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By: SALONI GOYAL
What are
these??
 Nanoporous materials consist of a
regular organic or inorganic framework supporting a regular,
porous structure.
 The size of the pores is generally 100 nm or smaller.
 Most nanoporous materials can be classified as:
1. bulk materials
2. membranes
 Activated carbon and zeolites are two examples of bulk
nanoporous materials
 cell membranes can be thought of as nanoporous membranes.
Activated carbon
(bulk nanoporous material)
(membrane nanoporous material)
 A porous medium or a porous material is a material
containing pores (voids).
 The skeletal portion of the material is often called the
"matrix" or "frame".
 The pores are typically filled with a fluid (liquid or gas).
There are many natural nanoporous materials, but artificial
materials can also be manufactured.
 One method of doing so is to combine polymers with
different melting points, so that upon heating one polymer
degrades.
 A nanoporous material with consistently sized pores has the
property of letting only certain substances pass through,
while blocking others.
 Microporous materials: <2 nm
 Mesoporous materials: 2–50 nm
 Macroporous materials: >50 nm
 Examples of microporous materials
include zeolites and metal-organic frameworks
(metal ions or clusters coordinated to organic ligands to form
one-, two-, or three-dimensional structures)
 in lab often used to facilitate contaminant-free exchange of
gases. Mold spores, bacteria, and other airborne contaminants
will become trapped, while allowing gases to pass through the
material. This allows for a sterile environment in the contained
area.
 Microporous adhesive tape(surgical tape) was introduced in 1959
with the trade name Micropore. It can be used to hold gauze
padding over small wounds, usually as a temporary measure until
a suitable dressing is applied.
 Microporous tape is used by some professional extreme yo-
yoers to wrap around their fingers and prevent string burn or
irritation.
 Rock climbers use microporous tape to wrap their hands in
'tape gloves', a means of protecting the skin from rock
abrasion.
 Microporous tape is also used by some film and TV sound
recordists to affix small radio microphones to actors' skin.
 Microporous material is also used as high performance
insulation material used from home applications up to metal
furnaces requiring material that can withstand more than 1000
Celsius.
 Typical mesoporous materials include some kinds
of silica and alumina that have similarly-sized fine mesopores.
Mesoporous oxides
of niobium, tantalum, titanium, zirconium, cerium and tin have also
been reported.
 a mesoporous material can be disordered or ordered in a
mesostructure.
 Mesoporous silica is the polymeric form of silica formed by Tetraethyl
orthosilicate (which is a monomer unit)
1. catalysis (as greater pore size is offered), sorption (both
adsorption and absorption),
2. gas sensing,
3. ion exchange (exchange of ions between two electrolytes or
between an electrolyte solution and a complex),
4. optics (including its interactions with matter and the
construction of instruments that use or detect it),
5. Photovoltaics (conversion of light
into electricity using semiconducting materials like in solar
panels)
 pores of size more than 50 nm host preferential soil solution
flow and rapid transport of solutes and colloids.
 Macropores increase the hydraulic conductivity of soil,
allowing water to infiltrate and drain quickly.
 In soil, macropores are created by plant roots, soil
cracks, soil fauna, and by aggregation of soil particles
into peds (soil granular structure)
 Macropores may be defined differently in other contexts. For
example, in the context of porous solids (i.e., not porous
aggregations such as soil), colloid and surface chemists
define macropores as cavities that are larger than 50 nm.[2]
 Carbon dioxide scrubber (by using NaOH & LiOH which converts
CO2 into Na2CO3 & Li2CO3 resp.) is used for the absorption of
exhaust green house gases from industry Futher modifications can
be done in the material depending upon the pore size of CO2.
 Micro electronics, manufacturing, medicine, clean energy
and the environment have wide applications.
 Microporous zeolites and molecular sieve works as a
nanoscale catalyst and gas separation membranes.
 Biosensors, nano reactors, biological separation, controlled
drug delivery, solar cells, nanoporous and nanocrysalline
semiconductors, econonic removal and recovery of organic
vapours also have a use of nanoporous materials.
Nanoporous particles

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Nanoporous particles

  • 3.  Nanoporous materials consist of a regular organic or inorganic framework supporting a regular, porous structure.  The size of the pores is generally 100 nm or smaller.  Most nanoporous materials can be classified as: 1. bulk materials 2. membranes  Activated carbon and zeolites are two examples of bulk nanoporous materials  cell membranes can be thought of as nanoporous membranes.
  • 4. Activated carbon (bulk nanoporous material) (membrane nanoporous material)
  • 5.  A porous medium or a porous material is a material containing pores (voids).  The skeletal portion of the material is often called the "matrix" or "frame".  The pores are typically filled with a fluid (liquid or gas). There are many natural nanoporous materials, but artificial materials can also be manufactured.
  • 6.  One method of doing so is to combine polymers with different melting points, so that upon heating one polymer degrades.  A nanoporous material with consistently sized pores has the property of letting only certain substances pass through, while blocking others.
  • 7.  Microporous materials: <2 nm  Mesoporous materials: 2–50 nm  Macroporous materials: >50 nm
  • 8.  Examples of microporous materials include zeolites and metal-organic frameworks (metal ions or clusters coordinated to organic ligands to form one-, two-, or three-dimensional structures)
  • 9.  in lab often used to facilitate contaminant-free exchange of gases. Mold spores, bacteria, and other airborne contaminants will become trapped, while allowing gases to pass through the material. This allows for a sterile environment in the contained area.  Microporous adhesive tape(surgical tape) was introduced in 1959 with the trade name Micropore. It can be used to hold gauze padding over small wounds, usually as a temporary measure until a suitable dressing is applied.
  • 10.  Microporous tape is used by some professional extreme yo- yoers to wrap around their fingers and prevent string burn or irritation.  Rock climbers use microporous tape to wrap their hands in 'tape gloves', a means of protecting the skin from rock abrasion.  Microporous tape is also used by some film and TV sound recordists to affix small radio microphones to actors' skin.  Microporous material is also used as high performance insulation material used from home applications up to metal furnaces requiring material that can withstand more than 1000 Celsius.
  • 11.  Typical mesoporous materials include some kinds of silica and alumina that have similarly-sized fine mesopores. Mesoporous oxides of niobium, tantalum, titanium, zirconium, cerium and tin have also been reported.  a mesoporous material can be disordered or ordered in a mesostructure.  Mesoporous silica is the polymeric form of silica formed by Tetraethyl orthosilicate (which is a monomer unit)
  • 12. 1. catalysis (as greater pore size is offered), sorption (both adsorption and absorption), 2. gas sensing, 3. ion exchange (exchange of ions between two electrolytes or between an electrolyte solution and a complex), 4. optics (including its interactions with matter and the construction of instruments that use or detect it), 5. Photovoltaics (conversion of light into electricity using semiconducting materials like in solar panels)
  • 13.  pores of size more than 50 nm host preferential soil solution flow and rapid transport of solutes and colloids.  Macropores increase the hydraulic conductivity of soil, allowing water to infiltrate and drain quickly.  In soil, macropores are created by plant roots, soil cracks, soil fauna, and by aggregation of soil particles into peds (soil granular structure)  Macropores may be defined differently in other contexts. For example, in the context of porous solids (i.e., not porous aggregations such as soil), colloid and surface chemists define macropores as cavities that are larger than 50 nm.[2]
  • 14.  Carbon dioxide scrubber (by using NaOH & LiOH which converts CO2 into Na2CO3 & Li2CO3 resp.) is used for the absorption of exhaust green house gases from industry Futher modifications can be done in the material depending upon the pore size of CO2.  Micro electronics, manufacturing, medicine, clean energy and the environment have wide applications.  Microporous zeolites and molecular sieve works as a nanoscale catalyst and gas separation membranes.  Biosensors, nano reactors, biological separation, controlled drug delivery, solar cells, nanoporous and nanocrysalline semiconductors, econonic removal and recovery of organic vapours also have a use of nanoporous materials.