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Exotic 2D Materials
Andres Castellanos-Gomez
2D Materials & Devices group
https://sites.google.com/site/2dmaterialsanddevicesgroup/home
andres.castellanos@imdea.org
IMDEA Nanoscience
Since April 2015
2D Materials and Devices group
Young Nanoscience institute (2014)
About 40 PIs
Physics / Chemistry / Biology
3 ERC Advanced + 1 ERC Strating
Madrid
2D Materials & Devices group
Why beyond graphene?
• Graphene transistors with low on/off ratio
– High consumption
– Low reliability
– No bit operations
Why beyond graphene?
• MoS2 transistors with large on/off ratio
• Low consumption
• High reliability
• Multiple bit operations
A. Kis’s groupManchester group
• Graphene transistors with low on/off ratio
– High consumption
– Low reliability
– No bit operations
• MoS2 transistors with large on/off ratio
• Low consumption
• High reliability
• Multiple bit operations
A. Kis’s group
Why beyond graphene?
Manchester group
2D Optoelectronics
Lee et al. Nano Letters (2012)
Yin et al. ACS Nano (2012)
Choi et al. Adv. Mater. (2012)
Buscema et al. Nano Letters (2013)
Ultrahigh photoresponse
MoS2 phototransistor
Lopez-Sanchez et al. Nature Nano. (2013)
2D Optoelectronics
Lee et al. Nano Letters (2012)
Yin et al. ACS Nano (2012)
Choi et al. Adv. Mater. (2012)
Buscema et al. Nano Letters (2013)
MoS2 phototransistor
Lopez-Sanchez et al. Nature Nano. (2013)
MoS2 phototransistor
Lee et al. Nano Letters (2012)
Yin et al. ACS Nano (2012)
Choi et al. Adv. Mater. (2012)
Buscema et al. Nano Letters (2013)
Limitted bandwidth!
2D Optoelectronics
Lopez-Sanchez et al. Nature Nano. (2013)
MoS2 phototransistor
Lee et al. Nano Letters (2012)
Yin et al. ACS Nano (2012)
Choi et al. Adv. Mater. (2012)
Buscema et al. Nano Letters (2013)
And slow!
2D Optoelectronics
Lopez-Sanchez et al. Nature Nano. (2013)
MoS2 based photodetection
2D Optoelectronics
Ultrahigh photoresponse
(0.1-800 A/W)
Narrow bandwidth
Low optical absorption
Slow response time
Unipolar (no PN junctions)
MoS2 based photodetection
2D Optoelectronics
Ultrahigh photoresponse
(0.1-800 A/W)
Narrow bandwidth
Low optical absorption
Slow response time
Unipolar (no PN junctions)
Advances in fundamental physics
and/or applications often come in the
form of new, unexplored materials
New layered materials
Yuangbo Zhang’s group. Nature Nanotech. (2014)
Peide Ye’s group. ACS Nano (2014)
Barbaros & Castro-Neto’s group. App. Phys. Lett. (2014)
Castellanos-Gomez et al. 2D Materials (2014)
Buscema et al. Nano Letters (2014)
Buscema et al. Nature Communications (2014)
Island et al. 2D Materials (2015)
Island et al. Adv. Opt. Mater. (2014)
Island et al. Adv. Mater. (2015)
Island et al. Sci. Rep. (2016)
TiS3
1.0 eV (direct) even in bulk
Black phosphorus
0.33 eV (direct) even in bulk
In2Se3
1.4 eV (direct) even in bulk
Bin Yu’s group. ACS Nano (2014)
Island et al. Nano Lett. (2015)
New layered materials
α-In2Se3
~30 cm2/Vs
Island et al. Nano Lett. (2015)
~30 cm2/Vs
Island et al. Nano Lett. (2015)
Island et al. Nano Lett. (2015)
Quereda et al. Unpublished (2016)
TiS3
C. Sanchez
I.J. Ferrer
J.R. Ares
M. Barawi
80 cm2/Vs
Island et al. Adv. Mater. (2015)
Island et al. Adv. Mater. (2015)
Island et al. Adv. Opt. Mater. (2014)
Black phosphorus
~120 cm2/Vs
Buscema et al. Nano Letters (2014)
Buscema et al. Nano Letters (2014)
Buscema et al. Nano Letters (2014)
Highly hydrophilic
Aging!
Island et al. 2D Materials (2015)
Sumary
TiS3
Huge photoresponse
Huge anisotropy
Response up to 1050 nm
Fast (5 msec)
Black phosphorus
Response up to 1050 nm
Fast (5 msec)
Ambipolar
Small photoresponse
Degradation
In2Se3
Huge photoresponse
Response up to 950 nm
Huge quantum confinement 1.4 eV – 2.8 eV
Slow (100 msec)
Sumary
Buscema et al. Chem. Soc. Rev. (2015)
A.J. Molina-Mendoza et al. arXiv:1606.06651
QH
Well-oriented layers
Naturally occurring vdW heterostructure
Ultrathin heterostructure by simply cleaving
P-type
Narrow gap (<0.7 eV)
Air-stable
MSc. Joshua
Island
Prof. Herre S. J.
van der Zant
Dr. Lucia
Aballe
Dr. Michael
Foerster
Dr. Miguel
Angel Niño
Dr. Emilio
M. Perez
Prof. Nicolás
Agraït
Prof. Gabino
Rubio-Bollinger
MSc. Aday J.
Molina-Mendoza
Dr. Emerson
Giovanelli
Dr. Charalambos
Evangeli
Prof. Juan Jose
Palacios
Msc. Wendel
Paz
Dr. Michele
Buscema
Ramon y Cajal program
2014-2021

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Andrés Castellano-Gómez-Exotic 2D materials

  • 1. Exotic 2D Materials Andres Castellanos-Gomez 2D Materials & Devices group https://sites.google.com/site/2dmaterialsanddevicesgroup/home andres.castellanos@imdea.org
  • 2. IMDEA Nanoscience Since April 2015 2D Materials and Devices group
  • 3. Young Nanoscience institute (2014) About 40 PIs Physics / Chemistry / Biology 3 ERC Advanced + 1 ERC Strating Madrid
  • 4. 2D Materials & Devices group
  • 6. • Graphene transistors with low on/off ratio – High consumption – Low reliability – No bit operations Why beyond graphene? • MoS2 transistors with large on/off ratio • Low consumption • High reliability • Multiple bit operations A. Kis’s groupManchester group
  • 7. • Graphene transistors with low on/off ratio – High consumption – Low reliability – No bit operations • MoS2 transistors with large on/off ratio • Low consumption • High reliability • Multiple bit operations A. Kis’s group Why beyond graphene? Manchester group
  • 8. 2D Optoelectronics Lee et al. Nano Letters (2012) Yin et al. ACS Nano (2012) Choi et al. Adv. Mater. (2012) Buscema et al. Nano Letters (2013) Ultrahigh photoresponse MoS2 phototransistor Lopez-Sanchez et al. Nature Nano. (2013)
  • 9. 2D Optoelectronics Lee et al. Nano Letters (2012) Yin et al. ACS Nano (2012) Choi et al. Adv. Mater. (2012) Buscema et al. Nano Letters (2013) MoS2 phototransistor Lopez-Sanchez et al. Nature Nano. (2013)
  • 10. MoS2 phototransistor Lee et al. Nano Letters (2012) Yin et al. ACS Nano (2012) Choi et al. Adv. Mater. (2012) Buscema et al. Nano Letters (2013) Limitted bandwidth! 2D Optoelectronics Lopez-Sanchez et al. Nature Nano. (2013)
  • 11. MoS2 phototransistor Lee et al. Nano Letters (2012) Yin et al. ACS Nano (2012) Choi et al. Adv. Mater. (2012) Buscema et al. Nano Letters (2013) And slow! 2D Optoelectronics Lopez-Sanchez et al. Nature Nano. (2013)
  • 12. MoS2 based photodetection 2D Optoelectronics Ultrahigh photoresponse (0.1-800 A/W) Narrow bandwidth Low optical absorption Slow response time Unipolar (no PN junctions)
  • 13. MoS2 based photodetection 2D Optoelectronics Ultrahigh photoresponse (0.1-800 A/W) Narrow bandwidth Low optical absorption Slow response time Unipolar (no PN junctions) Advances in fundamental physics and/or applications often come in the form of new, unexplored materials
  • 14. New layered materials Yuangbo Zhang’s group. Nature Nanotech. (2014) Peide Ye’s group. ACS Nano (2014) Barbaros & Castro-Neto’s group. App. Phys. Lett. (2014) Castellanos-Gomez et al. 2D Materials (2014) Buscema et al. Nano Letters (2014) Buscema et al. Nature Communications (2014) Island et al. 2D Materials (2015) Island et al. Adv. Opt. Mater. (2014) Island et al. Adv. Mater. (2015) Island et al. Sci. Rep. (2016) TiS3 1.0 eV (direct) even in bulk Black phosphorus 0.33 eV (direct) even in bulk In2Se3 1.4 eV (direct) even in bulk Bin Yu’s group. ACS Nano (2014) Island et al. Nano Lett. (2015)
  • 17. ~30 cm2/Vs Island et al. Nano Lett. (2015)
  • 18. ~30 cm2/Vs Island et al. Nano Lett. (2015)
  • 19. Island et al. Nano Lett. (2015)
  • 20. Quereda et al. Unpublished (2016)
  • 21. TiS3
  • 22. C. Sanchez I.J. Ferrer J.R. Ares M. Barawi
  • 23. 80 cm2/Vs Island et al. Adv. Mater. (2015)
  • 24. Island et al. Adv. Mater. (2015)
  • 25. Island et al. Adv. Opt. Mater. (2014)
  • 27. ~120 cm2/Vs Buscema et al. Nano Letters (2014)
  • 28. Buscema et al. Nano Letters (2014)
  • 29. Buscema et al. Nano Letters (2014)
  • 30. Highly hydrophilic Aging! Island et al. 2D Materials (2015)
  • 31. Sumary TiS3 Huge photoresponse Huge anisotropy Response up to 1050 nm Fast (5 msec) Black phosphorus Response up to 1050 nm Fast (5 msec) Ambipolar Small photoresponse Degradation In2Se3 Huge photoresponse Response up to 950 nm Huge quantum confinement 1.4 eV – 2.8 eV Slow (100 msec)
  • 32. Sumary Buscema et al. Chem. Soc. Rev. (2015)
  • 33.
  • 34. A.J. Molina-Mendoza et al. arXiv:1606.06651
  • 35.
  • 37.
  • 38.
  • 39.
  • 40. Naturally occurring vdW heterostructure Ultrathin heterostructure by simply cleaving P-type Narrow gap (<0.7 eV) Air-stable
  • 41. MSc. Joshua Island Prof. Herre S. J. van der Zant Dr. Lucia Aballe Dr. Michael Foerster Dr. Miguel Angel Niño Dr. Emilio M. Perez Prof. Nicolás Agraït Prof. Gabino Rubio-Bollinger MSc. Aday J. Molina-Mendoza Dr. Emerson Giovanelli Dr. Charalambos Evangeli Prof. Juan Jose Palacios Msc. Wendel Paz Dr. Michele Buscema
  • 42. Ramon y Cajal program 2014-2021

Editor's Notes

  1. Añadir explicacion moleculas y grafeno