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Introduc)on	
  in	
  PM2.5	
  measurements	
  in	
  	
  
                Urban	
  China	
  

    (中国城市空气颗粒物PM2.5监测简介)	
  




                       Roeland	
  Jansen	
  
             PhD	
  Student,	
  Fudan	
  University	
  

        Green	
  Drinks	
  China,	
  Shanghai,	
  August	
  9,	
  2012	
  
My	
  presenta)on	
   	
  
•  Introduc)on	
  in	
  PM2.5	
  
       •  Why	
  people	
  talk	
  about	
  it?	
  	
  
             – (为什么人们开始讨论?)	
  
       •  How	
  to	
  characterize	
  PM2.5?	
  
             – (PM2.5的特征是什么?)	
  
       •  Where	
  PM2.5	
  comes	
  from	
  and	
  where	
  it	
  goes?	
  
             – (PM2.5的来源和转化?)	
  
       •  Why	
  some	
  days	
  are	
  nice	
  and	
  most	
  days	
  are	
  not	
  so	
  nice?	
  
             – (为什么空气质量时好时坏?)	
  
       •  What	
  can	
  we	
  do	
  with	
  our	
  measurements?	
  
             – (我们如何进行监测?)	
  
Why	
  people	
  talk	
  about	
  PM2.5	
  and	
  
  what	
  are	
  they	
  talking	
  about?  	
  

(为什么人们开始讨论研究PM2.5  	
  
              	
  
  关于它的关键问题是什么?)
Effect	
  on	
  humans	
  (对人类的影响)
                                       	
  
•  Most	
  harmful	
  for:	
  	
  
      •  Elderly,	
  	
  
      •  Children	
  (0-­‐7	
  years)	
  and	
  	
  
      •  People	
  with	
  Asthma	
  
      •  People	
  with	
  heart	
  disease	
  

•  Most	
  harmful	
  are	
  the	
   human	
  body	
  unknown	
  species 	
  such	
  as	
  
   trace	
  elements	
  (=heavy	
  metals)	
  and	
  elemental	
  carbon	
  which	
  are	
  
   inside	
  PM2.5	
  	
  

•  Don t	
  do	
  any	
  physical	
  ac)vi)es	
  with	
  high	
  PM,	
  don t	
  go	
  running.	
  
   Instead	
  go	
  aXer	
  a	
  rain	
  period	
  or	
  period	
  with	
  strong	
  wind.	
  
Effect	
  on	
  the	
  Environment	
  
                                             	
  
               (对环境的影响)                 	
  
•  Dry	
  deposi)on:	
  gravity,	
  wind,	
  buildings,	
  trees	
  
•  Wet	
  deposi)on:	
  rain,	
  snow,	
  etc.	
  
Global	
  warming	
  effect.
                          	
  
What	
  does	
  PM	
  look	
  like?	
  
     (PM的结构?)            	
  
              Aerodynamic	
  diameter	
   dp 	
  

              PM10	
  dp	
  ≤	
  10	
  μm	
  (about	
  1/6	
  of	
  a	
  human	
  hair)	
  
              PM2.5	
  dp	
  ≤	
  2.5	
  μm	
  (about	
  1/24	
  of	
  a	
  human	
  hair)	
  
              Expressed	
  in	
  μg/m3	
  

                                            d	
  =	
  1	
  cm	
  
                                            I	
  =	
  1	
  cm3	
  
                                            Inside	
  are	
  up	
  to	
  
                                            10000	
  par)cles	
  

                                            This	
  means	
  that	
  every	
  breath	
  you	
  
                                            take	
  contains	
  about	
  5000000	
  
                                            par)cles	
  
What	
  does	
  PM	
  look	
  like?	
  




                          Reprinted	
  from	
  Fu	
  et	
  al.,	
  2012	
  
Names	
  and	
  standards(命名和标准)
                                    	
  
•  PM	
  =	
  par)culate	
  maber	
  
•  PM	
  =	
  Aerosols	
  =	
  Par)cles	
  =	
  solid/liquid	
  dispersed	
  
   in	
  the	
  atmosphere	
  

•  Standard	
  comes	
  from	
  Ministry	
  of	
  Environmental	
  
   Protec)on	
  (MEP)	
  and	
  is	
  	
  
             •  Annual	
  Average	
  =	
  35	
  μg/m3	
  (2010	
  BJ:	
  75	
  and	
  SH:	
  50)1	
  
             •  Compare	
  Annual	
  Average	
  set	
  by	
  USA	
  MEP	
  is	
  15	
  μg/m3	
  	
  

1	
  Ministry	
  of	
  Environmental	
  	
  Protec)on	
  and	
  Shanghai	
  Environmental	
  Monitoring	
  Center	
  
Where	
  does	
  PM2.5	
  come	
  from?   	
  
       The	
  “Natural”	
  sources	
  (来源) 	
  
Sea:	
  NaCl	
  
                                                       Desert:	
  
                                                       SiO2	
  (=sand)	
  




                                                       Vulcano:	
  
                                                       Sulfate	
  
                                                       Calcium	
  
                                                       Aluminium	
  
Where	
  does	
  PM2.5	
  come	
  from?	
  
The	
  human	
  or	
  “Anthropogenic”	
  sources	
  (=harmful)
                                                             	
  

                       NOx	
  
                       SO2	
  
                       VOC	
  
                       OH	
  
                       NH3	
  
Local	
  sources	
  and	
  transport	
  from	
  
             point	
  sources   	
  
                     Beijing	
  




                  Xiamen	
  
Nice	
  day!	
  (晴空万里)	
  	
  

  That s	
  why	
  some	
  days	
  
  are	
  nice	
  and	
  most	
  are	
  
  not	
  so	
  nice!	
  

Not	
  so	
  nice	
  day!(天气阴霾) 	
  




                                          Reprinted	
  from	
  	
  Jacob	
  
Where	
  does	
  PM2.5	
  go?	
  (沉降过程)
                                           	
  
•    Dry	
  deposi)on:	
  gravity,	
  wind,	
  buildings,	
  trees	
  
•    Wet	
  deposi)on:	
  rain,	
  snow,	
  etc.	
  
•    Chemical	
  conversion	
  by	
  oxida)on	
  
•    Transport	
  in	
  the	
  Environment	
  
Transport	
  in	
  the	
  Environment
                                                                    	
  
                                                                                                                                    在
                                                                                                                                    环
                                                                                                                                    境
                                                                                                                                    中
                                                                                                                                    的
                                                                                                                                    迁
                                                                                                                                    移



Picture	
  taken	
  at	
  278	
  km	
  height	
     Reprinted	
  from	
  NASA	
  (Science	
  vol.	
  300:	
  1103-­‐1104,	
  1996)	
  
Situa)on	
  in	
  China	
  
Energy	
  use	
  (1.000	
  TWh)	
  1990	
  
30	
  




25	
  




20	
  




15	
  




10	
  




  5	
  




  0	
  


          China	
                         US	
                               EU	
  

                                                                    Data	
  from	
  OECD,	
  IEA	
  
Energy	
  use	
  (1.000	
  TWh)	
  1990-­‐2008	
  
30	
  




25	
  




20	
  




15	
  




10	
  




  5	
  




  0	
  

          1990	
     2008	
                     1990	
     2008	
                    1990	
       2008	
  
              China	
                                  US	
                                  EU	
  
                                                                                     Data	
  from	
  OECD,	
  IEA	
  
Energy	
  use	
  (1.000	
  TWh)	
  1990-­‐2008	
  
30	
                                                                                                                            160	
  



                                                                                                                                140	
  
25	
                 146	
  
                                                                                                                                120	
  

20	
  
                                                                                                                                100	
  



15	
                                                                                                                            80	
  



                                                                                                                                60	
  
10	
  

                                                                                                                                40	
  

  5	
  
                                                                                                                                20	
  



  0	
  
                                                           20	
                                      7	
                        0	
  

          1990	
         2008	
                 1990	
              2008	
               1990	
              2008	
  
                China	
                                    US	
                                     EU	
  
                                                                                             Data	
  from	
  OECD,	
  IEA	
  
PopulaGon	
  Growth	
  from	
  1990-­‐2008	
  (million)	
  and	
  in	
  %	
  
                                                                                                                                             100	
  

1400	
  
                                                                                                                                             90	
  


1200	
                                                                                                                                       80	
  


                                                                                                                                             70	
  
1000	
  

                                                                                                                                             60	
  

 800	
  
                                                                                                                                             50	
  


 600	
                                                                                                                                       40	
  


                                                                                                                                             30	
  
 400	
  

                                                                                                                                             20	
  

 200	
  
                        17	
                                             22	
                                                                10	
  


     0	
                                                                                                                5	
                  0	
  

             1990	
              2008	
                       1990	
         2008	
                         1990	
              2008	
  
                 China	
                                                 US	
                                          EU	
  
                                                                                                    Data	
  from	
  OECD/World	
  Bank	
  
Energy	
  use	
  (kWh)	
  per	
  capita	
  1990-­‐2008	
  in	
  %	
  
90000	
                                                                                                                                                130	
  


80000	
                                  Effect	
  with	
  Increasing	
  wealth	
  	
                                                                   110	
  

70000	
                  111	
  
                                                                                                                                                       90	
  
60000	
  


                                                                                                                                                       70	
  
50000	
  


40000	
  
                                                                                                                                                       50	
  


30000	
  
                                                                                                                                                       30	
  

20000	
  

                                                                                                                                                       10	
  
10000	
  
                                                                           -­‐2	
  
                                                                                                                             1	
  
      0	
                                                                                                                                              -­‐10	
  

              1990	
          2008	
                           1990	
           2008	
                            1990	
             2008	
  
                   China	
                                                US	
                                           EU	
  
                                                                                            Data	
  from	
  OECD,	
  IEA	
  and	
  World	
  Bank	
  
Economics	
  and	
  rela)on	
  with	
  the	
  
              Environment       	
  
•  Increase	
  in	
  Energy	
  needs	
  is	
  supplied	
  by	
  Coal	
  
   factories(煤矿厂供应了不断增加的能量需求):	
  
        •  Burning	
  Coal	
  is	
  a	
  major	
  contribu)on	
  to	
  Air	
  Pollu)on	
  
        •  70%	
  of	
  the	
  Energy	
  in	
  China	
  is	
  from	
  Coal	
  
        •  Every	
  7	
  to	
  10	
  days	
  a	
  new	
  Coal	
  factory	
  opens	
  
        •  30%	
  of	
  the	
  world	
  (2003)	
  
•  Increase	
  in	
  traffic	
  
•  Increase	
  in	
  Agriculture	
  
•  All	
  have	
  a	
  big	
  impact	
  on	
  the	
  environment	
  
Why	
  China	
  is/was	
  so	
  bad?	
  
         (为什么中国污染这么严重?)                             	
  
•  Lack	
  of	
  Environmental	
  awareness	
  for	
  decades;	
  
    –  (数十年来缺少环保意识)	
  
•  Low	
  efficiency	
  of	
  Coal	
  factories;	
  
    –  (煤矿工厂能效利用率低下)	
  
•  High-­‐pollu)ng	
  vehicles;	
  
    –  (车辆尾气污染严重)	
  
•  Economic	
  growth	
  more	
  important	
  than	
  the	
  Environment?	
  
    –  (经济发展利益高于环境利益)	
  

•  But	
  things	
  are	
  changing…	
  
     –  (然而情况正在改变…….)	
  
Sample	
  and	
  analyze	
  PM2.5	
  
                     (PM2.5的采样和分析)	
  
Filter	
  measurements	
  (过滤器监测)	
  
     PM2.5 Inlet	

                                                    MassConc=	
  Mass	
  before-­‐	
  Mass	
  aXer	
  
                                                    (Mass	
  24hr-­‐Mass	
  t0)	
  /	
  airflow	
  


                                                            Eg:	
  
                                                            3020	
  ug	
  –	
  1100	
  ug	
  /	
  1	
  m3/hr	
  	
  
                                                            =	
  80	
  ug/m3	
  




Collected	
  aerosol	
  
mass	
  M	
  on	
  filter	
  
(eg	
  24	
  hrs)	



                               Flow
                               control	

   Air Pump
What’s	
  inside	
  a	
  PM2.5?	
  
                                	
  
   (PM2.5的组成)              	
  
Filter	
  	
  
     PM2.5 Inlet	





Collected	
  aerosol	
  
mass	
  M	
  on	
  filter	
  
(eg	
  24	
  hrs)	



                               Flow
                               control	

   Air Pump
Filter	
  
     PM2.5 Inlet	

                                                             Very	
  Harmful!!	
  




Collected	
  aerosol	
  
mass	
  M	
  on	
  filter	
  
(eg	
  24	
  hrs)	

                                                          General	
  composi)on	
  


                               Flow
                               control	

   Air Pump
Measurements	
  in	
  Shanghai
                                        	
  
           (PM2.5在上海的监测情况)                	
  
•  24	
  sta)ons	
  to	
  monitor	
  PM2.5	
  
    – (有24所监测站)	
  
•  Scien)sts	
  es)mate	
  that	
  ~50%	
  of	
  PM2.5	
  comes	
  from	
  
   vehicle	
  exhaust.	
  
    – (据科学家估计有约50%的PM2.5来自于汽车尾气)	
  
•  Each	
  sta)on	
  costs	
  about	
  80.000	
  –	
  380.000	
  RMB	
  
    – (每所监测站的平均费用在80.000	
  –	
  380.000	
  元)	
  
•  Hourly	
  data	
  (available	
  for	
  public)	
  
    – (实时数据(对公众开放))	
  
Towards	
  a	
  solu)on?	
  
What	
  does	
  the	
  government	
  do	
  (政府有何措施?):	
  
•  liminate	
  150.000	
  high-­‐pollu)ng	
  cars	
  by	
  2014;	
  
 E
      (
     – 到2014年淘汰150000辆重污染型汽车)	
  
• mprove	
  fuel	
  oil,	
  gasoline	
  and	
  diesel	
  quality;	
  	
  
 I
      (
     – 提升燃油,汽油,柴油的质量)	
  
•  ower	
  the	
  amount	
  of	
  sulfur	
  in	
  gasoline;	
  
 L
      (
     – 减少汽油中的含硫量)	
  
•  ontrol	
  of	
  dust	
  in	
  construc)on	
  sites;	
  
 C
      (
     – 有效控制建筑工地的扬尘)	
  
•  oal-­‐fired	
  boilers	
  replaced	
  with	
  cleaner	
  energy	
  hea)ng;	
  
 C
      (
     – 用清洁能源代替燃烧煤矿资源)	
  
Fudan:	
  4th	
  Teaching	
  building	
  
Our	
  current	
  research:	
  Visibility	
  
Reprinted	
  from	
  Malm,	
  1999.	
  
Hangzhou	
  site	
  in	
  ZheJiang	
  Uni
                                        	
  
App	
  
•  hbp://air.fresh-­‐ideas.cc/en/	
  
SCIENCE:	
  


                 Thank	
  you!
                             	
  

               And	
  special	
  thanks   	
  
                to	
  Annie	
  (刘佳)	
  
                                     	
  

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PM 2.5

  • 1.
  • 2. Introduc)on  in  PM2.5  measurements  in     Urban  China   (中国城市空气颗粒物PM2.5监测简介)   Roeland  Jansen   PhD  Student,  Fudan  University   Green  Drinks  China,  Shanghai,  August  9,  2012  
  • 3. My  presenta)on     •  Introduc)on  in  PM2.5   •  Why  people  talk  about  it?     – (为什么人们开始讨论?)   •  How  to  characterize  PM2.5?   – (PM2.5的特征是什么?)   •  Where  PM2.5  comes  from  and  where  it  goes?   – (PM2.5的来源和转化?)   •  Why  some  days  are  nice  and  most  days  are  not  so  nice?   – (为什么空气质量时好时坏?)   •  What  can  we  do  with  our  measurements?   – (我们如何进行监测?)  
  • 4. Why  people  talk  about  PM2.5  and   what  are  they  talking  about?   (为什么人们开始讨论研究PM2.5     关于它的关键问题是什么?)
  • 5.
  • 6.
  • 7. Effect  on  humans  (对人类的影响)   •  Most  harmful  for:     •  Elderly,     •  Children  (0-­‐7  years)  and     •  People  with  Asthma   •  People  with  heart  disease   •  Most  harmful  are  the   human  body  unknown  species  such  as   trace  elements  (=heavy  metals)  and  elemental  carbon  which  are   inside  PM2.5     •  Don t  do  any  physical  ac)vi)es  with  high  PM,  don t  go  running.   Instead  go  aXer  a  rain  period  or  period  with  strong  wind.  
  • 8. Effect  on  the  Environment     (对环境的影响)   •  Dry  deposi)on:  gravity,  wind,  buildings,  trees   •  Wet  deposi)on:  rain,  snow,  etc.  
  • 10. What  does  PM  look  like?   (PM的结构?)   Aerodynamic  diameter   dp   PM10  dp  ≤  10  μm  (about  1/6  of  a  human  hair)   PM2.5  dp  ≤  2.5  μm  (about  1/24  of  a  human  hair)   Expressed  in  μg/m3   d  =  1  cm   I  =  1  cm3   Inside  are  up  to   10000  par)cles   This  means  that  every  breath  you   take  contains  about  5000000   par)cles  
  • 11. What  does  PM  look  like?   Reprinted  from  Fu  et  al.,  2012  
  • 12. Names  and  standards(命名和标准)   •  PM  =  par)culate  maber   •  PM  =  Aerosols  =  Par)cles  =  solid/liquid  dispersed   in  the  atmosphere   •  Standard  comes  from  Ministry  of  Environmental   Protec)on  (MEP)  and  is     •  Annual  Average  =  35  μg/m3  (2010  BJ:  75  and  SH:  50)1   •  Compare  Annual  Average  set  by  USA  MEP  is  15  μg/m3     1  Ministry  of  Environmental    Protec)on  and  Shanghai  Environmental  Monitoring  Center  
  • 13. Where  does  PM2.5  come  from?   The  “Natural”  sources  (来源)   Sea:  NaCl   Desert:   SiO2  (=sand)   Vulcano:   Sulfate   Calcium   Aluminium  
  • 14. Where  does  PM2.5  come  from?   The  human  or  “Anthropogenic”  sources  (=harmful)   NOx   SO2   VOC   OH   NH3  
  • 15. Local  sources  and  transport  from   point  sources   Beijing   Xiamen  
  • 16. Nice  day!  (晴空万里)     That s  why  some  days   are  nice  and  most  are   not  so  nice!   Not  so  nice  day!(天气阴霾)   Reprinted  from    Jacob  
  • 17. Where  does  PM2.5  go?  (沉降过程)   •  Dry  deposi)on:  gravity,  wind,  buildings,  trees   •  Wet  deposi)on:  rain,  snow,  etc.   •  Chemical  conversion  by  oxida)on   •  Transport  in  the  Environment  
  • 18. Transport  in  the  Environment   在 环 境 中 的 迁 移 Picture  taken  at  278  km  height   Reprinted  from  NASA  (Science  vol.  300:  1103-­‐1104,  1996)  
  • 20. Energy  use  (1.000  TWh)  1990   30   25   20   15   10   5   0   China   US   EU   Data  from  OECD,  IEA  
  • 21. Energy  use  (1.000  TWh)  1990-­‐2008   30   25   20   15   10   5   0   1990   2008   1990   2008   1990   2008   China   US   EU   Data  from  OECD,  IEA  
  • 22. Energy  use  (1.000  TWh)  1990-­‐2008   30   160   140   25   146   120   20   100   15   80   60   10   40   5   20   0   20   7   0   1990   2008   1990   2008   1990   2008   China   US   EU   Data  from  OECD,  IEA  
  • 23. PopulaGon  Growth  from  1990-­‐2008  (million)  and  in  %   100   1400   90   1200   80   70   1000   60   800   50   600   40   30   400   20   200   17   22   10   0   5   0   1990   2008   1990   2008   1990   2008   China   US   EU   Data  from  OECD/World  Bank  
  • 24. Energy  use  (kWh)  per  capita  1990-­‐2008  in  %   90000   130   80000   Effect  with  Increasing  wealth     110   70000   111   90   60000   70   50000   40000   50   30000   30   20000   10   10000   -­‐2   1   0   -­‐10   1990   2008   1990   2008   1990   2008   China   US   EU   Data  from  OECD,  IEA  and  World  Bank  
  • 25. Economics  and  rela)on  with  the   Environment   •  Increase  in  Energy  needs  is  supplied  by  Coal   factories(煤矿厂供应了不断增加的能量需求):   •  Burning  Coal  is  a  major  contribu)on  to  Air  Pollu)on   •  70%  of  the  Energy  in  China  is  from  Coal   •  Every  7  to  10  days  a  new  Coal  factory  opens   •  30%  of  the  world  (2003)   •  Increase  in  traffic   •  Increase  in  Agriculture   •  All  have  a  big  impact  on  the  environment  
  • 26. Why  China  is/was  so  bad?   (为什么中国污染这么严重?)   •  Lack  of  Environmental  awareness  for  decades;   –  (数十年来缺少环保意识)   •  Low  efficiency  of  Coal  factories;   –  (煤矿工厂能效利用率低下)   •  High-­‐pollu)ng  vehicles;   –  (车辆尾气污染严重)   •  Economic  growth  more  important  than  the  Environment?   –  (经济发展利益高于环境利益)   •  But  things  are  changing…   –  (然而情况正在改变…….)  
  • 27. Sample  and  analyze  PM2.5   (PM2.5的采样和分析)  
  • 28. Filter  measurements  (过滤器监测)   PM2.5 Inlet MassConc=  Mass  before-­‐  Mass  aXer   (Mass  24hr-­‐Mass  t0)  /  airflow   Eg:   3020  ug  –  1100  ug  /  1  m3/hr     =  80  ug/m3   Collected  aerosol   mass  M  on  filter   (eg  24  hrs) Flow control Air Pump
  • 29. What’s  inside  a  PM2.5?     (PM2.5的组成)  
  • 30. Filter     PM2.5 Inlet Collected  aerosol   mass  M  on  filter   (eg  24  hrs) Flow control Air Pump
  • 31. Filter   PM2.5 Inlet Very  Harmful!!   Collected  aerosol   mass  M  on  filter   (eg  24  hrs) General  composi)on   Flow control Air Pump
  • 32. Measurements  in  Shanghai   (PM2.5在上海的监测情况)   •  24  sta)ons  to  monitor  PM2.5   – (有24所监测站)   •  Scien)sts  es)mate  that  ~50%  of  PM2.5  comes  from   vehicle  exhaust.   – (据科学家估计有约50%的PM2.5来自于汽车尾气)   •  Each  sta)on  costs  about  80.000  –  380.000  RMB   – (每所监测站的平均费用在80.000  –  380.000  元)   •  Hourly  data  (available  for  public)   – (实时数据(对公众开放))  
  • 33. Towards  a  solu)on?   What  does  the  government  do  (政府有何措施?):   •  liminate  150.000  high-­‐pollu)ng  cars  by  2014;   E ( – 到2014年淘汰150000辆重污染型汽车)   • mprove  fuel  oil,  gasoline  and  diesel  quality;     I ( – 提升燃油,汽油,柴油的质量)   •  ower  the  amount  of  sulfur  in  gasoline;   L ( – 减少汽油中的含硫量)   •  ontrol  of  dust  in  construc)on  sites;   C ( – 有效控制建筑工地的扬尘)   •  oal-­‐fired  boilers  replaced  with  cleaner  energy  hea)ng;   C ( – 用清洁能源代替燃烧煤矿资源)  
  • 34. Fudan:  4th  Teaching  building  
  • 35. Our  current  research:  Visibility  
  • 37. Hangzhou  site  in  ZheJiang  Uni  
  • 39. SCIENCE:   Thank  you!   And  special  thanks   to  Annie  (刘佳)