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Non-Ferrous Alloys
ME-02 – Material Science & Metallurgy
150010119075 – Pinkal Patel
150010119078 – Ronak Patel
150010119081 – Yash Patel
Guided by: Prof. D. J. Darji
Non-Ferrous Alloys
• As the name suggests, the material which do not contain
iron as major element are known as Non - Ferrous
materials.
1.Aluminium
2.Copper
3.Tin
4.Lead
5.Magnesium
6.Zinc
7.Titanium
• And alloys of these metals.
Aluminium & aluminium
alloys
Pure Al Al-alloys Powder aluminium
Deformable Cast alloys
alloys
Heat- Non heat- Heat- Non heat-
treatable treatable treatable treatable
Partial
solubility
No
solubility
Partial
solubility
No
solubility
Aluminium alloys
Solubility
1) Al-Cu-Mg-alloys (duraluminium) Cu → 5,7%
2) Al-Cu-Mg-Si-alloys (forgable) Mg → 14,9%
3) Al-Mg-Si-alloys (corrosion resistance)
4) Al-Zn-Mg-Cu-alloys (high strength)
5) Al-Cu-Mg-Ni-Fe-alloys (heat resistance)
Rm → 500 N/mm2
; Rp0,2 → 390 N/mm2
; A → 25%
Copper and copper alloys
Pure Cu Cu-alloys
Brasses Bronzes Cupronickels
Deformable Cast Deformable Cast
alloys alloys alloys alloys
• Moderate strength in the pure
state
• Malleable and ductile
• Very good electrical and thermal
conductor
• Good corrosion resistance
• Alloys with Zinc to give brass
• Alloys with Tin and others to
make bronze
Copper alloys
Cu-Ni alloys (→ 50% Ni)
- permanent CTE
(constantan) – 45% Ni
- corrosion resistant
(Ni+Fe+Mn) – 30% Ni
Cu with other elements - bronzes
- Cu-Sn (tin bronzes)
- Cu-Sn-P (phosphor bronzes)
- Cu-Pb (lead bronzes)
- Cu-Al (aluminium bronzes)
Cu - 25% Ni
(coin melhior, cupronickel)
Cu - 10-20% Ni + 20-35% Zn
(new silver, alpaca)
-Cu-Si (silicon bronzes)
-Cu-Be (beryllium bronzes)
Lead and lead alloys
• High Density
• Corrosion Resistant
• Malleable, but not ductile
• Very soft and weak
Magnesium and magnesium
alloys
Pure Mg
Tm – 649 °C
Density – 1740 kg/m3
(lightest among the engineering materials)
Mg-alloys
- Mg – Mn (up to 2,5 %)
- Mg – Al – Zn (up to 10 % Al, 5 % Zn)
Heat treatment of Mg-alloys
Similar to Al-alloys
Quenching + age hardening (NA, AA → MgZn2, Mg4Al3 jt) → Rm ↑ 20
… 30 %
Magnesium alloys
Designation
• deformable (ex MgMn2)
• cast alloys (ex designation MCMgAl8 / material No. MC21110)
Deformable Mg-alloys
Mg cast alloys (EN173)
Designation Rm Rp0,2
N/mm
2
A
%
Applications
MgMn2
MgAl8Zn
200 145
310 215
15
6
Corrosion resistant, weldable
cold formable; conteiners, car ,
aircraft and machine
manufacturing
MCMgAl8Zn1
MCMgAl6
MCMgAl4Si
240 90
190-250 120-150
200-250 120-150
8
4-14
3-12
Good castability.
Dynamically loadable. Car
and aircraft manufacturing.
Zinc and zinc alloys
Pure Zn
Tm – 419 °C
Density – 7140 kg/m3
Good corrosion resistance
Zn- alloys ____________________________________
Zn – Al Precision casting material
Zn – Al – Cu Bearing alloy material
Designation Material No.
ex ZnAl8Cu1 ZP0810
Z – Zn-alloy
P – casting
first two numbers – Al%, 3.─ Cu%, 4.–T- rest
• No structural engineering uses in pure state
• Used as sacrificial anodes to protect steel.
• Used as an alloy with copper to produce brass
• Used to corrosion coat steel by:
• Galvanising or
• Plating
Zinc cast alloys
Designation Rm
N/mm
2
Rpo,2
N/mm
2
A
%
HB Application
ZnAl4
(ZP3)
280 200 10 83 Excellent castability,
ZnAl4Cu1
(ZP5)
330 250 5 92 machinability;
ZnAl8Cu1
(ZP8)
370 220 8 100 Universal applications:
ZnAl11Cu1
(ZP12)
400 300 5 100 deep-draw and blow
molds for plastics
ZnAl27Cu2
(ZP27)
425 300 2,5 120
Titanium and titanium alloys
Pure Ti
Tm – 1660 °C
Density – 4540 kg/m3
Very active to O, C, N → 2x hardnes increase
Ti-alloys, classification
Ti – Al – alloys (4…6 % Al) – α-alloys
Ti – Al – Cr, V, Cu, Mo - alloys – α + β-alloys
Ti – Al – Mo, Cr, Zr - alloys – β-alloys
Heat treatment of Tialloys
Heating up to β-area (850…950 °C) and cooling → martensitic
transformation.
Ageing (450…600 °C) – max effect by β-stabilisators
(Cr, Mn, Fe, Ni, Cu, Si)
Additional heat treatment – nitriding (750…900 HV)
Titanium alloys
Designation HB Rm
N/mm
2
Rpo,2
N/mm
2
A
%
Applications
Ti 1…3 120-
170
290-
590
180-
320
30-
18
Weldable,
machinable and
cold formable.
Ti1Pd,
Ti2 Pd
120-
150
290-
540
180-
250
30-
22
Corrosion resistant
light constructions.
TiAl6V4 310 900-
920
830-
870
8 Machine elements
in medicine, food,
ZnAL11Cu1
(ZP12)
350 ≥ 1050 1050 9 chemical and
aircraft industry.
Advantages:
• highest specific strength
• good formability
Disadvantages:
• need for a protective atmosphere at HT (Ar)
• problematically casted (reacting with ladle material, ZrO2 must be used)
References
• www.wikipedia.org
• www.altonmaterials.com
• Material Science and Engineering by Callister

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Non ferrous alloys.ppt

  • 1. Non-Ferrous Alloys ME-02 – Material Science & Metallurgy 150010119075 – Pinkal Patel 150010119078 – Ronak Patel 150010119081 – Yash Patel Guided by: Prof. D. J. Darji
  • 2. Non-Ferrous Alloys • As the name suggests, the material which do not contain iron as major element are known as Non - Ferrous materials. 1.Aluminium 2.Copper 3.Tin 4.Lead 5.Magnesium 6.Zinc 7.Titanium • And alloys of these metals.
  • 3. Aluminium & aluminium alloys Pure Al Al-alloys Powder aluminium Deformable Cast alloys alloys Heat- Non heat- Heat- Non heat- treatable treatable treatable treatable Partial solubility No solubility Partial solubility No solubility
  • 4. Aluminium alloys Solubility 1) Al-Cu-Mg-alloys (duraluminium) Cu → 5,7% 2) Al-Cu-Mg-Si-alloys (forgable) Mg → 14,9% 3) Al-Mg-Si-alloys (corrosion resistance) 4) Al-Zn-Mg-Cu-alloys (high strength) 5) Al-Cu-Mg-Ni-Fe-alloys (heat resistance) Rm → 500 N/mm2 ; Rp0,2 → 390 N/mm2 ; A → 25%
  • 5. Copper and copper alloys Pure Cu Cu-alloys Brasses Bronzes Cupronickels Deformable Cast Deformable Cast alloys alloys alloys alloys • Moderate strength in the pure state • Malleable and ductile • Very good electrical and thermal conductor • Good corrosion resistance • Alloys with Zinc to give brass • Alloys with Tin and others to make bronze
  • 6. Copper alloys Cu-Ni alloys (→ 50% Ni) - permanent CTE (constantan) – 45% Ni - corrosion resistant (Ni+Fe+Mn) – 30% Ni Cu with other elements - bronzes - Cu-Sn (tin bronzes) - Cu-Sn-P (phosphor bronzes) - Cu-Pb (lead bronzes) - Cu-Al (aluminium bronzes) Cu - 25% Ni (coin melhior, cupronickel) Cu - 10-20% Ni + 20-35% Zn (new silver, alpaca) -Cu-Si (silicon bronzes) -Cu-Be (beryllium bronzes)
  • 7. Lead and lead alloys • High Density • Corrosion Resistant • Malleable, but not ductile • Very soft and weak
  • 8. Magnesium and magnesium alloys Pure Mg Tm – 649 °C Density – 1740 kg/m3 (lightest among the engineering materials) Mg-alloys - Mg – Mn (up to 2,5 %) - Mg – Al – Zn (up to 10 % Al, 5 % Zn) Heat treatment of Mg-alloys Similar to Al-alloys Quenching + age hardening (NA, AA → MgZn2, Mg4Al3 jt) → Rm ↑ 20 … 30 %
  • 9. Magnesium alloys Designation • deformable (ex MgMn2) • cast alloys (ex designation MCMgAl8 / material No. MC21110) Deformable Mg-alloys Mg cast alloys (EN173) Designation Rm Rp0,2 N/mm 2 A % Applications MgMn2 MgAl8Zn 200 145 310 215 15 6 Corrosion resistant, weldable cold formable; conteiners, car , aircraft and machine manufacturing MCMgAl8Zn1 MCMgAl6 MCMgAl4Si 240 90 190-250 120-150 200-250 120-150 8 4-14 3-12 Good castability. Dynamically loadable. Car and aircraft manufacturing.
  • 10. Zinc and zinc alloys Pure Zn Tm – 419 °C Density – 7140 kg/m3 Good corrosion resistance Zn- alloys ____________________________________ Zn – Al Precision casting material Zn – Al – Cu Bearing alloy material Designation Material No. ex ZnAl8Cu1 ZP0810 Z – Zn-alloy P – casting first two numbers – Al%, 3.─ Cu%, 4.–T- rest • No structural engineering uses in pure state • Used as sacrificial anodes to protect steel. • Used as an alloy with copper to produce brass • Used to corrosion coat steel by: • Galvanising or • Plating
  • 11. Zinc cast alloys Designation Rm N/mm 2 Rpo,2 N/mm 2 A % HB Application ZnAl4 (ZP3) 280 200 10 83 Excellent castability, ZnAl4Cu1 (ZP5) 330 250 5 92 machinability; ZnAl8Cu1 (ZP8) 370 220 8 100 Universal applications: ZnAl11Cu1 (ZP12) 400 300 5 100 deep-draw and blow molds for plastics ZnAl27Cu2 (ZP27) 425 300 2,5 120
  • 12. Titanium and titanium alloys Pure Ti Tm – 1660 °C Density – 4540 kg/m3 Very active to O, C, N → 2x hardnes increase Ti-alloys, classification Ti – Al – alloys (4…6 % Al) – α-alloys Ti – Al – Cr, V, Cu, Mo - alloys – α + β-alloys Ti – Al – Mo, Cr, Zr - alloys – β-alloys Heat treatment of Tialloys Heating up to β-area (850…950 °C) and cooling → martensitic transformation. Ageing (450…600 °C) – max effect by β-stabilisators (Cr, Mn, Fe, Ni, Cu, Si) Additional heat treatment – nitriding (750…900 HV)
  • 13. Titanium alloys Designation HB Rm N/mm 2 Rpo,2 N/mm 2 A % Applications Ti 1…3 120- 170 290- 590 180- 320 30- 18 Weldable, machinable and cold formable. Ti1Pd, Ti2 Pd 120- 150 290- 540 180- 250 30- 22 Corrosion resistant light constructions. TiAl6V4 310 900- 920 830- 870 8 Machine elements in medicine, food, ZnAL11Cu1 (ZP12) 350 ≥ 1050 1050 9 chemical and aircraft industry. Advantages: • highest specific strength • good formability Disadvantages: • need for a protective atmosphere at HT (Ar) • problematically casted (reacting with ladle material, ZrO2 must be used)
  • 14. References • www.wikipedia.org • www.altonmaterials.com • Material Science and Engineering by Callister