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Emission to air from ship -
Towards best practice for beyond
   compliance operations and
     management for ships



                          By
            Sulaiman Olanrewaju, Oladokun
          PhD Researcher ( Marine Technology)
Specific Objectives

To discuss :
• The links between air emission,
  efficiency, energy conservation and
  climate problem
• The source of air pollution from ships
• Air emission regulation regime
• Mitigation option for prevention and
  control
• Quantification and assessment
• Environmental Technology- Existing ship
  and new - built
Presentation Navigation
•   Introduction
•   Energy, efficiency and environment
•   Environmental issues in ship operations
•   Regulation built – up
•   Ships emission to air and issues of global warming
•   Energy and fuel quality
•   Good practice towards beyond compliance
•   Alternative energy and technology
•   Environmental technology
•   The future of energy and ship
"It does not matter where on Earth you live,
everyone is utterly dependent on the existence of
 that lovely, living saltwater soup. There’s plenty
of water in the universe without life, but nowhere
is there life without water. The living ocean drives
     planetary chemistry, governs climate and
 weather, and otherwise provides the cornerstone
of the life-support system for all creatures on our
      planet, from deep-sea starfish to desert
 sagebrush. That’s why the ocean matters. If the
   sea is sick, we’ll feel it. If it dies, we die. Our
    future and the state of the oceans are one."
     • Sea Change A Message of the Oceans
               • Sylvia Earle, 1995.
Introduction

Man, Environment and Technology
• Man
• Biosphere- Water, Air and Soil
• The techno sphere - The ship, The
  port
Introduction

  • Combustion -----> pollution control --->
    energy conservation
  • Combustion = Generation of electricity +
    release of chemical
  • Emission from combustion impacts:
    Generation of fossil fuel scarcity , Photo
    chemical smog, Oil dependent world.
    Aggressive quest for alternative
    energ,International and local registration
    build-up
  • Reassessment and revolution work on:
  • plan to reduce emission of existing and new
    engine
  • Challenge of matching energy efficiency at
    minimum emission of pollution
  • Control of emission is linked to traditional
    factors of reliability, fuel economy, per shaft
Fuel efficiency linked to pollution

  • Maximizing overall energy efficiency-temperature,
    electrical thermodynamic, and mechanical
  • A well insulated boiler system can achieve combustion
    efficiency close to 100% and thermal efficiency of the
    order of 90%
  • Heat loss by high temperature exhaust gas and in
    coolant systems reduce the thermal efficiency
  • For electrical energy, 70 percent of the primary energy
    is lost in the power generation & transmission stage
  • Thermal efficiency is improved by: insulation , recycling
    of gaseous effluents, rate of heat transfer in combustion
    chamber and liquid coolants
  • Designer of combustion chamber -> to achieve high
    combustion efficiency - unburnt fuel is considered to be
    a pollutants
  • Double incentive - complete combustion efficiency and
    reduce emission
Fuel efficiency linked to pollution

  • A good combustion require high temperature, a resident time
    sufficient long, present of oxidizer
  • Heat transfer from flame to solid surface is composed off
    conduction , convection and radiation
  • Luminosity and present of solid particles can lead to
    significance change in ratio of radioactive to convective heat
    transfer
  • Problem associated with achieving maximum efficiency are
    linked to pollution control
  • Complete oxidation and burning of fuel ->increase
    combustion efficiency and reduce pollution
  • However oxide of nitrogen have presented major problems
    due to contradictory requirement of pollutant formation and
    combustion efficiency
  • Formation of oxides of nitrogen has affinity to high
    temperature
  • Oxide of nitrogen ->difficult to treat as a pollutant - >
    restriction vital before formation
  • Sulfur control require removal of sulfur before burning or
    extraction from effluent
Issue of Today

• Worldwide focus of fuel-> Exhaust gas
  emission law by IMO and introduction of
  local rules
• Emission limits driving evolution to
  development and adaptation to new
  technology
• Solution anticipated to maintenance of ship
  life cycle at average of 25 years
• Focus is currently more on, NOx and SOx –
  HC, Cox and particulate will soon join
• Consideration involve not only fuel use and
  design but also OPERATIONAL ISSUE
Main Threat

 • Freshwater supply and quality – surface & groundwater
 • Risk and threats to human health -> collapse          of
   ecosystem health
 • Pollution of the lower atmosphere -> combustion of
   fossil fuels and biomass burning
 • Land/marine interaction & transboundary issues (
   eutrophication)
 • Environmental flashpoints/security
 • Nuclear waste issues
 • Long-term and inter-annual climate change
 • Habitat loss and forest fragmentation
 • Endangered species, link to food security & economic
   impacts
 • Sanitation and waste due to crosscutting urbanization
 • Chemical and toxic substances – Quality of life
 • Critical environmental zones
General Impacts

• The alteration and destruction of habitats
  and ecosystems

• The effects of sewage on human health

• Widespread and increasing Eutrophication

• The decline of living resources Sediments

• The impacts of Climate Change  Rising sea
Impact Categories

High Probability and High-Impact Events:

• Landbased resources degradation
• Marine Resource degradation
• Damages due to disasters
• Environmental damages:
-Loss of biodiversity
-Depletion of natural resource bases
-Increased greenhouse gas emissions

Low probability and slow impact events:

• Global climate change
• Stratospheric ozone depletion
• Persistent organic pollutants
Global Climate Change Impacts


Stratospheric ozone depletion:

  -   Loss of biodiversity
  -   Freshwater degradation
  -   Desertification and land degradation
  -   Deforestation and the unsustainable use of forests
  -   Marine environment and resource degradation
Pollution from Ships
 Release:

 • Water pollution
 • Air emission
 • Persistent organism

 • Accidental - Grounding ,Stranding, Loss of oil,
   Hazardous cargo, Noxious liquid, collision with
   marine mammals
 • Operation - Oil spill, Cargo and Bunker fuel, Emission
   ( Sox, Nox, CFC & VoC) Antifouling toxins ,Ballast
   water discharges, Noise, Waste disposal at sea,
   Dredging @dispersal of soil

 -Intentional
 -Unintentional
Flow Process of typical exhaust gas Composition



                                •Emission is
                                inherent
                                consequence of
                                powered shipping
                                •Fuel oil burning as
                                main source
                                •Continuous
                                combustion
                                machineries -
                                boilers, gas turbines
                                and incinerators
Global Warming Potentials by
Emission Sources




 12000
                               Cox
 10000
                               NOx
  8000
                               CHX
  6000
                               HFC-134a
  4000
                               HFC-227e a
  2000                         HFC-c-23a
    0                          CF
         GWP (100 Ye ar ITH)
Emission Source and Current Reduction Methods
UN Agencies Get Serious

• Galvanize the scientific community:
- set up panel's /collaborating scientists and
  technical bodies
- use existing scientific bodies and research
  centers
- use global observation systems

• Tap on informal sources of information related
  to early warning
• Dealing with problem of sharing sensitive data
  among countries
• Human capacity
• Rapid spread of Internet as a tool for
  information compilation, discussion, and
  dissemination
Regulation Build-Up
• UN Agencies
• Local agencies


          UN Agencies Regulation Cluster

 •(Oil Spills Protocol) - Protocol Concerning
 Specially Protected Areas and Wildlife (SPAW
 Protocol)
 •Protocol Concerning Pollution from Land-based
 Sources and Activities (LBS Protocol)
 •Agenda 21
IMO Get Serious – New Strategies


• To address greenhouse gas emissions from
  ships- Adoption of control and prevention
  measures in 2003;
• To address problems associated with the
  transfer of harmful aquatic organisms in ships'
  ballast water – adoption of final text of IMO
  Diplomatic Conference in 2004;
• To support the International Convention on the
  Control of Harmful Anti-fouling Systems in
  Ships 2001; and
• To address the ongoing implementation of the
  International Convention on Oil Pollution
  Preparedness, Response and Co-operation
  1990.
LEGAL INSTRUMENTS AND REGULATION CLUSTER -
IMO


 •   International convention for the prevention of pollution from ships (MARPOL)
     1973
 •   It covers accidental and operational oil pollution as well as pollution by
     chemicals, goods in packaged form, sewage, garbage and air pollution
 •   It was modified by the protocol in 1978 relating to (MARPOL 73/78)

  MARPOL cover:

 •   Annex I- Oil
 •   Annex II- Noxious liquid chemicals
 •   Annex III- Harmful Goods (package)
 •   Annex IV- Sewage
 •   Annex V – Ballast water
 •   Annex VI- emission and air pollution (Sox, Nox and green house gas,
     emission of ozone depletion gas (ODG))
IMO

New annex to MARPOL focus :

• Control and management of Ballast water to minimize
  transfer of harmful foreign species
• Global prohibition of TBT in antifouling Coating - phase
  out scheduled for 2008
• International convention on oil pollution, Response and
  cooperation (OPRC) - 1990
• Policy to combating major incidents or threats , control
  to prevent, mitigates or eliminates danger of marine
  pollution through port to its coastline from a maritime
  casualty
• Annex protocol under this convention (HNS Protocol)
  covers marine pollution by hazardous and noxious
  substances (HNS)
• Air emission from ships
MARPOL Annex VI Convention

 • Technical code for prevention of air emissions
   from ships
 • Diesel engine test
 • Survey
 • Certification of compliance (IAPPC)
 • NOx compliance limit -30% reduction
 • Review of 5 years interval
 • Restriction on use of fluorocarbons on board
 • Carbon dioxide emission from ship
 • Fuel quality
 • SOx Emission Control Areas (SECA)
NOx

 Requirement for control of emission from ship

 • n<130 rpm 17 g/kwh
 • N>2000 rpm 45n ^0.2) g/kwh
 • N>200 rpm 9.8 g/kwh

 Other requirement and standards :

 •   NOx depends on : Fuel efficiency, Large bore, Low speed
 •   Fuel grade - ISO 8217
 •   Emission test - ISO 8178
 •   One common limits for all engine - International
     harmonization of regulation and equipment standards
IMO Nox Compliance Line
IMO NOx Compliance Line

 •  Minimizing the NOx emissions from diesel engines is
    a pressing international problem
 •  The above graph shows the international regulation
    standards adopted by the IMO in September 1997
 •  In response to this, engine manufacturers are
    exploring all means of reducing NOx emissions
 •  Low-NOx type marine diesel engine for new series
    engines use the following methods to reduce NOx
    emissions:
 *NOx is generated when combustion gas is held at high
    temperature.
    To reduce NOx generation, the following steps are
    required:
    1. Lower the combustion temperature.
    2. Shorten the combustion time.
 •  Improvements aimed at NOx reduction are:
 1. Delay of fuel injection time
 2. Use of SCR
SOx Emission Control Areas (SECA)

  • Annex VI to MARPOL 73/78 limits the sulphur
    content of MFO to 1.5% per mass and will apply in
    designated SECAs.
  • The first SECA is the Baltic Sea ->enters into force on
    19 May 2006.
  • The North Sea Area and the English Channel SECA
    will enter into force 22 November 2007.
  • The geographical boundaries for these two SECAs
    are defined in MARPOL 73/78
  • EU directive 2005/33/EC, requires ships to burn fuel
    oil with less than 1.5% sulphur in the North Sea
    SECA from 11 August 2007.)
  • New SECAs are expected to be adopted in the future
    based on certain criteria and procedures for
    designation of SECAs
  • MARPOL Annex VI, Regulation 14 (4b) gives the
    option of using an exhaust gas cleaning system
    (EGCS) which reduces the total SOX emissions to 6.0
    g/kWh.
Baltic Sea SECA
Current Reduction Potentials
Emission Release from Prime Movers




                  6
                  5
                  4                        NOx
                  3                        SOx

                  2                        CO
                                           CO2/100
                  1
                  0
                         GTE   DFD   SSD



SOURCE : Prof. Frankel- MIT
COx contents for Different Plants and Fuel
Emission of Particulates as a Function of Fuel
Sulphur Content




  A large part of the difference between HFO and DO is related to
  the sulphur, which together with water forms particulates
Mitigation

  • Shipboard and waste emission outline –
  • Treatment and Elimination - Pollution Prevention
     (P2) or Pollution Control-this is backbone of the
     thrust in achieving clean ship.
  • The basic P2 principles follow:
  • Pollution Prevention Use fewer environmentally
     harmful substances and generate less waste on
     board.
  Pollution Control: Increase treatment, processing, or
     destruction of wastes on board.
  -Eliminating the use of environmentally harmful
     chemicals, such as ozone-depleting substance
     (ODSs), toxic anti-foulant hull coatings, and other
     hazardous materials, may be the best approach for
     some potential problems.
  • Emission can only be subject to reduction at best
     rather than elimination
  • Other pollution are subjects to zero discharge or use
     of minimum possible given current technology
Emission Reduction Potentials

 • Recent studies revealed that exhaust emission from ship is
    responsible for :
 - 14% of the worldwide NOx emission
 - 8% of world SOx
 • Emissions from ocean-going are forecast to increase
 - 9% to 13% by 2010
 - 20% to 29% by 2020
 • Bulk carrier, container and tanker vessels are the three largest
    contributors.
 • Low exhaust emission diesel engine could achieves a 25% reduction
    in air emissions
 • The IMO, NOx emission limit will reduce the average NOx emission
    factors for ocean-going vessels by:
 - 4.1% for main engines
 - 8.3% for auxiliary engines
General Mitigation Techniques

 Primary measures:
 • Use of low sulfur fuel – ( less than 6g/kwh)

 Secondary measures:
 • Exhaust gas cleaning system or technology
 ** Sox for ECA (Emission Control Area) & Fuel change over

 There are 3 ways by which pollution can be controlled
 • Cleaning fuel prior to combustion (fuel preparation
   such as fractionation , catalytic cracking ,
   desulphurization )
 • Reducing the production of pollutants during
   combustion ( state combustion, exhaust gas
   recirculation and reduced temperature level )
 • Cleaning exhaust gas

 **(All these methods attracts major design
   modification that heat economic of energy balance
Existing Emission Mitigation Methods

 • Nitrogen reduction -> through choice of
   propulsion system

 • Sulfur reduction ->in bunker fuel

 • On board Catalytic system -> like :
 -Converter
 -water injection
 -Emulsion

 • Operationally -> through :
 -speed reduction
 -Use of shore power connection
NOx Reduction Options

 For existing engines:
 • Use of NOx injectors
 • Retarding injection timing
 • Temperature control of the charge air
 • Exhaust Gas Recirculation (EGR)
 • Fuel / water emulsion
 • Water injection
 • Humid Air Motor (HAM) Technique- addition of wet steam
   to the engine
 • Selective Catalytic Reduction (SCR)

 For new engines:
 Engine certification
 - Pre-certification,
 - Technical file clarification on engine family and group,
 - Final certification
Operational Measures

 -Relifiquation plants for LNG/LPG carriers-> Reduction
    of NOx, Sox, + cost saving through boiled off gas
    reuse
 -Speed reduction at ashore proximity->~ 10-20%
 -Alfa Lubricator system - Reduction in cylinder oil
    consumption-> reduction in particulate emission
 -Electronic control engine -> Programmed fuel injection
    and exhaust valve->Emission reduction
 -Turbo generator plant –> Use of high efficiency air
    flow for power take off –> reduce fuel + reduction of
    emission
 -System integration ->Humid air Motor (HAM)- engine
    intake air operating with water + Exhaust gas
    recirculation (EGR) ~50% reduction
 - HFO sulfur content - Need for oil company to change
    their equipment for low sulfur oil production-> ship-
    owner will face high cost
 - Additive solution has been expensive so far
 - Dual fuel option for low sulphuR restricted areas(
    1.5-4.5)– need for additional tanks and
Mitigation for Existing Ships
Slide Valve Option
                     •The content of
                     hydrocarbons in the
                     exhaust gas from large
                     diesel engines depends
                     on the type of fuel, the
                     engine adjustment and
                     design.
                     •sac volume is the void
                     space in the fuel valve
                     downstream of the
                     closing face
                     •Reduced sac volume in
                     the fuel valves has
                     greatly reduced HC
                     emissions.
Slide Valve Option
Alfa Lubricator System
Alfa Lubricator System
• A high-pressure electronically controlled lubricator that
  injects the cylinder lube oil into the cylinder at the
  exact position and time -> optimal effect is not always
  possible with the conventional lubricators
• A parallel line is followed by the SIP (Swirl Injection
  Principle) lubricator, where the oil is injected prior to
  piston passage, thereby having the oil distributed by
  the air swirl.
• Use for marine engines and engines for power
  generation purposes, very low feed rates have been
  demonstrated, with oil consumption down to 0.5
  g/bhph.
• By applying low oil dosage -> emission is lowered +
  less cylinder oil is wasted in the engine- where it could
  end up in the system oil, resulting in increased TBN and
  viscosity.
Particulate Emission - Function of Potential
Lub. Oil Consumption
PM Measure
             •The picture of the
             filters used for dilution
             tunnel PM
             measurements taken
             before and after the
             scrubber at 75% load
             and 15% recirculation.
Scavenge Air Factor
                      •NOx reduction by
                      means of SCR can
                      only take place in
                      the mentioned
                      temperature
                      window
                      •Because if the
                      temperature is too
                      high, NH3 will burn
                      rather than react
                      with the NO/NO2.
                      • At too low a
                      temperature, the
                      reaction rate would
                      be too low, and
                      •condensation of
                      ammonium
                      sulphates would
                      destroy the catalyst
SCR Installation Block Diagram
                 •To reduce the NOx level by
                 up to 98%, it is necessary to
                 make use of the SCR
                 (Selective Catalytic
                 Reduction) technique.
                 •With this method, the
                 exhaust gas is mixed with
                 ammonia NH3 or UREA (as
                 NH3 carrier) before passing
                 through a layer of a special
                 catalyst at a temperature
                 between 300 and 400C,
                 whereby NOx is reduced to
                 N2 and H2O.
                 •The reactions are, in
                 principle, the following:
                 •4NO + 4NH3 + O2 → 4N2 +
                 6H2O
                 •6NO2 + 8NH3 → 7N2 +
SCR System Layout


                    The amount of
                    NH3 injected into
                    the exhaust gas is
                    controlled by a
                    process computer
                    dosing the NH3 in
                    proportion to the
                    NOx produced by
                    the engine as a
                    function of the
                    engine load.
SCR Performance Reference List
SCR Electronic System

                   •The flexibility of the
                   electronically controlled
                   engine can improve the
                   emission control and
                   operation of NOX reduction
                   by means of water emulsion
                   •When operating with an
                   SCR catalyst, it is difficult to
                   maintain the engine
                   dynamics and the
                   turbocharger stability at
                   transient engine loads.
                   •With the electronically
                   controlled engine, a faster
                   load-up by early exhaust
                   valve opening and late
                   injection timing is possible
                   •Also, modulated exhaust
                   valve timing stabilizes the
                   turbocharger.
SCR Configuration
Exhaust Gas Recovery (EGR)

                 •EGR system has two
                 water injection stages,
                 with a simple water
                 separator unit after both.
                 •The first water injection
                 stage involves
                 humidification with salt
                 water in order to ensure
                 that there is no
                 freshwater consumption
                 in the second freshwater
                 injection stage.
                 •The outlet temperature
                 of the first stage is
                 approximately 100oC.
                 •This stage has a single
                 multi-nozzle injector.
EGR with Water Treatment
                   •This system is
                   connected to the exhaust
                   system in the same way
                   as the simple EGR system
                   •But the EGR line is
                   routed to a .bubble-bath.
                   scrubber from the which
                   cleans and cools the
                   exhaust gas.
                   •The water loop in the
                   scrubber system is
                   cooled and monitored in
                   a Water Treatment Skid
                   with a filter and settling
                   system, cleaning the
                   used sea water.
EGR and HAM System

                 •The NOx production only
                 takes place at very high
                 temperatures (2,200°K and
                 above), and it increases
                 exponentially with the
                 temperature.
                 •The EGR method is based
                 on a reduction of the
                 oxygen content in the
                 cylinder charge, and the
                 HAM method is partly
                 based on reducing the
                 oxygen content of the
                 cylinder charge and
                 partly on increasing the
                 heat capacity of the
                 cylinder charge by the
                 addition of water vapor
Typical Pressurized Fuel Oil System with
Homogenizer
Humid Air Motor (HAM)




  •The addition of water to the HFO by homogenisation increases
  the viscosity

  •To keep the viscosity at the engine inlet at 10-15 cSt, max. 20
  cSt, It is necessary to raise the temperature to more than the
  150oC which is standard today (max. 170oC at 50% water)
  raise the fuel oil loop
NOx Reduction from Emulsification




  •10% NOx reduction for each 10% water added
  •The water amounts refer to the injected amount
  of fuel oil
EGR
      •At increased
      recirculation
      amounts, the HC
      and PM emissions
      are reduced
      corresponding to
      the reduction of
      the exhaust gas
      flow from the
      engine.
Annual Operating Cost for LNG Carrier
Case Study – Retrofit Installation of SCR




 Norwegian owned LPG-carrier Navion Dania, equipped with
 a 6S35MC main engine.
Emission Assessment Quantification

•   Emissions calculation- using emission factors
    and activity data by mode of operation:
•   Emissions = Σ[(P x LF x EF)Main+ (P x LF x EF
    )Auxiliary] Modex TMode
•   P = registered main or auxiliary engine power,
    kW;
•   LF = load factor relative to registered power;
•   EF = emission factor by mode, g/kWh;
•   Tmode= time in mode, hours.
Emission Factors
• NOx- 12-
  17g/kwh
• CO- 1.6g/kwh
• HC-0.5g/kwh
• Cox-660g/kwh
• Sox- 4.2g/kwh
Environmental Risk
•Since options are many and money
will be involve, it is better to use IMO
FSA HAZOP method for various
decision on alternatives.
•RISK = Hazard (Toxicity) x
Exposure (an
•estimate on probability that certain
toxicity will be realized)

For example:
•􀁺 Use of X rays has a high AQ (High
benefit, low risk)
•􀁺 Use of Thalidomide has a small AQ
(Small benefit,high risk)
•􀁺 Nuclear war has a very small AQ
(No benefit,very high risk)
Risk Management


• Risk management is the evaluation of
  • alternative risk reduction measures and the
    implementation of those that appear cost
    effective
• It must be remember that :
• Zero discharge = zero risk, but
-the challenge is to bring the risk to
  acceptable level
-at the same time, derive the max. benefit
Cost Benefit Analysis (CBA)




   Cost Benefit Analysis:
   Maximizing BOTH -> economic return +environmental return +
   environmental protection
Energy Source and Fuel Quality

 • The quests for an efficient fuel friendly to the
   environment have been recognized in maritime
   industry for a long time in maritime industry.
 • Improvements of gasoline and diesel by
   chemical reformulation that can lead to
   decrease in ozone-forming pollutants and
   carbon monoxide emissions
 • Inconvenience posed by these reformulation
   chemicals are performance problems:
 -cold-start ability
 -smooth operation
 -avoidance of vapor lock
 are disadvantages of using reformulated fuels.
 • Global trend in de-Carbonization of the energy
   system follow the following path: COAL > OIL>
   NATURAL GAS > HYDROGEN
Potential of Natural Gas

 • The drive towards environmentally friendlier
   fuels points next at Natural Gas (NG)
 • The infrastructures to support that trend are
   being pre-positioned by corporate
   mechanisms and governmental bodies
   worldwide.
 • NG is cheap and its reserve is plentiful.
 • Natural Gas as fuel is becoming more and
   more established in Urban Transport and
   Power Generation sectors.
 • Its use will also take aggressive approach
   for all coastal vessel including ferries due
   new regulations.
 • Internationally its operational record and
   GHG gas score is rated as GOOD.
Impact of Using New Fuel

 • That technology will transfer
   sympathetically to the marine industry via
   availability of engines, systems and
   technical assistance.
 • Marine craft operation in inland water
   operation as well as deep sea will require
   fuel supplied in bulk rendering the NG
   distribution viable
 • The use of an alternative fuel for vessel
   propulsion will leads to a design review of:
 - Power plant
 - associated fuel system
 - propulsion train;
 • + Effectively reshaping areas such as
   Machinery Arrangement, Hull Form,
   Compartment, Cargo Deck, Payloads,
   Superstructure, Interior Layouts, Escape &
Environmental Technology For
Emission Reduction


• Alternative energy
• Alternative fuel and dual fuel engines
• Infusion of water mist with fuel and
  subsequent gas scrubbing units for slow
  speed engines
• Additional firing chamber
• Potential for gas turbine complex cycle
• Potential for turbocharger diesel engine
• Compound cycle with : gasified fuel,
  external compressor, combustion with pure
  oxygen
• Exhaust after treatment for medium speed
  engines
Combine Cycle Engine
Combined Cycle
Round trip emission for 135,000 cubic meter
LNG ship
Option for LNG Propulsion System
Option for LNG Propulsion System
Prime Movers and Drives
Comparison of Propulsion Plants
efficiency and System Size
Environmental Technology Update
• Lloyd performed a research on exhaust
  gas emission assessment
• Roll-Royce built Allen 5000 Series engine
  with electronics fuel injectors that
  control NOx
• Mak engine has developed a new MDS
  engine with reduction in NOX without fuel
  penalty
Exhaust gas Monitoring Equipments




  Come with new technology must be monitoring system –
    some of the available monitoring systems are :

  • Electrochemical cells
  • Chemiluminescent analyzer
  • Paramagnetic analyzer
  • Analysis of optical radiation

  Monitoring mode could be :

  -In situ - with simultaneous data analysis
  -Extractive systems- data analysis transfer to other location
     for processing
Sustainability and Maritime

 MARITIME INDUSTRY IN NEW WORLD
  CHARACTERIZED BY SUSTAINABILITY
   CAPACITY BUILDING , EFFICIENCY
    OPTIMIZATION OF DEVELOPMENT ,
PRACTICE AND OPERATIONS THAT MEETS
THE NEEDS OF THE PRESENT GENERATION
WITHOUT COMPROMISSING THE ABILITY
 OF FUTURE GENERATION TO MEET THEIR
                NEED
Advantages of Maintaining
•
    Quality
    Good environmental quality is essential for sustaining
  coastal and marine ecosystems20, commercial,
  recreational fisheries, and economic growth in coastal
  communities.
• It is also an important means of providing natural
  protection against rising sea levels and storm damage.
• The health of coastal and marine ecosystems is affected
  by water quality, and in turn, water quality is
  dependent upon ecosystem health. If one is impaired,
  the other is threatened.
• Despite their value and the programs designed to protect
  them, many coastal waters are being degraded at an
  alarming rate in addition to this.

** Ship that meet environmental requirement will be able
  to meet requirement of “GREEN PASSPORT” concept for
  ships
Advantages of Maintaining Quality

 Other advantages are :

 • Compliance with all applicable environmental laws
 • and regulations;
 • No significant adverse environmental impacts;
 • Wastes treated or destroyed on board to the extent
 practicable;
 • No inappropriate dependence on shore facilities for
 waste off-load and disposal;
 • Minimal energy consumption;
 • Minimal logistical costs for waste management; and
 • Minimal use of hazardous materials.

 **Reducing emission will make ship to meet future
   local and international emission regulation.
LOCAL MARINE EMISSION RULES


  •   Today, only a few countries have ratified the IMO-regulations
  •   Countries like Sweden, Hamburg and Norway have introduced reductions in
      harbour fees for ships operating on low sulphur fuel and with a low NOx
      level, in order to encourage low pollution applications.
  •   There is potential for more local rules like these coming up, depending
      effectiveness of IMO enforcement regulationEuropean Union
  •   The EU has adopted the IMO annex VI Marpol convention including
      expanding the low-sulphur restricted area the French coast in the English
      Channel, and the North Sea.
  •   Sweden- The Swedish authorities decided to aim at a 75% emission
      reduction by the beginning of 2000. In order to reach this goal, the
      authorities apply financial incentives in the form of environmentally
      differentiated fairway and port due – To stimulate ship's to take measures
      which would benefit the environment, such as using catalytic converters or
      making other technical improvements that decrease the nitrogen oxide
      emissions and promote the use of low-sulphur bunker fuel..
  •   Norway -The Norwegian Maritime Directorate issues guidelines on emission
      limits. The limits do not apply to all ship types and are based on a
      calculation of the total emission load factors from NOX, SOX, the type of fuel,
      and the use of redundant machinery. The higher the emission factor, the
      better the protection of the environment, and the less is to be paid in
      tonnage tax by Norwegian owners and operators. This rule became effective
      on 28 November 2000, and applies to ships above 1000 net register tons.
The future Towards Clean Ship Operation

  • The development of new measuring equipment for emission control
    will continue in the coming years, and especially techniques like HAM
    and EGR
  • The concern of local authorities will change from focusing on NOx and
    SOx to include also smoke, in particular.
  • The IMO Annex VI unconditional ratification for NOx IN 2003 and the
    recent inclusion of SOx is sign for more environmental restriction in
    future
  • Local rules that encourage the use of emission cutting means, such as
    SCR reactors, through harbour fee reductions will become more
    dominant than today.
  • SCR units are preferably installed during the construction of the
    vessel, however, retrofitting is has been successfully practiced
  • The challenge to ship-owners will increase as vessels are required to
    have, or be prepared for, emission control equipment.
  • The sulphur content in fuel will be reduced, and vessel tank systems
    have to be prepared for dual fuel and dual cylinder lube oil systems.
  • In some areas, the operating profile of the ship will have to be
    adapted to local rules for reduced smoke emission.
The Future Towards Clean Ship Operation
• Land based air pollution regulation is a
  foundation for future legislatures in marine
  industry
• Fossil fuel is considered the single ;largest
  contributor to emission Apart from Nox , others
  like CO,HC, particulate matter , Cox, smoke
  emission are likely to attract new regulations
• To facilitate adaptation to emission regulations,
  operators, officers, engine builders, yards and
  ship-owners must have view to achieving the
  global target of a cleaner planet.
• The latest generation of electronically controlled
  engines are an integral part of that policy.
• "... [M]an’s fingerprint is found everywhere in
  the oceans. Chemical contamination and litter
  can be observed from the poles to the tropics
  and from beaches to abyssal depths...But
  conditions in the marine environment vary
  widely. The open sea is still relatively clean...In
  contrast to the open ocean, the margins of the
  sea are affected by man almost everywhere,
  and encroachment on coastal areas continues
  worldwide...If unchecked, this trend will lead to
  global deterioration in the quality and
  productivity of the marine environment."
 The State of the Marine Environment, 1989;Group of Experts on the Scientific Aspects
                                                                       of Marine Poll
Other Environmental Technology Update



•   Ozone safe substances- 200-Ton Air- conditioning Plant Conversion Kit -The CG-
    47and DDG-51 plants have been successfully converted to the ozone-friendly
    refrigerant HFC- 236fa conversion kit has been established by NRL

•   Solid waste - Solid-Waste Pulpers -The pulper (especially the large pulper) is the
    machine into which you dump tremendous quantities of paper, cardboard, or
    food waste. The waste mixes with seawater to form slurry, which is then
    discharged overboard.
•   Studies show an immediate 100,000-to-1 dilution when discharged into the wake
    of a ship. Ships equipped with a pulper can dispose of their paper, cardboard,
    and food waste just about anywhere and at anytime—at sea including MARPOL
    areas.

•   Liquid waste - OWS and Bilge water Polishers: Many bilge cleaners the Navy uses
    today contain long-lasting emulsifying agents, which produce stable oil-in-water
    emulsions that shipboard OWSs cannot effectively process.
Recent Development in Coalition Control
Work

A number of promising developments that exist today are:

• Kutsuro Kijima     showed a modeling approach that
  permitted analysis of passing situations that would help
  set procedural standards for safe passing.

• IanDand reported on the development of models
 for ship squat that have shown very good accuracy over the
   years.

• Larry Daggett described the advent of dual frequency
  DGPS receivers and their role in gathering full-scale ship
  trial data. In addition to the excellent horizontal accuracy
  of the normal DGPS receiver, these receivers provide
  vertical location with an accuracy measured in
  centimeters.
Measure for Ship Design for Safety
and Environmental Protection
  IMO approved interim guidelines for estimating the
    maneuverability:

  •   Rudder size and effectiveness,
  •   Ability to transit at slow forward speed,
  •   Propulsion and propeller characteristics,
  •    Number of available engine reversals,
  •    Adequate horsepower for control,
  •   Extra reserve rudder angle needed to allow for ship
      crabbing from wind
  •   forces or moored ship suction,
  •   Visibility from bridge and bridge arrangement,
  •    Hull form squat (trim and sink age) characteristics,
  •   effect of bank forces on moorings and passing ships,
  •   Air draft, Emergency anchoring ability,
  •   Amount of tow line leads and line access.
General Best Practice for Power Plants


 • General conservation practice for machineries are
   :
 • Fan lubrication
 • Pumps lubrications
 • Compressors lubrications
 • Repair steam and compress air leaks
 • Insulate bare steam lines
 • Inspect and repair steam traps increase
   condensate return
 • Minimize boiler blow down
 • Maintain and inspect temperature measuring
   devices
 • Maintain and inspect pressure measuring devices
Best Practice for Operation of
Machineries
• Recover energy from hot gases
• Reduce energy from hot liquid
• Reuse hot wash water
• Add effects to existing evaporators
• Use liquefied gases as refrigerants
• Recompress vapor for low pressure steam
• Generate low pressure steam from flash
  operation
• Use waste heat for absorption to reduce heat
  loss
Management Responsibility
• Maintain air- conditioner efficiency and reduce heated
  and cooled space
• Maintain boiler efficiency
• Use nature ventilation whenever and wherever
  possible, reduce air infiltration and seal leaks in pipes
  and ducts
• Raise office temperatures in summer
• Lower office temperature in winter
• Use shading efficiently
• Close windows and other air leaks
• Do not use light necessarily
• Turn off office equipment that is not use
Area of Concentration for Domestic Utilities


•   Cooking
•   Heating
•   Hot water
•   Cooking
•   Lighting
•   New equipment application
Personal Responsibility
• Buy energy efficient equipments
• Use well tuned engine for gain in efficiency and
  safety
• Use natural ventilation wherever it is possible
• Use natural ventilation in dwelling place
• Avoid unnecessary trips
• Do not waste food
• Do not overeat
• Make conscious effort to conduct your life in an
  energy efficient basis

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Emision from ship

  • 1. Emission to air from ship - Towards best practice for beyond compliance operations and management for ships By Sulaiman Olanrewaju, Oladokun PhD Researcher ( Marine Technology)
  • 2. Specific Objectives To discuss : • The links between air emission, efficiency, energy conservation and climate problem • The source of air pollution from ships • Air emission regulation regime • Mitigation option for prevention and control • Quantification and assessment • Environmental Technology- Existing ship and new - built
  • 3. Presentation Navigation • Introduction • Energy, efficiency and environment • Environmental issues in ship operations • Regulation built – up • Ships emission to air and issues of global warming • Energy and fuel quality • Good practice towards beyond compliance • Alternative energy and technology • Environmental technology • The future of energy and ship
  • 4. "It does not matter where on Earth you live, everyone is utterly dependent on the existence of that lovely, living saltwater soup. There’s plenty of water in the universe without life, but nowhere is there life without water. The living ocean drives planetary chemistry, governs climate and weather, and otherwise provides the cornerstone of the life-support system for all creatures on our planet, from deep-sea starfish to desert sagebrush. That’s why the ocean matters. If the sea is sick, we’ll feel it. If it dies, we die. Our future and the state of the oceans are one." • Sea Change A Message of the Oceans • Sylvia Earle, 1995.
  • 5. Introduction Man, Environment and Technology • Man • Biosphere- Water, Air and Soil • The techno sphere - The ship, The port
  • 6. Introduction • Combustion -----> pollution control ---> energy conservation • Combustion = Generation of electricity + release of chemical • Emission from combustion impacts: Generation of fossil fuel scarcity , Photo chemical smog, Oil dependent world. Aggressive quest for alternative energ,International and local registration build-up • Reassessment and revolution work on: • plan to reduce emission of existing and new engine • Challenge of matching energy efficiency at minimum emission of pollution • Control of emission is linked to traditional factors of reliability, fuel economy, per shaft
  • 7. Fuel efficiency linked to pollution • Maximizing overall energy efficiency-temperature, electrical thermodynamic, and mechanical • A well insulated boiler system can achieve combustion efficiency close to 100% and thermal efficiency of the order of 90% • Heat loss by high temperature exhaust gas and in coolant systems reduce the thermal efficiency • For electrical energy, 70 percent of the primary energy is lost in the power generation & transmission stage • Thermal efficiency is improved by: insulation , recycling of gaseous effluents, rate of heat transfer in combustion chamber and liquid coolants • Designer of combustion chamber -> to achieve high combustion efficiency - unburnt fuel is considered to be a pollutants • Double incentive - complete combustion efficiency and reduce emission
  • 8. Fuel efficiency linked to pollution • A good combustion require high temperature, a resident time sufficient long, present of oxidizer • Heat transfer from flame to solid surface is composed off conduction , convection and radiation • Luminosity and present of solid particles can lead to significance change in ratio of radioactive to convective heat transfer • Problem associated with achieving maximum efficiency are linked to pollution control • Complete oxidation and burning of fuel ->increase combustion efficiency and reduce pollution • However oxide of nitrogen have presented major problems due to contradictory requirement of pollutant formation and combustion efficiency • Formation of oxides of nitrogen has affinity to high temperature • Oxide of nitrogen ->difficult to treat as a pollutant - > restriction vital before formation • Sulfur control require removal of sulfur before burning or extraction from effluent
  • 9. Issue of Today • Worldwide focus of fuel-> Exhaust gas emission law by IMO and introduction of local rules • Emission limits driving evolution to development and adaptation to new technology • Solution anticipated to maintenance of ship life cycle at average of 25 years • Focus is currently more on, NOx and SOx – HC, Cox and particulate will soon join • Consideration involve not only fuel use and design but also OPERATIONAL ISSUE
  • 10.
  • 11.
  • 12. Main Threat • Freshwater supply and quality – surface & groundwater • Risk and threats to human health -> collapse of ecosystem health • Pollution of the lower atmosphere -> combustion of fossil fuels and biomass burning • Land/marine interaction & transboundary issues ( eutrophication) • Environmental flashpoints/security • Nuclear waste issues • Long-term and inter-annual climate change • Habitat loss and forest fragmentation • Endangered species, link to food security & economic impacts • Sanitation and waste due to crosscutting urbanization • Chemical and toxic substances – Quality of life • Critical environmental zones
  • 13. General Impacts • The alteration and destruction of habitats and ecosystems • The effects of sewage on human health • Widespread and increasing Eutrophication • The decline of living resources Sediments • The impacts of Climate Change Rising sea
  • 14. Impact Categories High Probability and High-Impact Events: • Landbased resources degradation • Marine Resource degradation • Damages due to disasters • Environmental damages: -Loss of biodiversity -Depletion of natural resource bases -Increased greenhouse gas emissions Low probability and slow impact events: • Global climate change • Stratospheric ozone depletion • Persistent organic pollutants
  • 15. Global Climate Change Impacts Stratospheric ozone depletion: - Loss of biodiversity - Freshwater degradation - Desertification and land degradation - Deforestation and the unsustainable use of forests - Marine environment and resource degradation
  • 16.
  • 17.
  • 18.
  • 19. Pollution from Ships Release: • Water pollution • Air emission • Persistent organism • Accidental - Grounding ,Stranding, Loss of oil, Hazardous cargo, Noxious liquid, collision with marine mammals • Operation - Oil spill, Cargo and Bunker fuel, Emission ( Sox, Nox, CFC & VoC) Antifouling toxins ,Ballast water discharges, Noise, Waste disposal at sea, Dredging @dispersal of soil -Intentional -Unintentional
  • 20. Flow Process of typical exhaust gas Composition •Emission is inherent consequence of powered shipping •Fuel oil burning as main source •Continuous combustion machineries - boilers, gas turbines and incinerators
  • 21. Global Warming Potentials by Emission Sources 12000 Cox 10000 NOx 8000 CHX 6000 HFC-134a 4000 HFC-227e a 2000 HFC-c-23a 0 CF GWP (100 Ye ar ITH)
  • 22. Emission Source and Current Reduction Methods
  • 23. UN Agencies Get Serious • Galvanize the scientific community: - set up panel's /collaborating scientists and technical bodies - use existing scientific bodies and research centers - use global observation systems • Tap on informal sources of information related to early warning • Dealing with problem of sharing sensitive data among countries • Human capacity • Rapid spread of Internet as a tool for information compilation, discussion, and dissemination
  • 24. Regulation Build-Up • UN Agencies • Local agencies UN Agencies Regulation Cluster •(Oil Spills Protocol) - Protocol Concerning Specially Protected Areas and Wildlife (SPAW Protocol) •Protocol Concerning Pollution from Land-based Sources and Activities (LBS Protocol) •Agenda 21
  • 25. IMO Get Serious – New Strategies • To address greenhouse gas emissions from ships- Adoption of control and prevention measures in 2003; • To address problems associated with the transfer of harmful aquatic organisms in ships' ballast water – adoption of final text of IMO Diplomatic Conference in 2004; • To support the International Convention on the Control of Harmful Anti-fouling Systems in Ships 2001; and • To address the ongoing implementation of the International Convention on Oil Pollution Preparedness, Response and Co-operation 1990.
  • 26. LEGAL INSTRUMENTS AND REGULATION CLUSTER - IMO • International convention for the prevention of pollution from ships (MARPOL) 1973 • It covers accidental and operational oil pollution as well as pollution by chemicals, goods in packaged form, sewage, garbage and air pollution • It was modified by the protocol in 1978 relating to (MARPOL 73/78) MARPOL cover: • Annex I- Oil • Annex II- Noxious liquid chemicals • Annex III- Harmful Goods (package) • Annex IV- Sewage • Annex V – Ballast water • Annex VI- emission and air pollution (Sox, Nox and green house gas, emission of ozone depletion gas (ODG))
  • 27. IMO New annex to MARPOL focus : • Control and management of Ballast water to minimize transfer of harmful foreign species • Global prohibition of TBT in antifouling Coating - phase out scheduled for 2008 • International convention on oil pollution, Response and cooperation (OPRC) - 1990 • Policy to combating major incidents or threats , control to prevent, mitigates or eliminates danger of marine pollution through port to its coastline from a maritime casualty • Annex protocol under this convention (HNS Protocol) covers marine pollution by hazardous and noxious substances (HNS) • Air emission from ships
  • 28. MARPOL Annex VI Convention • Technical code for prevention of air emissions from ships • Diesel engine test • Survey • Certification of compliance (IAPPC) • NOx compliance limit -30% reduction • Review of 5 years interval • Restriction on use of fluorocarbons on board • Carbon dioxide emission from ship • Fuel quality • SOx Emission Control Areas (SECA)
  • 29. NOx Requirement for control of emission from ship • n<130 rpm 17 g/kwh • N>2000 rpm 45n ^0.2) g/kwh • N>200 rpm 9.8 g/kwh Other requirement and standards : • NOx depends on : Fuel efficiency, Large bore, Low speed • Fuel grade - ISO 8217 • Emission test - ISO 8178 • One common limits for all engine - International harmonization of regulation and equipment standards
  • 31. IMO NOx Compliance Line • Minimizing the NOx emissions from diesel engines is a pressing international problem • The above graph shows the international regulation standards adopted by the IMO in September 1997 • In response to this, engine manufacturers are exploring all means of reducing NOx emissions • Low-NOx type marine diesel engine for new series engines use the following methods to reduce NOx emissions: *NOx is generated when combustion gas is held at high temperature. To reduce NOx generation, the following steps are required: 1. Lower the combustion temperature. 2. Shorten the combustion time. • Improvements aimed at NOx reduction are: 1. Delay of fuel injection time 2. Use of SCR
  • 32. SOx Emission Control Areas (SECA) • Annex VI to MARPOL 73/78 limits the sulphur content of MFO to 1.5% per mass and will apply in designated SECAs. • The first SECA is the Baltic Sea ->enters into force on 19 May 2006. • The North Sea Area and the English Channel SECA will enter into force 22 November 2007. • The geographical boundaries for these two SECAs are defined in MARPOL 73/78 • EU directive 2005/33/EC, requires ships to burn fuel oil with less than 1.5% sulphur in the North Sea SECA from 11 August 2007.) • New SECAs are expected to be adopted in the future based on certain criteria and procedures for designation of SECAs • MARPOL Annex VI, Regulation 14 (4b) gives the option of using an exhaust gas cleaning system (EGCS) which reduces the total SOX emissions to 6.0 g/kWh.
  • 35. Emission Release from Prime Movers 6 5 4 NOx 3 SOx 2 CO CO2/100 1 0 GTE DFD SSD SOURCE : Prof. Frankel- MIT
  • 36. COx contents for Different Plants and Fuel
  • 37. Emission of Particulates as a Function of Fuel Sulphur Content A large part of the difference between HFO and DO is related to the sulphur, which together with water forms particulates
  • 38. Mitigation • Shipboard and waste emission outline – • Treatment and Elimination - Pollution Prevention (P2) or Pollution Control-this is backbone of the thrust in achieving clean ship. • The basic P2 principles follow: • Pollution Prevention Use fewer environmentally harmful substances and generate less waste on board. Pollution Control: Increase treatment, processing, or destruction of wastes on board. -Eliminating the use of environmentally harmful chemicals, such as ozone-depleting substance (ODSs), toxic anti-foulant hull coatings, and other hazardous materials, may be the best approach for some potential problems. • Emission can only be subject to reduction at best rather than elimination • Other pollution are subjects to zero discharge or use of minimum possible given current technology
  • 39.
  • 40. Emission Reduction Potentials • Recent studies revealed that exhaust emission from ship is responsible for : - 14% of the worldwide NOx emission - 8% of world SOx • Emissions from ocean-going are forecast to increase - 9% to 13% by 2010 - 20% to 29% by 2020 • Bulk carrier, container and tanker vessels are the three largest contributors. • Low exhaust emission diesel engine could achieves a 25% reduction in air emissions • The IMO, NOx emission limit will reduce the average NOx emission factors for ocean-going vessels by: - 4.1% for main engines - 8.3% for auxiliary engines
  • 41. General Mitigation Techniques Primary measures: • Use of low sulfur fuel – ( less than 6g/kwh) Secondary measures: • Exhaust gas cleaning system or technology ** Sox for ECA (Emission Control Area) & Fuel change over There are 3 ways by which pollution can be controlled • Cleaning fuel prior to combustion (fuel preparation such as fractionation , catalytic cracking , desulphurization ) • Reducing the production of pollutants during combustion ( state combustion, exhaust gas recirculation and reduced temperature level ) • Cleaning exhaust gas **(All these methods attracts major design modification that heat economic of energy balance
  • 42. Existing Emission Mitigation Methods • Nitrogen reduction -> through choice of propulsion system • Sulfur reduction ->in bunker fuel • On board Catalytic system -> like : -Converter -water injection -Emulsion • Operationally -> through : -speed reduction -Use of shore power connection
  • 43. NOx Reduction Options For existing engines: • Use of NOx injectors • Retarding injection timing • Temperature control of the charge air • Exhaust Gas Recirculation (EGR) • Fuel / water emulsion • Water injection • Humid Air Motor (HAM) Technique- addition of wet steam to the engine • Selective Catalytic Reduction (SCR) For new engines: Engine certification - Pre-certification, - Technical file clarification on engine family and group, - Final certification
  • 44. Operational Measures -Relifiquation plants for LNG/LPG carriers-> Reduction of NOx, Sox, + cost saving through boiled off gas reuse -Speed reduction at ashore proximity->~ 10-20% -Alfa Lubricator system - Reduction in cylinder oil consumption-> reduction in particulate emission -Electronic control engine -> Programmed fuel injection and exhaust valve->Emission reduction -Turbo generator plant –> Use of high efficiency air flow for power take off –> reduce fuel + reduction of emission -System integration ->Humid air Motor (HAM)- engine intake air operating with water + Exhaust gas recirculation (EGR) ~50% reduction - HFO sulfur content - Need for oil company to change their equipment for low sulfur oil production-> ship- owner will face high cost - Additive solution has been expensive so far - Dual fuel option for low sulphuR restricted areas( 1.5-4.5)– need for additional tanks and
  • 46. Slide Valve Option •The content of hydrocarbons in the exhaust gas from large diesel engines depends on the type of fuel, the engine adjustment and design. •sac volume is the void space in the fuel valve downstream of the closing face •Reduced sac volume in the fuel valves has greatly reduced HC emissions.
  • 49. Alfa Lubricator System • A high-pressure electronically controlled lubricator that injects the cylinder lube oil into the cylinder at the exact position and time -> optimal effect is not always possible with the conventional lubricators • A parallel line is followed by the SIP (Swirl Injection Principle) lubricator, where the oil is injected prior to piston passage, thereby having the oil distributed by the air swirl. • Use for marine engines and engines for power generation purposes, very low feed rates have been demonstrated, with oil consumption down to 0.5 g/bhph. • By applying low oil dosage -> emission is lowered + less cylinder oil is wasted in the engine- where it could end up in the system oil, resulting in increased TBN and viscosity.
  • 50. Particulate Emission - Function of Potential Lub. Oil Consumption
  • 51. PM Measure •The picture of the filters used for dilution tunnel PM measurements taken before and after the scrubber at 75% load and 15% recirculation.
  • 52. Scavenge Air Factor •NOx reduction by means of SCR can only take place in the mentioned temperature window •Because if the temperature is too high, NH3 will burn rather than react with the NO/NO2. • At too low a temperature, the reaction rate would be too low, and •condensation of ammonium sulphates would destroy the catalyst
  • 53. SCR Installation Block Diagram •To reduce the NOx level by up to 98%, it is necessary to make use of the SCR (Selective Catalytic Reduction) technique. •With this method, the exhaust gas is mixed with ammonia NH3 or UREA (as NH3 carrier) before passing through a layer of a special catalyst at a temperature between 300 and 400C, whereby NOx is reduced to N2 and H2O. •The reactions are, in principle, the following: •4NO + 4NH3 + O2 → 4N2 + 6H2O •6NO2 + 8NH3 → 7N2 +
  • 54. SCR System Layout The amount of NH3 injected into the exhaust gas is controlled by a process computer dosing the NH3 in proportion to the NOx produced by the engine as a function of the engine load.
  • 56. SCR Electronic System •The flexibility of the electronically controlled engine can improve the emission control and operation of NOX reduction by means of water emulsion •When operating with an SCR catalyst, it is difficult to maintain the engine dynamics and the turbocharger stability at transient engine loads. •With the electronically controlled engine, a faster load-up by early exhaust valve opening and late injection timing is possible •Also, modulated exhaust valve timing stabilizes the turbocharger.
  • 58. Exhaust Gas Recovery (EGR) •EGR system has two water injection stages, with a simple water separator unit after both. •The first water injection stage involves humidification with salt water in order to ensure that there is no freshwater consumption in the second freshwater injection stage. •The outlet temperature of the first stage is approximately 100oC. •This stage has a single multi-nozzle injector.
  • 59. EGR with Water Treatment •This system is connected to the exhaust system in the same way as the simple EGR system •But the EGR line is routed to a .bubble-bath. scrubber from the which cleans and cools the exhaust gas. •The water loop in the scrubber system is cooled and monitored in a Water Treatment Skid with a filter and settling system, cleaning the used sea water.
  • 60. EGR and HAM System •The NOx production only takes place at very high temperatures (2,200°K and above), and it increases exponentially with the temperature. •The EGR method is based on a reduction of the oxygen content in the cylinder charge, and the HAM method is partly based on reducing the oxygen content of the cylinder charge and partly on increasing the heat capacity of the cylinder charge by the addition of water vapor
  • 61. Typical Pressurized Fuel Oil System with Homogenizer
  • 62. Humid Air Motor (HAM) •The addition of water to the HFO by homogenisation increases the viscosity •To keep the viscosity at the engine inlet at 10-15 cSt, max. 20 cSt, It is necessary to raise the temperature to more than the 150oC which is standard today (max. 170oC at 50% water) raise the fuel oil loop
  • 63. NOx Reduction from Emulsification •10% NOx reduction for each 10% water added •The water amounts refer to the injected amount of fuel oil
  • 64. EGR •At increased recirculation amounts, the HC and PM emissions are reduced corresponding to the reduction of the exhaust gas flow from the engine.
  • 65. Annual Operating Cost for LNG Carrier
  • 66. Case Study – Retrofit Installation of SCR Norwegian owned LPG-carrier Navion Dania, equipped with a 6S35MC main engine.
  • 67. Emission Assessment Quantification • Emissions calculation- using emission factors and activity data by mode of operation: • Emissions = Σ[(P x LF x EF)Main+ (P x LF x EF )Auxiliary] Modex TMode • P = registered main or auxiliary engine power, kW; • LF = load factor relative to registered power; • EF = emission factor by mode, g/kWh; • Tmode= time in mode, hours.
  • 68. Emission Factors • NOx- 12- 17g/kwh • CO- 1.6g/kwh • HC-0.5g/kwh • Cox-660g/kwh • Sox- 4.2g/kwh
  • 69. Environmental Risk •Since options are many and money will be involve, it is better to use IMO FSA HAZOP method for various decision on alternatives. •RISK = Hazard (Toxicity) x Exposure (an •estimate on probability that certain toxicity will be realized) For example: •􀁺 Use of X rays has a high AQ (High benefit, low risk) •􀁺 Use of Thalidomide has a small AQ (Small benefit,high risk) •􀁺 Nuclear war has a very small AQ (No benefit,very high risk)
  • 70. Risk Management • Risk management is the evaluation of • alternative risk reduction measures and the implementation of those that appear cost effective • It must be remember that : • Zero discharge = zero risk, but -the challenge is to bring the risk to acceptable level -at the same time, derive the max. benefit
  • 71. Cost Benefit Analysis (CBA) Cost Benefit Analysis: Maximizing BOTH -> economic return +environmental return + environmental protection
  • 72. Energy Source and Fuel Quality • The quests for an efficient fuel friendly to the environment have been recognized in maritime industry for a long time in maritime industry. • Improvements of gasoline and diesel by chemical reformulation that can lead to decrease in ozone-forming pollutants and carbon monoxide emissions • Inconvenience posed by these reformulation chemicals are performance problems: -cold-start ability -smooth operation -avoidance of vapor lock are disadvantages of using reformulated fuels. • Global trend in de-Carbonization of the energy system follow the following path: COAL > OIL> NATURAL GAS > HYDROGEN
  • 73. Potential of Natural Gas • The drive towards environmentally friendlier fuels points next at Natural Gas (NG) • The infrastructures to support that trend are being pre-positioned by corporate mechanisms and governmental bodies worldwide. • NG is cheap and its reserve is plentiful. • Natural Gas as fuel is becoming more and more established in Urban Transport and Power Generation sectors. • Its use will also take aggressive approach for all coastal vessel including ferries due new regulations. • Internationally its operational record and GHG gas score is rated as GOOD.
  • 74. Impact of Using New Fuel • That technology will transfer sympathetically to the marine industry via availability of engines, systems and technical assistance. • Marine craft operation in inland water operation as well as deep sea will require fuel supplied in bulk rendering the NG distribution viable • The use of an alternative fuel for vessel propulsion will leads to a design review of: - Power plant - associated fuel system - propulsion train; • + Effectively reshaping areas such as Machinery Arrangement, Hull Form, Compartment, Cargo Deck, Payloads, Superstructure, Interior Layouts, Escape &
  • 75. Environmental Technology For Emission Reduction • Alternative energy • Alternative fuel and dual fuel engines • Infusion of water mist with fuel and subsequent gas scrubbing units for slow speed engines • Additional firing chamber • Potential for gas turbine complex cycle • Potential for turbocharger diesel engine • Compound cycle with : gasified fuel, external compressor, combustion with pure oxygen • Exhaust after treatment for medium speed engines
  • 78. Round trip emission for 135,000 cubic meter LNG ship
  • 79. Option for LNG Propulsion System
  • 80. Option for LNG Propulsion System
  • 82. Comparison of Propulsion Plants efficiency and System Size
  • 83. Environmental Technology Update • Lloyd performed a research on exhaust gas emission assessment • Roll-Royce built Allen 5000 Series engine with electronics fuel injectors that control NOx • Mak engine has developed a new MDS engine with reduction in NOX without fuel penalty
  • 84. Exhaust gas Monitoring Equipments Come with new technology must be monitoring system – some of the available monitoring systems are : • Electrochemical cells • Chemiluminescent analyzer • Paramagnetic analyzer • Analysis of optical radiation Monitoring mode could be : -In situ - with simultaneous data analysis -Extractive systems- data analysis transfer to other location for processing
  • 85. Sustainability and Maritime MARITIME INDUSTRY IN NEW WORLD CHARACTERIZED BY SUSTAINABILITY CAPACITY BUILDING , EFFICIENCY OPTIMIZATION OF DEVELOPMENT , PRACTICE AND OPERATIONS THAT MEETS THE NEEDS OF THE PRESENT GENERATION WITHOUT COMPROMISSING THE ABILITY OF FUTURE GENERATION TO MEET THEIR NEED
  • 86. Advantages of Maintaining • Quality Good environmental quality is essential for sustaining coastal and marine ecosystems20, commercial, recreational fisheries, and economic growth in coastal communities. • It is also an important means of providing natural protection against rising sea levels and storm damage. • The health of coastal and marine ecosystems is affected by water quality, and in turn, water quality is dependent upon ecosystem health. If one is impaired, the other is threatened. • Despite their value and the programs designed to protect them, many coastal waters are being degraded at an alarming rate in addition to this. ** Ship that meet environmental requirement will be able to meet requirement of “GREEN PASSPORT” concept for ships
  • 87. Advantages of Maintaining Quality Other advantages are : • Compliance with all applicable environmental laws • and regulations; • No significant adverse environmental impacts; • Wastes treated or destroyed on board to the extent practicable; • No inappropriate dependence on shore facilities for waste off-load and disposal; • Minimal energy consumption; • Minimal logistical costs for waste management; and • Minimal use of hazardous materials. **Reducing emission will make ship to meet future local and international emission regulation.
  • 88. LOCAL MARINE EMISSION RULES • Today, only a few countries have ratified the IMO-regulations • Countries like Sweden, Hamburg and Norway have introduced reductions in harbour fees for ships operating on low sulphur fuel and with a low NOx level, in order to encourage low pollution applications. • There is potential for more local rules like these coming up, depending effectiveness of IMO enforcement regulationEuropean Union • The EU has adopted the IMO annex VI Marpol convention including expanding the low-sulphur restricted area the French coast in the English Channel, and the North Sea. • Sweden- The Swedish authorities decided to aim at a 75% emission reduction by the beginning of 2000. In order to reach this goal, the authorities apply financial incentives in the form of environmentally differentiated fairway and port due – To stimulate ship's to take measures which would benefit the environment, such as using catalytic converters or making other technical improvements that decrease the nitrogen oxide emissions and promote the use of low-sulphur bunker fuel.. • Norway -The Norwegian Maritime Directorate issues guidelines on emission limits. The limits do not apply to all ship types and are based on a calculation of the total emission load factors from NOX, SOX, the type of fuel, and the use of redundant machinery. The higher the emission factor, the better the protection of the environment, and the less is to be paid in tonnage tax by Norwegian owners and operators. This rule became effective on 28 November 2000, and applies to ships above 1000 net register tons.
  • 89. The future Towards Clean Ship Operation • The development of new measuring equipment for emission control will continue in the coming years, and especially techniques like HAM and EGR • The concern of local authorities will change from focusing on NOx and SOx to include also smoke, in particular. • The IMO Annex VI unconditional ratification for NOx IN 2003 and the recent inclusion of SOx is sign for more environmental restriction in future • Local rules that encourage the use of emission cutting means, such as SCR reactors, through harbour fee reductions will become more dominant than today. • SCR units are preferably installed during the construction of the vessel, however, retrofitting is has been successfully practiced • The challenge to ship-owners will increase as vessels are required to have, or be prepared for, emission control equipment. • The sulphur content in fuel will be reduced, and vessel tank systems have to be prepared for dual fuel and dual cylinder lube oil systems. • In some areas, the operating profile of the ship will have to be adapted to local rules for reduced smoke emission.
  • 90. The Future Towards Clean Ship Operation • Land based air pollution regulation is a foundation for future legislatures in marine industry • Fossil fuel is considered the single ;largest contributor to emission Apart from Nox , others like CO,HC, particulate matter , Cox, smoke emission are likely to attract new regulations • To facilitate adaptation to emission regulations, operators, officers, engine builders, yards and ship-owners must have view to achieving the global target of a cleaner planet. • The latest generation of electronically controlled engines are an integral part of that policy.
  • 91. • "... [M]an’s fingerprint is found everywhere in the oceans. Chemical contamination and litter can be observed from the poles to the tropics and from beaches to abyssal depths...But conditions in the marine environment vary widely. The open sea is still relatively clean...In contrast to the open ocean, the margins of the sea are affected by man almost everywhere, and encroachment on coastal areas continues worldwide...If unchecked, this trend will lead to global deterioration in the quality and productivity of the marine environment." The State of the Marine Environment, 1989;Group of Experts on the Scientific Aspects of Marine Poll
  • 92. Other Environmental Technology Update • Ozone safe substances- 200-Ton Air- conditioning Plant Conversion Kit -The CG- 47and DDG-51 plants have been successfully converted to the ozone-friendly refrigerant HFC- 236fa conversion kit has been established by NRL • Solid waste - Solid-Waste Pulpers -The pulper (especially the large pulper) is the machine into which you dump tremendous quantities of paper, cardboard, or food waste. The waste mixes with seawater to form slurry, which is then discharged overboard. • Studies show an immediate 100,000-to-1 dilution when discharged into the wake of a ship. Ships equipped with a pulper can dispose of their paper, cardboard, and food waste just about anywhere and at anytime—at sea including MARPOL areas. • Liquid waste - OWS and Bilge water Polishers: Many bilge cleaners the Navy uses today contain long-lasting emulsifying agents, which produce stable oil-in-water emulsions that shipboard OWSs cannot effectively process.
  • 93.
  • 94. Recent Development in Coalition Control Work A number of promising developments that exist today are: • Kutsuro Kijima showed a modeling approach that permitted analysis of passing situations that would help set procedural standards for safe passing. • IanDand reported on the development of models for ship squat that have shown very good accuracy over the years. • Larry Daggett described the advent of dual frequency DGPS receivers and their role in gathering full-scale ship trial data. In addition to the excellent horizontal accuracy of the normal DGPS receiver, these receivers provide vertical location with an accuracy measured in centimeters.
  • 95. Measure for Ship Design for Safety and Environmental Protection IMO approved interim guidelines for estimating the maneuverability: • Rudder size and effectiveness, • Ability to transit at slow forward speed, • Propulsion and propeller characteristics, • Number of available engine reversals, • Adequate horsepower for control, • Extra reserve rudder angle needed to allow for ship crabbing from wind • forces or moored ship suction, • Visibility from bridge and bridge arrangement, • Hull form squat (trim and sink age) characteristics, • effect of bank forces on moorings and passing ships, • Air draft, Emergency anchoring ability, • Amount of tow line leads and line access.
  • 96. General Best Practice for Power Plants • General conservation practice for machineries are : • Fan lubrication • Pumps lubrications • Compressors lubrications • Repair steam and compress air leaks • Insulate bare steam lines • Inspect and repair steam traps increase condensate return • Minimize boiler blow down • Maintain and inspect temperature measuring devices • Maintain and inspect pressure measuring devices
  • 97. Best Practice for Operation of Machineries • Recover energy from hot gases • Reduce energy from hot liquid • Reuse hot wash water • Add effects to existing evaporators • Use liquefied gases as refrigerants • Recompress vapor for low pressure steam • Generate low pressure steam from flash operation • Use waste heat for absorption to reduce heat loss
  • 98. Management Responsibility • Maintain air- conditioner efficiency and reduce heated and cooled space • Maintain boiler efficiency • Use nature ventilation whenever and wherever possible, reduce air infiltration and seal leaks in pipes and ducts • Raise office temperatures in summer • Lower office temperature in winter • Use shading efficiently • Close windows and other air leaks • Do not use light necessarily • Turn off office equipment that is not use
  • 99. Area of Concentration for Domestic Utilities • Cooking • Heating • Hot water • Cooking • Lighting • New equipment application
  • 100. Personal Responsibility • Buy energy efficient equipments • Use well tuned engine for gain in efficiency and safety • Use natural ventilation wherever it is possible • Use natural ventilation in dwelling place • Avoid unnecessary trips • Do not waste food • Do not overeat • Make conscious effort to conduct your life in an energy efficient basis