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UACJ
        Biomedical Sciences Institute




                 Etchant Acid

             Dra. Angela Arisbeth Avendaño Ortega

Dr. Alfredo Nevárez Rascón
On the 50’s
Dr. Michael G.
Buonocore studies’, it has
been creating a way to
get more retentive
enamel surfaces, in other
words: enamel etchant                                                     Pic. 1
acid technique                     http://www.urmc.rochester.edu/dentistry/about/history.cfm




                    It provides a strong junction
                    between resin and enamel.
Also called Orthophosphoric acid, is a flammable chemical
compund of formula H3PO4.

On its liquid form the phosphoric acid is transparent, colorless and
viscous. Is obtained by treating calcium phosphate rocks with
sulfuric acid, then filtering the resultant liquid to remove
the calcium sulfate.
The acid is useful in the laboratory
  because of its resistance to oxidation,
  reduction and evaporation , as
  glue for dentures.

It forms the basis of innovative procedures such as:

    • Resin bonded metal retainers
    • Porcelain laminate veneers
    • Holders of orthodontics (brackets)


    Also solves the problems arising from the resins such as filtering and
    marginal pigmentation .

    The bond strength of etched enamel :
     165 kg/cm² to 227 kg/cm² , depending on the resin.
Phosphoric acid concentration
among 30 to 37%

Objective: acts as demineralizing to
the enamel creating micro pores from
20 to 30 microns in depth which allow
greater adhesion of restorative
materials.


                     ((microretentions) in green,        Pic. 2
       blue compositeand yellow enamel prisms.      http://www.sdpt.net/OPERATORIADENTAL/grabadoaci
                                                    doesmalte.htm
1. Placed on the enamel phosphoric acid concentration of 30
   to 37%
2. Leave for 15 to 60 sec
3. Wash with water and air for 5 sec
4. Pressurized air dry for 5 sec
5. Placing liquid resin or adhesive based on BIS-GMA with a
   solvent such as triethylene glycol dimethacrylate (TEGDMA)
   and a solvent such as alcohol or acetone gives the liquid flow.
6. Harden for either polymerization systems.
Hydrophobic




                                                                                        Hydrophilic



      Pic. 3
http://www.deltadent.es/blog/2010/03/07/porque-duele-la-muela-clinica-dental-madrid/
• Etch enamel and dentin in one step, the first 15 seconds on the enamel and
then about another 15 sec dentin.
   (No more than this time)

•Wash thoroughly from 15 to 30 sec with water

•Dry with cotton or special sponge (Do not use air or alcohol)

•Place adhesive hydrophilic with solvent such as water, acetone or alcohol

•Volatilize with air insufflations for 5 sec

•Polymerize

•Place the composite



                         http://www.youtube.com/watch?v=5DnY3h9LbQw
Directions:
                                     To condition both the surfaces of the tooth enamel and
                                     the dentin prior to placing an adhesive restoration.

                                     To clean porcelain surfaces, metal or resin Para la limpieza
                                     de superficies de porcelana, metal or resin before the
                                     accession of any resin, sealant or adhesive cements.



 Pic. 4
http://dentala2z.co.uk/Pre10019/es


    Presentation: 10 mL Dropper
Product Benefits:
•Ideal viscosity
•Application via syringe
•37% phosphoric acid to give the best results in etching dentin
•2% benzalkonium chloride makes an antimicrobial etching
•Provides controlled depth of dental etching
•Does not dry and maintains its consistency
•Predictable dental etching
•No fillers or additives
                                                    Pic. 5
                                                                  http://dentala2z.co.uk/Pre10019/es


                                        Composition:
                                        •Phosphoric Acid
                                        •Purified Water and Thickening Agent
                                        •Methylene Blue as Dye
                                        •Benzalkonium Chloride
                                        •The operating instructions are included inside
                                        the product.
  Pic. 6
http://dentala2z.co.uk/Pre10019/es
http://icctdaryluz.blogspot.com/p/protocolo-de-resina.html
Pic. 7




                                                       Pic. 8
                                                     http://www.omniodonto.com.br/categoria1.html
Pic. 9

•Gel Etchant

•OptiBond Solo™ Plus
•OptiBond® FL
•OptiBond All-In-One™
•Vertise™ Flow

•3M ESPE
                        Pic. 10
• It is an acid that attacks and creates channels on glass or
  ceramics.
• It is highly toxic
• Create these channels in the glass-ceramic
  (Leucite, feldspar, lithium disilicate, no other)
  producing a mechanical retention similar to that makes the
  phosphoric on dental tissue, then add the silane which
  penetrates these canaliculi and which binds chemically to the
  glass, the resin is on the silane as part of resinous elements are
  used to apply ceramic restorations on dental tissue. The
  silane chemically bonded to the resin.
• Silanes aid the adhesion between organic and inorganic
  substances. As bi-functional molecules, radicals combine their
  silica with the silica in restorative materials, and their co-organic
  radicals polymerize with the organic matrix resin cements.
   They can also be ceramic or bondingprimers / Coupling
  agents.




                                   Pic. 11
 http://www.dentusonline.com/productos/detalle.php?id_pro=394
• Product                                                     http://www.ar.all.biz/g60549/
• Etchant Acid /Porcelain Fgm                                  Pic. 12


• Description
• Fondac Porcelain is a low viscosity gel containing 10% hydrofluoric
  acid etching of porcelain.

• Presentation:
• Pack containing: • A syringe with 2.5 ml. of product.

• Indications for use: It is suitable for etching dental porcelain surface with the
  aim of increasing their membership in restoration processes. The engraving is
  critical to have an optimal interaction between the resin cement and ceramic
  restoration, promoting retention and encouraging resistance to the restoration.
• Porcelain preparer – CLARBEN

• Hydrofluoric Acid – CLARBEN
The main advantages of etchant systems are:
• Demineralization and infiltration´s dentin quickly
• They are not as sensitive to different moisture conditions of
  dentin
• Hygienic application
• Consistent and stable composition
• Blue dye application for facilitation
The main disadvantages are:
• If not handled the right time, excessive demineralization occurs
• Irreversible mistake
• Expensive
¨Materiales Dentales¨, Barceló Santana, Federico Humberto

“Ciencia de los materiales dentales”, Philips

http://www.dentaflux.com/acido_fosforico_37.html

http://www.sdpt.net/OPERATORIADENTAL/grabadoacidoesmalte.htm

http://es.wikipedia.org/wiki/%C3%81cido_fosf%C3%B3rico

http://www.kerrdental.es/materialesrestauraciones/category/EtchingMaterialsAndA
dhesives

http://www.hispadent.es/Catalogo/2_cementos.pdf

http://dentala2z.co.uk/Pre10019/es
http://www.monografias.com/trabajos36/adhesion-dentina/adhesion-dentina2.shtml
http://scielo.isciii.es/scielo.php?pid=S021312852004000400004&script=sci_ar
ttext

http://www.ar.all.biz/g60549/

http://issuu.com/zone0/docs/oral_38_sin_curvas

http://www.odontologia-online.com/foros/propiedades-grabadoras-del-fluoruro-
t4791.html
UACJ Etchant Acid Technique

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UACJ Etchant Acid Technique

  • 1. UACJ Biomedical Sciences Institute Etchant Acid Dra. Angela Arisbeth Avendaño Ortega Dr. Alfredo Nevárez Rascón
  • 2. On the 50’s Dr. Michael G. Buonocore studies’, it has been creating a way to get more retentive enamel surfaces, in other words: enamel etchant Pic. 1 acid technique http://www.urmc.rochester.edu/dentistry/about/history.cfm It provides a strong junction between resin and enamel.
  • 3. Also called Orthophosphoric acid, is a flammable chemical compund of formula H3PO4. On its liquid form the phosphoric acid is transparent, colorless and viscous. Is obtained by treating calcium phosphate rocks with sulfuric acid, then filtering the resultant liquid to remove the calcium sulfate.
  • 4. The acid is useful in the laboratory because of its resistance to oxidation, reduction and evaporation , as glue for dentures. It forms the basis of innovative procedures such as: • Resin bonded metal retainers • Porcelain laminate veneers • Holders of orthodontics (brackets) Also solves the problems arising from the resins such as filtering and marginal pigmentation . The bond strength of etched enamel : 165 kg/cm² to 227 kg/cm² , depending on the resin.
  • 5. Phosphoric acid concentration among 30 to 37% Objective: acts as demineralizing to the enamel creating micro pores from 20 to 30 microns in depth which allow greater adhesion of restorative materials. ((microretentions) in green, Pic. 2 blue compositeand yellow enamel prisms. http://www.sdpt.net/OPERATORIADENTAL/grabadoaci doesmalte.htm
  • 6. 1. Placed on the enamel phosphoric acid concentration of 30 to 37% 2. Leave for 15 to 60 sec 3. Wash with water and air for 5 sec 4. Pressurized air dry for 5 sec 5. Placing liquid resin or adhesive based on BIS-GMA with a solvent such as triethylene glycol dimethacrylate (TEGDMA) and a solvent such as alcohol or acetone gives the liquid flow. 6. Harden for either polymerization systems.
  • 7. Hydrophobic Hydrophilic Pic. 3 http://www.deltadent.es/blog/2010/03/07/porque-duele-la-muela-clinica-dental-madrid/
  • 8. • Etch enamel and dentin in one step, the first 15 seconds on the enamel and then about another 15 sec dentin. (No more than this time) •Wash thoroughly from 15 to 30 sec with water •Dry with cotton or special sponge (Do not use air or alcohol) •Place adhesive hydrophilic with solvent such as water, acetone or alcohol •Volatilize with air insufflations for 5 sec •Polymerize •Place the composite http://www.youtube.com/watch?v=5DnY3h9LbQw
  • 9. Directions: To condition both the surfaces of the tooth enamel and the dentin prior to placing an adhesive restoration. To clean porcelain surfaces, metal or resin Para la limpieza de superficies de porcelana, metal or resin before the accession of any resin, sealant or adhesive cements. Pic. 4 http://dentala2z.co.uk/Pre10019/es Presentation: 10 mL Dropper
  • 10. Product Benefits: •Ideal viscosity •Application via syringe •37% phosphoric acid to give the best results in etching dentin •2% benzalkonium chloride makes an antimicrobial etching •Provides controlled depth of dental etching •Does not dry and maintains its consistency •Predictable dental etching •No fillers or additives Pic. 5 http://dentala2z.co.uk/Pre10019/es Composition: •Phosphoric Acid •Purified Water and Thickening Agent •Methylene Blue as Dye •Benzalkonium Chloride •The operating instructions are included inside the product. Pic. 6 http://dentala2z.co.uk/Pre10019/es
  • 11. http://icctdaryluz.blogspot.com/p/protocolo-de-resina.html Pic. 7 Pic. 8 http://www.omniodonto.com.br/categoria1.html
  • 12. Pic. 9 •Gel Etchant •OptiBond Solo™ Plus •OptiBond® FL •OptiBond All-In-One™ •Vertise™ Flow •3M ESPE Pic. 10
  • 13.
  • 14. • It is an acid that attacks and creates channels on glass or ceramics. • It is highly toxic • Create these channels in the glass-ceramic (Leucite, feldspar, lithium disilicate, no other) producing a mechanical retention similar to that makes the phosphoric on dental tissue, then add the silane which penetrates these canaliculi and which binds chemically to the glass, the resin is on the silane as part of resinous elements are used to apply ceramic restorations on dental tissue. The silane chemically bonded to the resin.
  • 15. • Silanes aid the adhesion between organic and inorganic substances. As bi-functional molecules, radicals combine their silica with the silica in restorative materials, and their co-organic radicals polymerize with the organic matrix resin cements. They can also be ceramic or bondingprimers / Coupling agents. Pic. 11 http://www.dentusonline.com/productos/detalle.php?id_pro=394
  • 16. • Product http://www.ar.all.biz/g60549/ • Etchant Acid /Porcelain Fgm Pic. 12 • Description • Fondac Porcelain is a low viscosity gel containing 10% hydrofluoric acid etching of porcelain. • Presentation: • Pack containing: • A syringe with 2.5 ml. of product. • Indications for use: It is suitable for etching dental porcelain surface with the aim of increasing their membership in restoration processes. The engraving is critical to have an optimal interaction between the resin cement and ceramic restoration, promoting retention and encouraging resistance to the restoration.
  • 17. • Porcelain preparer – CLARBEN • Hydrofluoric Acid – CLARBEN
  • 18. The main advantages of etchant systems are: • Demineralization and infiltration´s dentin quickly • They are not as sensitive to different moisture conditions of dentin • Hygienic application • Consistent and stable composition • Blue dye application for facilitation
  • 19. The main disadvantages are: • If not handled the right time, excessive demineralization occurs • Irreversible mistake • Expensive
  • 20. ¨Materiales Dentales¨, Barceló Santana, Federico Humberto “Ciencia de los materiales dentales”, Philips http://www.dentaflux.com/acido_fosforico_37.html http://www.sdpt.net/OPERATORIADENTAL/grabadoacidoesmalte.htm http://es.wikipedia.org/wiki/%C3%81cido_fosf%C3%B3rico http://www.kerrdental.es/materialesrestauraciones/category/EtchingMaterialsAndA dhesives http://www.hispadent.es/Catalogo/2_cementos.pdf http://dentala2z.co.uk/Pre10019/es http://www.monografias.com/trabajos36/adhesion-dentina/adhesion-dentina2.shtml