposition of metal on duplicate die  Burnishing & heat treating metal foil on a die  Cad – cam  Casting pure metal by lost wax tecnique  Bonding of metal to ceramic, the ceramic must have :  Fusion temp well above its sintering temp  Co efficient of thermal contraction closely matched to that of the alloys.  Metal oxide on the metal is necessary for bonding
  • 42. Porcelain condensation  Careful cleaning metal frame work and thin layer of opaque porcelain is applied and baked.  Dentin porcelain powder in the shade selected for body/dentine portion.  Porcelain is supplied in powder & mixed with water and condensed into desired.  To achieve thorough condensation, 3 methods are used  Mild vibration  Cleaned excess water by tissue paper  Use brush to add dry powder to absorb excess water.
  • 43.
  • 44. Firing/ Sintering of porcelain  Porcelain restoration are fired either by temperature control alone or temperature or time control.  Sintering is defined as a process of heating without melting closely packed particles to form a cohert mass by inter-particle bonding and sufficient diffusion to decrease the surface area and increase the density of the structure.
  • 45.  The aim of glazing is to seal the open pores in the surface of a fired porcelain. Dental glazes are composed of colorless glass powder, applied to the fired crown surface, so as to produce a glossy surface.  Porcelain is cleaned and necessary stains applied.  Glazing is short, when glazing temperature is reached, on thin glassy film (glaze) is formed by viscous flow on the porcelain surface.  Fracture resistance of glazed porcelain is greater than unglazed porcelain
  • 47. CAPTEK SYSTEM : ( capillary casting technique) Duplicated refractory die Metal impregnated wax sheet Final coping Porcelain veneering CAPTEK is the answer for the most challenging situation because of its strength and excellent esthetics Captek G-97.5 gold, 2.5 silver Pt-pd
  • 48. (HELIO FORM HF 600 SYSTEM) Equipment Polyurethane dies Completed restorations ELECTRO FORMED
  • 49. 1965 Mc lean and Hughes 40 t0 50 wt% of Al2O3 Flexural strength 131 Mpa Platinum foil technique ALUMINOUS CORE PORCELAIN Finished CoresMaster model with dies Platinum foil adapted to die (Hi-Ceram)
  • 50. Unsintered CrownsDentin Ceramic additions Finished Crowns on dies Post-Cementation Mc lean 1979 Five year failure rate 2% for anteriors 15% for posteriors Large sintering shrinkage Seiber et al 1981 :light reflection better than porcelain fused to metal
  • 51. IN-CERAM A process used to form green ceramic shape by applying a slurry of ceramic particles and water or a special liquid to a porous substrate Such as a die material, there by allowing capillary action to remove water and densify the mass of deposited particles Flexural strength 350 MPa 500 MPa 700 MPa In-ceram Alumina In-ceram Spinell In-ceram Zirconia Crack deflection is the main Phenomenon ( Slip casting technique ) Saadoun 1989
  • 52. Al2O3 slip Glass infiltration Vita Inceramat3 Giordono 1995 : Al2O3 Core glass infiltrated Ceramic > Strength than Hi-Ceram, Di-Cor & Feldspathic Porcelain Vaccumat 4000 Premium
  • 53. Duplication In-Ceram refractory dies In-Ceram application Al2O3 slip 10 hrs 1120 c- 2hrs vita inceramat Working model Glass infiltration 4hrs 1100cShrinkage of dies
  • 54. Application of body and incisal porcelain Postoperative veiw of In-Ceram crowns Finished In-Ceram copings (Air abraded) Finished crowns Preoperative veiw Probster et al : Strength of In-Ceram > IPS Empress < PFM
  • 56. CASTABLE CERAMICS A glass ceramic material that combines the properties of a restorative material for function with the capability to be cast using the lost wax process  Di-Cor  Cerestore  IPS Empress  New types Cera pearl Canasite glass ceramic Optimal pressable ceramic Olympus castable ceramics Castable phosphate glass ceramic 1968 Mc Culloch
  • 57. DI-COR Non porous, homogenous, microstructure with uniform crystal size which is derived from the controlled growth of crystals within an amorphous matrix of glass. Ancestry Fredrick carter corning glass works Composition : SiO2, K2O and MgO, MgF2, Al2O3, ZrO2 and flourescing agent – TETRA SILICIC FLUOROMICA GLASS CERAMIC. Mica crystals Feldspathic porcelain
  • 58. Wax pattern Spruing Investing Burnout Divesting Cast glass coping Ceramming 1750 for 12hr 450 for 12 hr Centrifugal casting 2600 f
  • 59. Ceramming Ceramming oven Crystallised glass coping Conventional porcelain application & Firing Finished crown Cerramming done from room temparature- 1900 f for 1½ hrs and sustained for 6hrs inorder to form tetra silicic flouro mica crystals
  • 60. Properties : Flexural strength 81 6.8 Mpa Marginal adaptation : Weaver et al 1988 – conducted a study on 10 dicor crowns Marginal opening – 57 9 µm Due to less seating pressure, increase in density of ceramic after ceramming. Biocompatibility : Less bacterial counts Reason : smooth surface, low surface tension, flouride content, Low thermal conductivity
  • 61. Esthetics : Gross man and adiar : Hue and chroma of metal ceramics and castable ceramics matched natural teeth. Value of only castable ceramics matched natural teeth. Presence of mica crystals scatter light similar to enamel rods. Cementation : zinc phosphate, light activated urethane resin Bailey&Bennet 1988 etching with ammonium biflouride for 2 min
  • 62. Survival rate : Kenneth et al 1999 14yr study Crowns 82% Cores 100% Inlay and onlay 90% Partial coverage 92% Posterior 70% anterior 82.7% Expenstein et al 2000
  • 63. CERESTORE (SHRINK FREE CERAMICS) Chemistry : Binder silicone SiO SiO2 Unfired cerestore core : Al2O3 MgO Glass frit Silicone resin Fillers Al2O3 + MgO MgAl2O4 + Corrundum Strength 160-1800C Fired cerestore core : - Al2O3 (Corundun) MgAl2O4 (Spinel) Ba Mg2Al3 (Si9Al2O30) – Barium osumilite
  • 64. TECHNIQUE : Tooth preparation : 1.25 – 1.5 mm (Labial-lingual,interproximal) 1.5 – 2.mm (occlusal) 900 (full shoulder ) Conventional wax-up on heat stable Epoxy dies Investing Ceramic pellet in flask for pressing 160 c
  • 65. Ceramic injected into mold Plaster removal from pressed coping Refining green state coping Coping on master die fired at 1300 c
  • 66. Tooth preparation and impression Cerestore epoxy die Wax up and invest with master die Boil out Heat flask to 1800C Transfer mould ceramic into lost wax cavity directly on master die Retrieve master die Refine coping, add veneer porcelain
  • 67. Properties : • Flexural strength : 225 Mpa • Fit : exceptional fit because of direct moulding process. • Low thermal conductivity • Radio density similar to enamel • Biocompatible
  • 68. IPS-EMPRESS (PRESSABLE CERAMIC) Hot pressed ceramics Leucite reinforced K2O – Al2O3 – 4 SiO2 Lithium Disilicate reinforced SiO2 – LiO2 – P2O5 – ZrO2 2 types IPS Empress IPS Empress 2
  • 69. LEUCITE REINFORCED IPS EMPRESS Feldspar Leucite + glass phase In congruent Melting Resistance to crack propagation Pre cerammed Ingots Processing :
  • 70. Wax pattern Ceramic ingot & Al plunger Investing Pressing under vaccum 11500C Sprue removal Edward B Goldin 2005 compared leucite IPS Empress with PFM Mean marginal discrepancy 94 + 41 PFM 81 +25 IPS Burn out 8500 C 26 min hold
  • 71. Properties : Flexural strength : 117.3 - 167 Mpa Ion exchange method used to strengthen IPS empress (KnO3) 204 Mpa 11 hr immersion Esthetics : high esthetic value Clinical survival : Deniz G in 2002 95% survival 2-4 years Marginal adaptation : Shearer et al in 1996 : better marginal adaptation with hot pressed ceramics than aluminous core material.
  • 72. LITHIUM DISILICATE REINFORCED Base glass Melted with raw materials1400 to 16000C Poured into water Glass grains 20-30 microns Cylindrical ingots obtained Pressed into mold at 9000Cin Vaccum for 10 minute Automatic molding cycle 200 to 300 N Manufacturing : Mainly for post and core purposes Flexural strength :164+26 Mpa Cosmo glass Ceramic
  • 73. Full contouring Cut back Sprued pattern Investing Ingot pressing
  • 74. CERAPEARL CaO – P2O5 – MgO – SiO2 – Hobo and Kyocera bioceram group 1985 Crystalline microstructure similar to natural enamel Mechanical properties superior to enamel Laboratory steps : Tooth preparation, die preparation Wax patterns 2 stage burn out (8000C final temperature) Melted ceramic at 14600C casted under vaccum (special ring liners required {1.2mm} ) Reheating -870 c – Crystalline oxy apatite - moisture exposure – hydroxy apatite
  • 75. Clinical success : Nahara Y et al (1991) 2 year success rate – 100% Burn out chamber Centrifugal casting machine Ceramming unit and shading A) Pretreatment B) 3 months after cementation C) 2 yrs post- cementation Mainly indicated for inlays and full crowns
  • 76. FLUORCANASITE Multiple chain silicate glass ceramic that exhibits high strength and fracture toughness. Al2O3 – CaO – F – K2O – SiO2 CaF2 Nucleating agent Procedure : Wax pattern invested in Crystoballite investment Burn out at 7000C Heat soak for 0.5 hours Temperature drop to 5900C Centrifugal casting machine used at 12000C Direct ceramming Heat soaking 5200C Heating at 8600C CANASITE
  • 77. Properties : Flexural strength : 116 12 MPa Johnson et al in 2000 : Biaxial flexural strength 280.4 Mpa Fracture toughness : 660 Mpa
  • 78. OLYMPUS CASTABLE CERAMIC It consists of glass phase of LiO2 – Na2O – ZnO – Al2O3 – TiO2 – SiO2 and crystalline phase of Na Mg3 (SiO3AlO10) F2 and Li2OAl2O3 – 4SiO2 Procedure : Burn out 3000C 30 min 8000C for 30 min Casting at 5500C Ceramming at 7500C for 2 hrs. Shimida et al 2000 : prior to cementation : Silane coupling agent +Primer increases bond strength
  • 79. OPTIMAL PRESSABLE CERAMIC 1996 Janeric Pentron Company Optimally pressable ceramic system Glass ceramic with leucite phase Crystalline compacted ceramic on heating Die fabrication Wax pattern
  • 80. Sprued wax patterns ready for investing Paper casting ring is closed from top as the material sets Paper casting ring is peeled Investment placed in burnout furnace 850 c -90min
  • 81. Colored pellets used for casting Hot mold placed in optimal auto press machine Pressed molds cooled to room temperature mold is scored and broken apart Recovering of casting Removal of remaining investment 1150 c -20min hold
  • 82. CASTABLE PHOSPHATE GLASS CERAMIC Contains : Natural phosphate as natural teeth Marketed as ‘Crys-Cera’
  • 83. MACHINABLE CERAMICS Luthy et al 1991 Kelly et al 1991 Strength > Laboratory fabricated Ceramic
  • 84. CEREC SYSTEMS Materials involved : Vita mart II, Dicor MGC and Pro Cad Sanidine KAlSi3O8 Mica crystals 70% Leucite containing ceramic CERamic REConstruction, Optical scanning
  • 85. The compact, mobile unit consists of three components: a small camera, a computer screen and a three – axis – of – rotation milling machine.
  • 86. The cad/cam cerec system has evolved from the: cerec- 1,which fabricated only marginally fitting single and dual surface ceramic inlays. Cerec-2,which showed advances in computing, upgraded software and expanded form of grinding technique.
  • 87. Cerec-3 that can design well-fitting inlays, onlays, crowns, veneers etc., in a single visit.
  • 88. 3D cerec Scanning and designing 3 dimensional viewing Milling
  • 89. CELAY SYSTEM Uses copy milling technique Resin pattern fabricated directly on master die and pattern is used for milling porcelain restorations Jacot et al 1998 : in ceram blanks in celay system. Inlay pattern mounted (copy side) Copy milling pattern out of ceramic material (milling side) Sorenson 1994 : marginal fit of CELAY > CEREC
  • 90. PROCERA SYSTEM Dies are enlarged to compensate for sintering shrinkage. Scanning Milling machine Shape on computer screen Contact scanner
  • 92. Tooth color gradation reproducibility : CCM ( computer color matching ) Shigemi Ishikawa et al 2005
  • 96. Porcelain laminate veneers Laminate : Is an extremely thin shell of porcelain applied directly to tooth structure 1930-1940 Charles Pincus used thin porcelain shells, denture adhesives were used 1970-1980 Composite resin laminate veneers Monochromatic appearance Staining Loss of luster
  • 97. 1980s Bonding porcelain to etched surfaces Hsu et al 1985 - Mechanical retention increased by etching porcelain Shear bond strength of etched 4 > Unetched Calamia et al 1984 - Application of silane coupling agent- Improved bond strength *min thickness of laminate: 0.3 – 0.5 mm
  • 98. All ceramic F P D Two part build up Bulk in lingual connector region Pre (PFM) Post (All Ceramic)3 unit FPD
  • 99. DC – ZIRKON technique : Vult von steyern et al in 2004 < 5% flaws, flexural strength : 900 Mpa Used for posterior FPD’s DC-Zirkon Blocks Milled Block Tried on Working Cast
  • 100. All ceramic Resin bonded fixed partial dentures Introduced 1986-1988 Ibsen et al and Garber et al Matthias kern 2005 :Cantilever resin bonded FPD
  • 101. Ceramic veneer F P D Ceramic inlay metal reinforced F P D Ceramic veneer / Composite substructure F P D
  • 102. All ceramic Posts 1993 Luthy et al – Post made of TZP-ZrO2 High flexural strength 1400 Mpa 1994 Sandhaus – Zirconia post with composite core 1995 Akagawa et al - Castable ceramic attached to zirconia post 1997 Ivoclar – introduced Ceramic core directly pressed onto Zirconia post IPS Empress Cosmo ingot Direct method Indirect method
  • 104. One who works with his hands is a labourer
  • 105. One who works with his hands & mind is a craftsman
  • 106. One who works with his hands , mind & heart is an artist
  • 107.
  • 108. 1.CONTEMPORARY FIXED PROSTHODONTICS -ROSENSTIEL 2.PHILLIPS SCINCE OF DENTAL MATERIALS -ANUSAVICE 3.FUNDAMENTALS OF FIXED PROSTHODONTICS -SCHILLINGBURG 4.CONTEMPORARY ESTHETIC DENTISTRY: -BRUCE J.CRISPIN 5.ESTHETIC DENTISTRY: AN ARTISTS SCIENCE -RATNADEEP PATIL 6.JPD 1996;75:18-32 7.JPD 2004;91:136-43 8.OPERATIVE DENTISTRY 1990;15:61-70 9.QUINT INT 1991;22:257-262 10.QUINT INT 2005;36:141-147 REFERENCES
  • 109. 11.INT J PERIODONT REST DENT 1998;18:587-593 12.JOR 2005;32:180-187 13.JPD 2002;87:133-135 14.DENT MATER 2000;16:226-233 15.JPD 2000;83:530-534 16.QUINT INT 1985;3:135-141 17.JPD 1991;66:754-758 18.DENT MATER 2002;18:380-388 19.JPD 1991;66:747-753 20.J DENT 1990;18:227-235 REFERENCES
  • 110. 21.QUINT INT 1998;29:285 22.INT J PROSTHOD 1997;10:478 23.J PROSTHET DENT 1999;81:277 24.QUINT INT 1991;22:257-262 25.INT J PROSTHOD 1992;5:9-16 REFERENCES
  • 111. Thought for the Day THERE ARE TWO KINDS OF FAILURES ONE WHO THOUGHT AND NEVER DID ONE WHO DID BUT NEVER THOUGHT