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HOW DOES KRYSTOL AFFECT
CORROSION OF REBAR
ALIREZA BIPARVA
Research & Development Manager / Concrete Specialist
Kryton International Inc.
www.kryton.com
www.kryton.com
WHAT IS CORROSION?
Corrosion is a natural and costly process of destruction, like 
earthquakes and floods. 
but :
• It is silent; and 
• Can be prevented or at least controlled.
www.kryton.com
WHAT IS CORROSION?
ASTM defines corrosion as:
The chemical or electrochemical reaction between 
a material and its environments 
that produces a deterioration of the material.
www.kryton.com
WHAT IS THE COST OF CORROSION?
Corrosion is the main cause of damage and early failure of reinforced concrete 
structures. 
Makes up more than 80% of all damages of the reinforced concrete structures. 
In the United States alone, the total annual repair costs associated with 
concrete deterioration is estimated to be $300 billion.
Nearly 95% of concrete damage in the GCC’s coastal region is caused by 
reinforcement corrosion and consequent spalling of concrete.
www.kryton.com
WHY STEEL IS NEEDED IN CONCRETE?
Concrete is one of the most widely used construction materials with many advantages 
such as:
• Formability;
• Durability;
• High compressive strength‐Typical Compressive Strength: 20‐40 MPa;
But
• It is weak in tension ‐ Typical Tension Strength: 2‐5 MPa. 
www.kryton.com
WHY STEEL IS NEEDED IN CONCRETE?
www.kryton.com
www.kryton.com
WHY STEEL IS NEEDED IN CONCRETE?
www.kryton.comwww.kryton.com
www.kryton.com
WHY STEEL IS NEEDED IN CONCRETE?
www.kryton.comwww.kryton.comwww.kryton.com
Weight
www.kryton.com
WHY STEEL IS NEEDED IN CONCRETE?
www.kryton.comwww.kryton.comwww.kryton.comwww.kryton.com
Weight
Compression
Tension
www.kryton.com
WHY STEEL IS NEEDED IN CONCRETE?
www.kryton.comwww.kryton.comwww.kryton.comwww.kryton.com
www.kryton.com
WHAT IS THE SOLUTION?
www.kryton.comwww.kryton.comwww.kryton.comwww.kryton.com
Weight
Tension Steel
www.kryton.com
WHY STEEL IS NEEDED IN CONCRETE?
www.kryton.comwww.kryton.comwww.kryton.comwww.kryton.com
www.kryton.com
WHAT ARE THE REQUIRMENTS FOR CORROSION
TO OCCUR?
Iron (Fe) 
Oxygen Water
Corrosion
www.kryton.com
WHY DOES STEEL IN CONCRETE CORRODE?
Due to the high‐alkalinity of concrete, the 
steel reinforcing bars are passivated by an 
iron oxide film (Fe2O3) that protects the steel. 
SO
Concrete normally provides reinforcing steel 
with excellent corrosion protection. 
UNTIL
The passive layer breaks down.
Photo Courtesy of PCA 
www.kryton.com
WHY DOES STEEL IN CONCRETE CORRODE?
Different systems such as chloride ions can break down this passivity and allow 
the steel to actively corrode.
The Corrosion Cell
ww.kryton.com
Steel 
Product
Steel 
Corrosion
Ore
Mining
Smelting
Iron oxide 
Iron Un‐Stable
Stable
WHY DOES CORROSION OCCUR?
www.kryton.com
WHY DOES CORROSION OCCUR?
Iron oxide is the natural state of iron, and it is more 
thermodynamically stable.
www.kryton.com
HOW DOES CORROSION AFFECT THE INTEGRITY OF A
CONCRETE SRUCTURE?
Products of corrosion (rust), occupy a greater volume than the original steel 
Staining, cracking, and spalling of the concrete 
This expansion creates tensile stresses in the concrete
www.kryton.com
Cover Cracking and Spalling of the Concrete 
HOW DOES CORROSION AFFECT INTEGRITY OF A
CONCRETE SRUCTURE?
www.kryton.com
HOW DOES CORROSION AFFECT INTEGRITY OF A
CONCRETE SRUCTURE?
www.kryton.com
WHAT ARE THE STEPS ON DETERIORATION OF
REINFORCED CONCRETE?
www.kryton.com
WHAT IS THE PREMATURE CORROSION
DETERIORATION?
www.kryton.com
WHAT IS THE EFFECTIVE CORROSION CONTROL SYSTEM?
Either 
• Extend the time to corrosion initiation; or 
• Reduce the corrosion rate of embedded steel; or 
• Both 
www.kryton.com
WHAT ARE THE STEPS OF DETERIORATION OF
REINFORCED CONCRETE?
www.kryton.com
WHAT ARE THE STEPS OF DETERIORATION OF
REINFORCED CONCRETE?
www.kryton.com
A crack is a direct path for corrosive agents to penetrate and reach the steel.
An experiment performed in the Middle East found that concrete exposed to hot 
climates had significantly higher permeability and up to a 70% reduction in the time 
to corrosion‐induced‐cracking compared to concrete exposed to moderate 
conditions. 
The loss of durability was attributed to micro‐cracking due to thermal cycling, which 
was designed to simulate a hot, Middle Eastern climate. 
HOW CRACKING INFLUENCES CORROSION OF REBAR?
www.kryton.com
HOW CRACKING INFLUENCES CORROSION OF REBAR?
www.kryton.com
WHAT ARE THE TYPICAL CORROSION PROTECTION
SYSTEMS?
Traditional measures to mitigate corrosion are:
• Cathodic Protection
• Corrosion Inhibitor admixtures
• Anti‐corrosion coating
And 
• Using less permeable and durable concrete
www.kryton.com
HOW TO CONSTRUCT DURABLE STRUCTURES?
The penetration of water into concrete is a critical factor in the corrosion of 
steel reinforcement. 
• Water acts as a carrier for chloride ions, and 
• Water is required for corrosion to occur. 
Therefore, the first line of defense against corrosion is to prevent the 
penetration of water into the concrete. 
www.kryton.com
With the exception of mechanical damage, all the adverse influence on durability
involve the transport of fluids through the concrete.
(Properties of Concrete, Neville)
Water Permeability determines the rate of deterioration
Service life - Durability
HOW TO CONSTRUCT DURABLE STRUCTURES?
www.kryton.com
Concrete is a hard material with a network of openings
(capillaries, pores, cracks and micro cracks)
Water can pass through unprotected concrete
Water can directly damage concrete (Freeze – Thaw).
Water acts as a carrier of aggressive chemicals (Chloride).
HOW TO REDUCE PERMEABILITY OF CONCRETE?
www.kryton.com
Sheet membranesFluid-applied
membranes
Membrane forms a barrier against water penetration
Membrane
HOW TO REDUCE PERMEABILITY OF CONCRETE?
www.kryton.com
Traditional waterproofing system apply 
a barrier to the concrete
Alternative: 
Make the concrete the barrier
HOW TO REDUCE PERMEABILITY OF CONCRETE?
www.kryton.com
Admixture can replace the need for external
waterproofing membranes
HOW TO REDUCE PERMEABILITY OF CONCRETE?
www.kryton.com
Crystalline waterproofing as an admixture (KIM) was invented and
pioneered by Kryton during the 1980’s.
Powdered form:
• Added into the concrete mix at 2% of the cementitious content
• Added directly to ready mix truck or at the batch plant
• Effective against hydrostatic pressure
WHAT IS INTEGRAL CRYSTALLINE WATERPROOFING?
www.kryton.com
Regular Concrete
ICW Concrete
HOW TO CONSTRUCT DURABLE STRUCTURES?
www.kryton.com
Crystallization
Reduce Shrinkage
cracking
Reactive
Improve SS 
Water
Concrete
ICW
HOW DOES KIM AFFECT WATER PENETRATION?
www.kryton.com
HOW TO SELECT THE BEST SOLUTION?
Long Term Hawaii Study
Which product is best to do the job of protecting your steel from 
corroding? 
A long‐term field exposure study was conducted 
(2002‐2012) to evaluate the durability of reinforced concrete 
specimens exposed to an aggressive marine environment.
www.kryton.com
www.kryton.com
Twenty five reinforced concrete 
panels containing various: 
• Pozzolans; and 
• chemical admixtures; 
were exposed to a marine 
environment.
HOW TO SELECT THE BEST SOLUTION?
Long Term Hawaii Study
www.kryton.com
HOW TO SELECT THE BEST SOLUTION?
Long Term Hawaii Study
Corrosion
Inhibitor
Control
Waterproofing
admixture (densifier) 
Kryton
(KIM)
www.kryton.com
HOW TO SELECT THE BEST SOLUTION?
Long Term Hawaii Study
The key findings in the reports are as follows:
• The panel using KIM outperformed all other chemical 
admixtures. 
• KIM panel showed significant reduced half‐cell reading when 
compared with the control specimen. 
• In addition, after 10 years exposure, KIM panel does not have 
any signs of corrosion. 
www.kryton.com
HOW DOES KIM AFFECT CORROSION OF REBAR?
KIM
Self‐Sealing
Crystallization
Reduce Permeability
Cont. Heat of Hydration Control Bleeding
Reduce Cracking
Inhibit Water and 
Chemical Penetration
Extend Initiation Reduce Corrosion Rate
Reduce Corrosion of Rebar
THANK YOU
www.kryton.com
www.kryton.com
THANK YOU FOR
ATTENDING
A wealth of presentations and reports are available at
www.middleeastconcrete/presentations
PLEASE DON’T FORGET TO COLLECT YOUR ATTENDANCE CERTIFICATE

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