Advanced cleaning product formulations Vol. 4

ADVANCED CLEANING
PRODUCT FORMULATIONS

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ADVANCED
CLEANING
PRODUCT
FORMULATIONS
Volume 4
Ernest W. Flick
NOYES PUBLICATIONS
Westwood, New JOrsey, U.S.A.

Copyright 0 19% by Ernest W. Flick
No part of this book may be reproduced or utilized in
any form or by any means. electronic or mechanical,
including photocopying. recording or by any informa-
tion storage and retrieval system. without permission
in writing from the Publisher.
Library of Congress Catalog Cud Number: 89-30274
Printed in the United States
ISBN 0-8155-1396-8
Published in the United States of America by
Noyes Publications
369 Fairview Avenue
Weshvood, New Jersey 07675
10 9 8 7 6 5 4 3 2 1
Library of Congress Cataloging-in-Publication Data
(Revised for vo1.4)
Flick, Ernest W.
Advanced cleaning produd formulations
Includes bibliographid references and index.
1.Cleaning compounds. I. Title
TP990.F56 1989 668'1 89-30274
ISBN 0-8155-1186-8 (v. 1)
ISBN 0-8155-1346-1 (v. 2)
ISBN 0-8155-1382-1 (v. 3)
ISBN 0-8155-1396-8 (v. 4)

To
Ernie and Jeanne
and
AIIp and Barbara
and
Chris and Rachel
V

This book (Volume 4) presents more than 435 up-to-date advanced cleaning
product formulations for household, industrial and automotive applications. It is
the result of information received fromnumerous industrial companies and other
organizations. The data represent selections made at no cost to, nor influence
from, the makers or distributors of these materials. Only the most recent
formulas have been included. All formulations are completely different than
those contained in Volumes 1, 2 and 3 published earlier.
Formulation in the cleaning product industry has gradually been undergoing
significant change during the past years. Raw materials costs have risen and
manufacturers have been reluctant to pass along these increases. Environmental
considerations have also played a part. By changing formulations to improve
cost/performance characteristics, manufacturers have been able to control costs
but still enhance performance. This book presents manufacturers' suggested
formulations which might meet new performance criteria.
The formulations in this book are divided into the following sections and
chapters, with the number of formulations indicated in ( ):
I. Household and Industrial Cleaners and Polishes
1. Bathroom Cleaners (26)
2. Dairy, Food and General Industrial Cleaners (15)
3. Degreasers (5)
4. Dishwashing Detergents (47)
5. General Purpose Cleaners (34)
6. Glass Cleaners/Polishes (25)
7. Hard Surface Cleaners (44)
8. Laundry Products (65)
9. Metal Cleaners and Polishes (22)
10. Oven, Grill and Hot Plate Cleaners (3)
11. Polishes, Coatings and Finishes (30)
12. Rinse Aids (4)
13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (32)
14. Miscellaneous (32)
vii
Preface

viii Preface
11. Transportation Cleaners and Polishes
15. Auto Cleaners and Polishes (14)
16. Car and Truck Wash Compounds (27)
17. Whitewall Tire Cleaners (4)
18. Miscellaneous (8)
Each formula is located in the chapter which is most applicable. The reader,
seeking a formula for a specific end use, should check each chapter which could
possibly apply. In addition to the above, there are two other sections which will
be helpful to the reader.
111. Achemical trademark section where each tradenamed raw material
included in the book is listed with a chemical description and the
supplier's name. The specifications which each raw material meets
are included, if applicable.
IV. Main office addresses of the suppliers of trademarked raw
materials.
Each formulation in the book lists the following information, as available, in the
manufacturer's own words:
0
Description of end use and most outstanding properties.
The percent by weight or volume of each raw material included in
the formula, rounded to a decimal figure.
Key properties of the formula, which are the features that the
source considers to be more outstanding than other formulations
of the same type.
The formula source, which is the company or organization that
supplied the formula. The secondary source may be the originating
company and/or the primary source's publication title, or both. A
formula number is included, if applicable.
0
The table of contents is organized in such a way as to serve as a subject index.
My fullest appreciation is expressed to the companies and organizations who
supplied the original starting formulations included in this book. I also thank the
suppliers of the raw materials included in these formulations, who furnished
information describing their trademarked raw materials.
Newburyport, Massachusetts
August 1996
Ernest W. Flick

NOTICE
To the best of our knowledge the information in this pub-
lication is accurate; however, the Publisher does not assume
any responsibility or liability for the accuracy or completeness
of, or consequences arising from, such information. This book
is intended for informational purposes only. Mention of trade
names or commercial products doesnot constitute endorsement
or recommendation for use by the Publisher. Final determ-
ination of the suitability of any information or product for use
contemplated by any user, and the manner of that use, is the
sole responsibility of the user. We recommend that anyone in-
tending to rely on any recommendation of materials or pro-
cedures mentioned in this publication should satisfy himself as
to such suitability, and that he can meet all applicable safety
and health standards.
X

1.
Contents and Subject Index
SECl'ION I
HOUSEHOLDAND INDU-
CLEANERS AND POLISHES
BATHROOM CLEANERS .............................. 2
Bathtub and Faucet Cleaner ............................ 3
Bathroom Cleaner ................................... 3
Toilet Bowl Cleaner ................................. 3
Tub and Tile Cleaner ................................ 3
Thick Toilet Bowl Cleaner ............................ 4
Foamable Acid Tile Cleaner ........................... 5
Liquid Toilet Bowl Cleaner ............................ 5
Solid Automatic Toilet Bowl Cleaner Formulation ........... 6
Acid Toilet Bowl Cleaner ............................. 6
Tub. Tile and Bathroom Cleaner ........................ 6
Tile. Porcelain and Bathroom Cleaner. Acid ................ 7
Hypochlorite Tub and Tile Cleaner and Mildew Stain
Remover ....................................... 7
Soap Scum RemoverICleaner ........................... 7
Toilet Cleaner
LiquidA ...................................... 8
Liquid B ...................................... 8
Clear Liquid Bowl Cleaner ............................ 4
Medium Viscosity-A ............................. 8
Medium Viscosity-B ............................. 8
Medium Viscosity-A ............................. 9
Medium Viscosity-B ............................. 9
Powder ....................................... 9
Powder-B ..................................... 9
Extruded-A ................................... 10
Extruded-B ................................... 10
Cast-A ...................................... 10
Cast-B ...................................... 10
Toilet Cleaning Block
xi

xii Contents and Subject Index
2. DAIRY. FOOD AND GENERAL INDUSTRIAL CLEANERS . . . 11
Acid Dilutable Concentrate ........................ 12
Low Cost Acid Dilutable Concentrate . . . . . . . . . . . . . . . . 12
Dairy Milkstone Remover
Dairy Pipeline Cleaner-High Alkaline Low Foam
Institutional Stainless Steel Cleaner ..................... 13
High Pressure Cleaner for Industrial Use . . . . . . . . . . . . . . . . . 14
Cleaner for Milking Equipment ........................ 14
Cleaner for Meat Plants ............................. 14
Meat Packaging Plant Cleaner Concentrate . . . . . . . . . . . . . . . . 15
Steam Cleaners
Light Duty .................................... 16
Hypochlorite Cleaner .............................. 13
Medium Duty .................................. 16
Heavy Duty (for Oily Soils) ....................... 16
General Purpose ................................ 16
Light Duty for Soft Metals ........................ 16
Compound .................................... 16
3. DEGREASERS ...................................... 17
d-Limonene Microemulsion Cleanermegreaser . . . . . . . . . . . . . 18
Concentrated d-Limonene Biodegradable Degreaser . . . . . . . . . 18
Solvent Degreasing ................................. 19
4. DISHWASHING DETERGENTS ......................... 20
Clear Liquid Dishwash .............................. 21
Non-Chlorinated Machine Dishwashing Compound. Liquid . . . . 21
Clear. Colorless Manual Dish Wash ..................... 21
Powder for Automatic Dishwashing Machines . . . . . . . . . . . . . . 23
Dishwashing Detergent
Medium Viscosity
Dish Washing Agent ................................ 22
Basis Marlon A-A ........................... 24
Basis Marlon A-B ........................... 24
Basis Marlon AS3-A ......................... 24
Basis Marlon AS3-B ......................... 24
Basis Marlon PS-A .......................... 25
Basis Marlon PS-B .......................... 25
Basis Marlon Compounds-A ..................... 25
Basis Marlon Compounds-B .................... 25
Powdered
Spray Mixing Process-A ...................... 26
Spray Mixing Process B ....................... 26
Phosphate-Free. Spray Mixing. Process A . . . . . . . . . . 26

Contents and Subject Index xiii
Phosphate.Free. Spray Mixing. Process B .......... 26
40% Solids-A .............................. 27
40% Solids-B .............................. 27
Hand Dishwashing Liquid ............................ 27
Dish Wash w/Amine Oxide/LABS/SLES ................. 28
Dish Wash w/Amine Oxide/LABS/ALES ................. 28
Dish Wash w/Amine Oxide/LABS ...................... 28
High-Performance Hand Dish Detergent ................. 29
Mild Liquid Hand Dish Detergent ...................... 29
Starting Formulations for Home Machine Dishwashing
Detergents
8.7% Phosphorous(A) ............................ 30
8.7% Phosphorous(l3) ............................ 30
Nonphosphate ................................. 30
Pilot Formula #LDL-010-01 ...................... 31
Pilot Formula #LDL-O15-01 ...................... 31
Premium Hand Dishwash ......................... 32
Economy Hand Dishwash ......................... 32
Liquid Hand Dish Detergent .......................... 33
Mechanical Dishwashing Detergent. Chlorinated ............ 34
Mechanical Dishwashing Detergent. Liquid ............... 34
Non-DDBSA Dishwashing Liquid ...................... 35
Starting Formulations for Commercial Machine
Light Duty Liquid Detergents
Dishwashing Detergents
Nonchlorine/Noncaustic .......................... 36
Noncaustic .................................... 36
ChlorineKaustic ................................ 36
5. GENERAL PURPOSE CLEANERS ....................... 37
Phosphate Free All Purpose Cleaner ..................... 38
Bathroom Tile Cleaner .............................. 38
All Purpose Cleaner ................................ 39
Hard-surface Cleaner ............................... 39
All-Purpose Cleaner
Cleaner-A .................................... 40
Cleaner-B .................................... 40
With Microbicidal Properties. Liquid-B ............... 40
All Purpose Cleaner ................................ 38
Liquid-A ..................................... 41
Liquid-B ..................................... 41
With Microbicidal Properties. Liquid-A ...............41

xiv Contents and Subject Index
Pasty-A ...................................... 42
With Soap. High Viscosity-A ...................... 42
With Soap. High Viscosity-B
Pasty-B ...................................... 42
...................... 42
D-Limonene Emulsifiable Concentrate . . . . . . . . . . . . . . . . . . . 43
D-Limonene All Purpose Cleaner ...................... 43
General Cleaners
Household .................................... 44
Alkaline Cleaner ............................... 44
Liquid Hand Cleaner ............................ 44
Germicidal Cleaner .............................. 44
High-Performance General Purpose Cleaner Concentrate . . . . . . 45
Heavy-Duty Cleaner Powder .......................... 45
Neutral All-Purpose Cleaner. with Pearlescence Effect
High Viscosity-A ............................... 46
High Viscosity-B ............................... 46
With Acetic Acid-A ............................. 46
With Acetic Acid-B ............................. 46
Non-Phosphate All Purpose Cleaner .................... 47
Oil Splitting General Purpose Cleaner ................... 47
Scouring Cleaner
Medium Viscosity-A ............................ 48
Medium Viscosity-B ............................ 48
Powder-A .................................... 48
Powder-B .................................... 48
All-Purpose Cleaner
6. GLASS CLEANERSD’OLISHES ......................... 49
For Application to Cloth .......................... 50
For Direct Application to Glass ..................... 51
Anti-Fogging. Anti-Static Glass Cleaner ................. 52
Ammoniated Glass Cleaner ........................... 52
Glass Cleaners
Ammonia ..................................... 53
Vinegar ...................................... 53
Antifog Composition
Glassware and Bottle Cleaners
Bottle Cleaner
Alkaline-Powder ............................ 54
Acid-Powder ............................... 54
Acid-Liquid ............................... 54
Highly Alkaline ............................. 54
Household Window Cleaner .......................... 55
Premium Household Window Cleaner ................... 55

Contents and Subject Index xv
Low VOC Antistat/Cleaner for Glass .................... 56
Anti-Fog Glass Cleaner ............................. 56
Glass Cleaner ..................................... 56
Traditional Consumer Glass Cleaner .................... 57
Consumer Acid Glass Cleaner ......................... 57
7. HARD SURFACE CLEANERS .......................... 58
Abrasive Cleaner-1 ................................ 59
Concentrated Liquid Household Hard-surface Cleaner ....... 60
All-Purpose Household Spray Cleaner ................... 60
Consumer Tile Cleaner .............................. 61
Industrial Strength Chlorine Cleaner ..................... 61
D-Limonene Hard-surface Cleaners .................... 62
d'limonene Spray Cleaner ............................ 63
d'limonene Cleaner Concentrate ....................... 63
General Purpose Hard Surface Cleaner ................... 64
Alkaline Hard Surface Cleaner ........................ 64
General Purpose Hard-surface Cleaners .................. 65
Unbuilt. High-Sudsing. Hard-surface Cleaner ............. 65
Hard Surface Cleaner ............................... 66
Non-Abrasive Cleanser .............................. 66
Hard Surface Cleaner ............................... 66
Floor Cleaner Products .............................. 68
Rug Cleaner ...................................... 68
Plastic. Vinyl and Leather Cleaner ...................... 68
Hard Surface Cleaners .............................. 69
Tub and Tile Cleaners ............................... 69
Counter Top/Wall Cleaners
AlIPurposeType ............................... 69
Ammoniated Type .............................. 69
Hard Surface Cleaner w/Amphoteric .................... 70
Hard Surface Cleaner Concentrate
w/d'Limonene ................................. 70
Alkaline All-Purpose Cleaner Concentrate ............. 71
All-Purpose Alkaline Cleaner for Sponge or Spray
Application ................................. 71
High-Performance. Hard Surface Cleaners ................ 72
Economical Pine Oil Hard-surface Cleaner ............... 72
Mild Abrasive Hard Surface Cleaner .................... 73
Non-Phosphate Household Hard-surface Cleaner ........... 74
Non-Phosphate Concentrated Household Hard-surface
Cleaner ....................................... 74

xvi Contents and Subject Index
Pine Oil Cleaner Concentrate .......................... 75
Liquid Super Concentrate ............................ 75
8. LAUNDRY PRODUCTS ............................... 76
Anionic/Nonionic Heavy-Duty Laundry Detergent . . . . . . . . . . 77
Nonionic/Amphoteric Heavy-Duty Laundry Liquid . . . . . . . . . . 78
Cold Water Detergent ............................... 79
Fine Fabric Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79
Process-A .................................... 80
P~OUXS-B. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80
Detergent for Fine Fabrics-1 .......................... 82
Detergent for Fine Fabrics-2 .......................... 82
Enzymatic Heavy-Duty Laundry Detergent
Non-Phosphate Laundry Powder ....................... 83
Fabric Pretreatment Spritz ............................ 84
Low VOC Pump Fabric Antistatic Spray
Laundry Pre-Spotter and Stain Remover
Detergent for Colored Fabrics. Powder. Spray Mixing
Detergent for Curtains
Manual-Wash Detergent. Foaming
. . . . . . . . . . . . . . . 83
. . . . . . . . . . . . . . . . . 84
. . . . . . . . . . . . . . . . . 84
Process-1 .................................... 85
Pr0~ess-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
Process-3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
Low Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
Low Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
Concentrate. Low Viscosity-A ..................... 86
Concentrate. Low Viscosity-B ..................... 86
Spray Mixing Process-A .......................... 87
Spray Mixing Process-B . . . . . . . . . . . . . . . . . . . . . . . . . . 87
Spray Mixing Process-B .......................... 88
Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
Fabric Softener
Heavy-Duty Detergent. Powder
Liquid Heavy-Duty Detergent. Built Type. High
Heavy Duty Liquid Laundry Detergent-Type DN . . . . . . . . . . 89
Built Formulation #1 ................................ 89
Heavy Duty Liquid Laundry Detergent-Type TA . . . . . . . . . . 90
Heavy Duty Liquid Laundry Detergent-Type WA . . . . . . . . . . 91
Liquid Laundry Detergents ........................... 90

Contents and Subject Index xvii
Built Formulation #2 ................................ 91
Liquid Heavy-Duty Detergent
Low Viscosity-A ............................... 92
Low Viscosity-B ............................... 92
Built Type.High Viscosity-B ...................... 92
Light-Duty Detergent. Powder
Spray M i n g Process-B .......................... 93
With Incorporated Softener. Low Viscosity-A .......... 93
Low VisCosity-A ............................... 94
Low Viscosity-B ............................... 94
With Incorporated Softener. Low Viscosity-B .......... 94
Industrial Laundry Two-Part Systems. Uniforms
(Petroleum Greases and Oils) ........................ 95
HoteVLinen Supply (Animal and Vegetable Grease) ......... 95
Industrial Laundry Powder. Uniforms .................... 95
Laundry Liquids ................................... 96
"Fine Care" Fabric Detergents
Pilot Formula #LDY-OO3-01 ...................... %
Pilot Formula #HDL-004-01 ...................... %
Pilot Formula #HDL-005-01 ...................... %
Laundry Powder Detergent ........................... 97
Industrial Laundry One-Shot Liquid .................... 97
Liquid Heavy Duty Detergent HDLD .................... 98
Liquid Detergent "FSL" A ............................ 98
Thick Bleach-2 ................................... 99
Wool Detergent
Medium Viscosity-A ........................... 100
Medium Viscosity-B ........................... 100
Liquid Light-Duty Detergent
Heavy Duty Laundry Liquids
Thick Bleach-1 ................................... 99
9. METAL CLEANERS AND POLISHES ................... 101
Aluminum CleanerDrightener ........................ 102
Aluminum Smut Cleaner ............................ 102
Aluminum Cleaner Concentrate ....................... 103
Aluminum Wash ................................. 103
Cleaners and Cleaning Solutions ...................... 104
Metal Cleaning
Alkaline .................................... 104
Acid ....................................... 104
Paint Removal ................................ 104

xviii Contents and Subject Index
Rust Removal ................................ 104
Copper Cleaning .................................. 105
Acid ....................................... 105
Brightening .................................. 105
Aluminum Aircraft-Brightener (U.S. Patent 2.687.346) . . . . . . 105
Electrocleaner ................................... 106
Moderate Alkalinity. Soil Splitting Soak Cleaner . . . . . . . . . . . 106
High-Foaming Acid Scrubber ........................ 107
Acid Cleaner .................................... 107
Metal Cleaner and Degreaser .........................
Thickened Clear Degreaser Concentrate . . . . . . . . . . . . . . . . . 108
Cleaner-A ................................... 109
Cleaner-B ................................... 109
Liquid-A .................................... 109
Liquid-B .................................... 109
Aluminum Cleaning
108
Stainless Steel
Silver Polish
10.OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . . 110
Pump Spray Oven Cleaner .......................... 111
Caustic Oven Cleaner .............................. 111
Oven/Grill Cleaner ................................ 111
11. POLISHES. COATINGS AND FINISHES ................. 112
Aerosol Furniture Polish (Carbon Dioxide Propellant) . . . . . . . 113
General Purpose Liquid Polish (Oil-in-Water Type) . . . . . . . . 113
Aerosol Furniture Polish (Hydrocarbon Propellant) . . . . . . . . . 114
Furniture Paste Wax ............................... 114
Detergent Resistant. Cream Cleaner Polish . . . . . . . . . . . . . . . 115
Non-Abrasive. Detergent Resistant. Glaze Emulsion . . . . . . . . 115
High Gloss. Detergent Resistant. Soft Paste Polish . . . . . . . . . 116
Detergent Resistant Cream Polish ..................... 116
For Clear Coat Finishes ......................... 117
No Solvent .................................. 117
Outer Phase Oil ............................... 118
Non-Wax Liquid Polish (Oil-in-Water Type) ............ 118
Liquid Furniture Polish ............................. 119
20% Wax Emulsion-1 ............................. 119
20% Was Emulsion-2 ............................. 119
Liquid Water-Based Glaze .......................... 120
Solvent Wax Glaze ................................ 120
Paste Polish (Oil-in-Water Type) ..................... 121
Liquid Polish

Contents and Subject Index xir
Spray-and-Wipe Polish ............................ 121
Paste Polish
Oil-in-Water Type
Type-1 .................................. 122
Type-2 .................................. 122
Type-3 .................................. 123
Outer Phase Oil ............................... 123
Spray-and-Wipe Polish (Pump) ...................... 124
20%Wax Emulsion-1 ............................. 124
20% Wax Emulsion-2 ............................. 124
Spray and Wipe Type
Aerosol or Non-Aerosol (1) ...................... 125
Liquid Wax-Solvent Furniture or Floor Polish ............ 125
12.RINSE AIDS ....................................... 126
For Hard Water ............................... 127
For Neutral or Soft Water ........................ 127
Rinse Aid ...................................... 128
Automatic Dishwash Rinse Aid
13.RUG. FJ.DOR, CARPET. UPHOLSTERY SHAMPOOS
ANDCLEANERS ................................... 129
Liquid-A .................................... 130
Liquid-B .................................... 130
Liquid-A .................................... 130
Liquid-B .................................... 130
Dry-Foam Cleaner
Basic Floor Cleaner
Floor Cleaner. for Everyday Use
Carpet and Upholstery Cleaners
Liquid-A ................................ 131
Liquid-B ................................. 131
Powder-A ................................ 131
Powder-B ................................. 131
Carpet Shampoo. High Foam ......................... 132
Evaporative (No Rinse) Wax Stripper ................... 133
Waxed Floor Cleaner .............................. 133
Floor Cleaner .................................... 134
Floor Polish
Mor-Glo 2-457 20% Solids ...................... 135
ML-870-389 20%Solids ........................ 136
Liquid Carpet Cleaner .............................. 137

XT Contents and Subject Index
Carpet Stain Remover-Liquid ........................ 137
Carpet Cleaner/Booster.Dry. Destainer . . . . . . . . . . . . . . . . . 137
Low Cost Extraction Carpet Cleaner . . . . . . . . . . . . . . . . . . . 138
Non-Ammoniated Floor Stripper ...................... 139
Quarry Tile Cleaner ............................... 140
Low Foam Floor Cleaner ........................... 140
Special-Purpose Floor Cleaner
Liquid-A .................................... 141
Liquid-A .................................... 141
Medium Cost Steam Extraction Carpet Cleaner . . . . . . . . . . . . 138
Premium. Heavy Duty Steam Extraction Carpet Cleaner . . . . . 138
Liquid-B .................................... 141
Wash-and-Wax Floor Cleaner
Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141
14.MISCELLANEOUS .................................. 142
Condensate T L Typical Formulations . . . . . . . . . . . . . . . . . . 143
All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Dilutable Shampoo ................................ 143
Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Opacified Hand Soap .............................. 143
d'lmonene Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . 144
Waterless Hand Cleaner ............................ 144
Dry Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145
Dust Control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146
Hand and Body Cleanser ............................ 147
Heavy Duty Degreaser ............................. 148
Burnishing Compound .............................. 148
Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Viscous Floor Cleaner .............................. 143
Corrosion Inhibiting Coating Oil-Emulsifiable . . . . . . . . . . . . 148
Heavy Duty Industrial Spray Metal Cleaner Concentrate . . . . . 149
Low Foam Hypochlorite Cleaner ...................... 149
Metal CleanerBrightener ........................... 149
Low Foam Heavy Duty Alkaline Cleaner-A . . . . . . . . . . . . . . 150
Low Foam Heavy Duty Alkaline Cleaner-B . . . . . . . . . . . . . . 150
Paint Brush Cleaners ............................... 151
Steam Cleaner ................................... 152
Heavy Duty Industrial Spray Cleaner Concentrate . . . . . . . . . . 152
Hot Tank Stripper/Cleaner/Derster .................... 150
High Solids Alkaline Cleaner ........................ 152
Wallpaper Removal ............................... 153

Contents and Subject Index m-
SECTION II
TRANSPORTATION CLEANERS AND POLISHES
15.AUTO CLEANERS AND POLISHES .................... 155
Auto Polishlcleanser. Oil in Water Emulsion ............. 156
Detergent Resistant Auto PolishlCleanser. Paste Wax ....... 156
Camauba Hotwax ................................. 157
Pressure Spray Truckwash ........................... 157
Detergent Resistant Auto Polish. Oil in Water Emulsion ..... 158
High Luster Auto Finish. Paste Wax ................... 158
High Gloss. Detergent Resistant Polish .................. 159
High Gloss Auto PolishPinish ........................ 159
Spraywax ....................................... 160
Spraywax Ladder of Formulas ........................ 161
Spraywax Concentrate .............................. 160
16.CAR AND TRUCK WASH COMPOUNDS ................ 162
Automatic Car Wash Concentrate ..................... 163
General Purpose Car Wash .......................... 163
Auto Shampoo Concentrate .......................... 164
High Foaming Car Wash ............................ 164
Car Wash ....................................... 164
Car Wash Liquid ................................. 165
Car Wash Powder ................................. 165
Economy Truck Wash .............................. 166
Truck Wash Liquid ................................ 166
Foamy Brush Car Wash. Liquid ....................... 167
1:2 Dilutable Car Wash ............................. 167
High Oil Splitting Vehicle
Wash-A .................................... 168
Wash-B .................................... 168
Liquid Car Wash ................................. 169
Spray-On Car Wash Concentrate ...................... 169
Liquid Hi@ Pressure Coocentrate ..................... 170
Tmck Wash w/varamide A-83 ....................... 170
Liquid Tmck Wash ................................ 171
Mild Car Shampoo ................................ 172
Cgrspray CW Concentrate ........................... 172
Automotive "Wash t Wax" ......................... 172
Premium Carspray 500 Concentrate .................... 173
Standard Carspray 500 Concentrate .................... 173
Premium Carspray 700 Concentrate .................... 174
Standard Carspray 700 Concentrate .................... 174

xxii Contents and Subject Index
17.WHITEWALL TIRE CLEANERS ....................... 175
White Wall Tire Cleaner ............................ 176
Bug Remover Concentrate ........................... 176
Whitewall Tire Cleaner Concentrate .................... 177
Whitewall Tire Cleaner Liquid ....................... 177
18.MISCELLANEOUS .................................. 178
Automobile Windshield Cleaners ...................... 179
General Purpose Liquid Boat Polish-(l) ................. 180
General Purpose Liquid Boat Polish-(2) ................. 180
Liquid Aluminum Engine Block Cleaner ................ 181
Foaming Engine Cleaner ............................ 181
SECTION Ilk TRADE-D RAW MATERIAIS ........... 182
SECTION N:SUPPLIERS'ADDRESSES .................... 197

Section I
Household and Industrial
Cleaners and Polishes
1

Bathroom Cleaners 3
Bathtub and Faucet Cleaner
I n g r e d i e n t : Percent by We1q h t
Ammoni um hydroxide s o l u t i o n 28% 3.2
Cellosolve solvent 5.0
Nonionic s u r f a c t a n t (Neodol 25-9) 6.0
Water 65.8
L i q u i d C i t r i c Acid-50% (Haarman & Reimer Corp.) 20.0
Fragrance, dye q . s .
Mix t h e L i q u i d C i t r i c Acid-50% w i t h an equal volume o f water.
Slowly add t h e ammonium hydroxide s o l u t i o n . The n e u t r a l i z a t i o n
should be done c a u t i o u s l y and under a g i t a t i o n , as t h e r e a c t i o n
i s exothermic. Add Cellosolve, s u r f a c t a n t , remaining water,
fragrance and dye. The formula i s s u i t a b l e f o r a pump spray.
Bathtub, sinks, faucets and other hard surfaces should be
sprayed from a distance o f about 10 inches. For maximum e f f e c t -
iveness, t h e deposited cleaner f l u i d should be e f t a t work
f o r a t l e a s t f i v e minutes and then r i n s e d o f f w t h water o r
removed w i t h a wet c l o t h o r sponge.
SOURCE: Haarman 81 Reimer Corp.: Suggested Formu
__Bathroom_ _ _ - ~Cleaner
Water
Sodium C i t r a t e
Glucopon 425 CS
Propylene Glycol nButy1 Ether
T o i l e t B o w l Cleaner
Water
Phosphoric Acid
Glucopon 425 CS
Tub 8 7 1 l e Cleaner
a t i o n
Water
Sodium C i t r a t e
STPP
Standapol ES-2
Velvetex A0-45
Standamid KD
Isopropyl Alcohol
SOURCE: Henkel Corp., CD D i v i s i o n : S t a r t i n g Formulations
"rtb
79
9
9
3
W t %
79
15
6
W t %
75
4
1
12
4
1
3

4 Advonced CleoningRoduct Formulotions
Clear Liquid Bowl Cleaner
Formula BC-0001
Miranol FBS
Hydrochloric A c i d (20Be)
Water
Wt.%
3.0
20.0
77.0
Procedure
Add t h e Miranol FBS. Mix u n t i l uniform.
Phvsi-1 Prooerties
Add t h e water. Slowly add t h e h y d r o c h l o r i c acid, w i t h mixing.
Appearance: Clear, l i g h t y e l l o w
V i s c o s i t y : <10 cps
S p e c i f i c G r a v i t y : 1-03
pH (as i s ) : <1.0
Thick T o i l e t Bowl Cleaner
Formula BC-0002
Wt.%
M i r a t a i ne TM 5.0
Hydrochloric Acid (20Be)
Water
32.0
Q.S
Prowdur g
add t h e M i r a t a i n e TM and mix u n t i l uniform.
PhvsiG a l Prooerties
Add t h e h y d r o c h l o r i c a c i d t o t h e water, w i t h s t i r r i n g . Slow
Appearance: C1ear, ye11ow 1iqui d
V i scosi t y : 1.035 cps
Speci f ic Gravi t y : 1,037
pH (as i s ) : <1.0
Y
SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s : Formulas

Bathroom Cleaners 5
Foarnable A c i d T i l e Cleaner
Hard Foaming Hard Surface Cleaner f o r Soap Scum Removal
Inaredi e n t :
Dei oni zed Water
C i t r i c Acid (50%)
Mazon 98
Wt.%
87.00
10.00
3.00
pH (as i s ) : 2.0-2.5
Appearance: Clear, water-white l i q u i d
S p e c i f i c G r a v i t y : 1 .01
Procedure:
above. Mix u n t i l c l e a r .
Notes :
This formula produces a copious, dense foam. I t i s s u i t a b l e
f o r cleaning soap scum from shower s t a l l t i l e s and other bath-
room and household f i x t u r e s .
To a mixing vessel, charge t h e i n g r e d i e n t s i n t h e order l i s t e d
Formula CH-105
L i a u i d T o i l e t Bowl Cleaner
A L i q u i d S t a i n and Rust Remover
I n s r e d i e n t :
Deionized Water
Phosphoric Acid (75%)
Avanel S-70
pH (as i s ) : t1.5
S p e c i f i c G r a v i t y : 1.124
Wt.%
66.00
30.00
4 . 0 0
Procedure:
phosphoric a c i d under a g i t a t i o n . Use c a u t i o n during a c i d add-
i t i o n t o avoid s p a t t e r i n g . When a l l o f t h e a c i d i s dissolved,
cool t o room temperature and add t h e Avanel s u r f a c t a n t .
Notes:
i c u l a r l y e f f e c t i v e i n t h e removal o f scale build-up and r u s t
s t a i n s .
This m a t e r i a l may be marketed i n an appropriate squeeze
b o t t l e t o f a c i l i t a t e "under t h e r i m " bowl cleaning by t h e
consumer.
Formula CT-101
SOURCE: Mazer Chemicals: Suggested Formulations
Charge t h e water t o t h e mixing vessel, and slowly charge t h e
This formulation i s designed t o be used "as i s " and i s p a r t -

S o l i d Automatic T o i l e t Bowl Cleaner Formulation
I n g r e d i e n t :
Macol DNP 150
Incromide L90
Carbowax PEG 8000
Macol 27
Versaflex 207 ( d r y )
Water
%-
25.0
25.0
20.0
20.0
5.0
5.0
Procedure:
1. Melt t h e Macol 27, Macol DNP 150, and Carbowax PEG 8000, and
2. Maintain a temperature o f about 70C, and add t h e Incromide
3. Add water and Versaflex 207 ( d r y ) and mix.
4. Pour formulation i n t o a mold, and a l l o w t o cool.
SOURCE: National Starch and Chemical Co.: Reference #8069:49
mix together.
L90 w h i l e mixing.
__A c i d T o i l e t Bowl Cleaner
Water, D . I .
Hydrochloric Acid (37%)
Rewoteric AM TEG
% bv Weiaht
71 . O
27.0
2.0
B1endi ng Procedure:
Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between
each addi t i on.
Typical Properties:
V i s c o s i t y , cps: 135
Solids: 1.0%
pH: 2.8
SOURCE: Witco Corp.: Formula 532
Tub, T i l e and Bathroom Cleaner
Water
Sodium Carbonate
Tetrasodium EDTA (40%)
Phosphoteric T-C6
Nonoxynol 10
Procedure:
% bv Wei aht
81.5
5.0
10.0
1.5
2.0
Add i n g r e d i e n t s i n order l i s t e d , a l l o w i n g s u f f i c i e n t time
between a d d i t i o n s .
This product may be applied w i t h a t r i g g e r pump o r by aerosol.
Formulation Properties:
Physical Appearance: Clear l i q u i d
Cloud Point: 42C
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulation
6 Advanced CleaningRoabct Formulations

Bathroom Cleaners 7
T i l e , Porcelain and Bathroom Cleaner, Acid
Water. D . 1
% by Weiqht
75.5
Rhodopol 23 0.5
Petro BAF Powder 2.0
Phosphori c Acid, 75% 12.0
Hydroxyacetic Acid, 70% 10.0
Perfume, Dye q . s .
B1endi ng Procedure :
t o mix u n t i l material thickens. Add remaining ingredients i n
order l i s t e d . If problems develop adding Rhodopol t o water,
premix the Rhodopol 23 i n some isopropanol before adding t o
water.
Formula 529
Add Rhodopol 23 slowly t o water w i t h high speed mixing. Allow
Hypochlorite Tub and T i l e Cleaner and Mildew S t a i n Remover
% by Weiqht
Water, D.I. 44.9
Sodium Hydroxide (30%) 1 .o
Varox 365 1.5
Sodium Hypochlorite (5.7%) 52.6
81endi ng Procedure :
between each addi t ion.
Typical Properties:
Viscosity, cps: 4
Solids: 3.8%
pH: 13.5
Formula 531
Add ingredients i n order shown and dissolve completely
Soap Scum Remover/Cleaner
% by Weiaht
Water, D.I. q . s .
*Builder Solution 0.20
Tetrasodi um EDTA 0.25
Rewoteric AM V 1 .oo
Dowanol EB 0.50
81ending Procedure:
Blend ingredients i n the order shown, mixing thoroughly
between each a d d i t i o n .
Typical Properti es :
Viscosity, cps: 4
Solids: 2.0%
pH: 11-12
Comments:
*Builder Solution: Sodium Carbonate (Na2C03): 4%
Potassi um Hydroxide (KOH) : 3%
DI Water 93%
Formula 544
SOURCE: Witco Corp.: Suggested Formulations

8 Advanced CleaningRoabct Formulations
T o i l e t Cleaner. Liquid-A
Marl ipal 013/99
Acetic acid*
Balance water, fragrance, dyestuff
A c t i v e matter: 2.7%
Toi 1e t Cleaner . L iquid-B
Marl ipal 013/99
C i t r i c a c i d
Balance water, fragrance, d y e s t u f f
Toi 1e t C1eaner , Medi urn V i scosi t y - A
Marlazin OL 2
M a r l i p a l 013/99
C i t r i c a c i d
Na Cumene sulphonate 40 (approx.)
T o i l e t Cleaner, Medi urn V i scosi tv-B
Marlazin OL2
Marl ip a l 013/99
C i t r i c a c i d
Phosphoric acid, 85%
KNA cumene sulphonate 40 (approx.)
Balance waser, fragrance, d y e s t u f f
A c t i v e matter: 2.0
* f u r t h e r products o f Huls AG
96
3.0
6.0
t o 100
%
5.0
1.7
t o 100
%
1.5
0.5
5.0
1.5
t o 100
%
1.5
0.5
2.5
7.5
1.3
t o 100
SOURCE: Huls America, I n c . : Baslc Formulations o f Detergents
and Cleaning Agents f o r Household Purposes

Bathroom Cleaners 9
Toi 1e t Cleaners, Mediurn V i scosi t y - A
Marlazin 7102
Phosphoric acid, 85%
Sodium c h l o r i d e
Active matter: 4.0%
Toi 1e t C l eaner . Mediurn V i scosi ty-B
Marlazin OL 2
M a r l i p a l 013/99
Acetic Acid*
KNA cumene sulphonate 40 (approx.)
Balance water, fragrance, dyestuff
Active matter: 3.5%
Toi 1e t Cleaner. Powder
Marlon ARL
Amidosulphonic a c i d
Magnesium carbonate
Sodi um b i sulphate
Sodium bicarbonate, fragrance, d y e s t u f f
Active matter: 4.0%
T o i l e t Cleaner. Powder-B
Marlon A 390
C i t r i c a c i d
Sodi um sulphate
Sodium bicarbonate, fragrance, dyestuff
96
4.0
5.0
3.5
t o 100
%
3 . 0
0.5
6.0
3.1
t o 100
96
5 . 0
20.0
5 . 0
6 0 . 0
t o 100
%
5.0
25.0
55.0
t o 100
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and
Cleaning Agents for Household Purposes

10 Advanced Cleaning Roduct Formulations
T o i l e t Cleaning Block, Extruded-A
Marlon ARL
M a r l i p a l 1618/25 powder
Marlamid M1618
Vestinol C*
Sodium sulphate, d y e s t u f f
Active matter: 42.0%
T o i l e t Cleaning Block. Extruded-B
Marlon ARL
Marlon A390
Lipoxol 6000*
Sodi um tripolyphosphate
Fragrance
Sodium sulphate, d y e s t u f f
T o i l e t Cleanino Block. Cast-A
Marl i n a t 242/70
Marlon A375
M a r l i p a l 1618/25 powder
M a r l i p a l 1618/40
Marlamid M 1618
L ipoxol 12000*
Fragrance
Dyestuff
T o i l e t Cleaning Block. Cast-B
Marl i pal 013/90
M a r l i p a l 1618/40
M a r l i p a l M 1618
L ipoxol 12000*
Fragrance
Dyestuff
* f u r t h e r products o f Huls Ag
96
40.0
4.0
6.0
4.0
t o 100
ss
40.0
30.0
8.0
1.o
5.0
t o 100
%
3.0
13.0
30.0
24.0
15.0
10.0
4.0
1.o
96
12.0
60.0
10.0
13.0
4.0
1.o
SOURCE: Huls Chemical Co.: Basic Formulations o f Detergents and
Cleaning Agents f o r Household Products

2. Dairy, Food and
General Industrial Cleaners
11

12 Advanced CleaningRoduct Formulations
An
Inaredient :
Deionized Water
G l y c o l i c Acid (70%)
Avanel S-150
Dairy Mi 1kstone Remover
Acid D i l u t a b l e Concentrate
Wt.%
53.40
28.60
10.00
8 . 0 0
pH (as i s ) : ~ 2 . 0
Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d
Procedure:
Charge water t o t h e mixing vessel and s t a r t a g i t a t i o n . Under
a g i t a t i o n , charge t h e G l y c o l i c Acid followed by t h e Phosphoric
Acid. Charge t h e Phosphoric Acid slowly t o avoid s p l a t t e r i n g .
Charge t h e Avanel S-150 and cool t o room temperature. F i l l o f f .
Notes :
m i 1kstone from dai r y equipment .
Brush thoroughly, then r i n s e .
Formula CD-101
This formulation i s h i g h l y e f f e c t i v e a t removing d a i r y
Use concentration i s 1/2 t o 1 ounce per g a l l o n o f water.
Dairy M i 1kstone Remover
Low Cost Acid D i l u t a b l e Concentrate
Inaredient :
Deioni zed Water
Gluconic Acid (50%)
Avanel 5-70
pH (as i s ) : < 2 . 0
Wt.%
55.00
37.50
3 . 5 0
4 . 0 0
Procedure:
To mixing vessel, charge t h e water and s t a r t a g i t a t i o n .
Slowly charge t h e Phosphoric Acid t o avoid s p l a t t e r i n g . Cool
t o room temperature and charge t h e Gluconic Acid and Avanel S-70.
Notes:
A lower cost s u b s t i t u t e f o r PPG/Mazers CD-101 d a i r y cleaner
formulation. I t r e t a i n s t h e general performance a t t r i b u t e s o f
t h e o r i g i n a l formulation.
Use concentration i s 1/2 t o 1 ounce per g a l l o n o f water.
Brush thoroughly, then r i n s e .
Formula CD-102

&ky, Food and GeneralI . . Cleaners 13
D a i r y P i p e l i n e Cleaner
H i g h A1 k a l ine Low Foam Hvpochlorit e Cleaner
I n n r e d ient:
Deionized Water
Sodium Hydroxide (50%)
Avanel S-74
Sodium Cumene Sulfonate (40%)
Sodium Hypochlorite (12.5%)
pH (as i s ) : 12.5-13.5
Appearance: Clear, 1ight-ye1 low 1i q u i d
Speci f ic G r a v i t y : 1 . 1 5
Wt.%
52.00
20.00
2.50
1 .50
24.00
Procedure:
Hydroxide, and cool t o l e s s than 9OF. Add t h e Avanel 5-74 and
Sodium Cumene Sulfonate. Mix u n t i l c l e a r and add t h e Sodium
Hypochlorite.
Notes:
a l k a l i n i t y o f common p i p e l i n e cleaners r e s u l t i n g i n a s i n g l e
cleaning system.
Shelf s t a b i l i t y o f h y p o c h l o r i t e cleaners i s dependent on t h e
absence o f t r a c e metals. Care should be taken t o i n s u r e good
q u a l i t y water and hypochlorite.
Formula may be adjusted t o use other commercially a v a i l a b l e
concentrations o f Sodium Hypochlorite. Absolute concentration o f
a v a i l a b l e c h l o r i n e i s 3.0%.
SOURCE: Mazer Chemicals: Formulation CD-103
Charge water t o mixing vessel and s t a r t a g i t a t i o n . Add Sodium
This formulation combines a c h l o r i n e cleaner w i t h t h e h i g h
I n s t i t u t i o n a l S t a i n l e s s Steel Cleaner
Components:
Water
50% C i t r i c Acid
Burcosperse LP
Dequest 2000*
Burco NPS 50%
45% KOH
% by Weight
52.75
20.00
5.00
5.00
5.00
12.25
*From Monsanto o r use equivalent product.
Procedure:
Add components i n t h e order l i s t e d . Blend u n t i l uniform
SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formulation

14 Advanced CleaningProduct Formulations
High Pressure Cleaner for I n d u s t r i a l Use
L i q u i d , transparent, a l k a l i n e
I n q r e d i ents:
A Genapol UD-050
Genapol UD-080
Genopur ASA
KOH (85%)
B Water (ca.5OC)
C Sodi ummetasi 1ic a t e x 5H20
Manufacturing:
I The components o f A a r e mixed.
I 1 Then B i s added.
I11 F i n a l l y t h e components o f C are added
Aquamollin 8C Powder h i g h l y conc.
2,50%
2,50%
3,00%
5.00%
67,00%
10,00%
10,00%
Cleaner f o r M i 1k i n a EauiDment
L i q u i d
I n g r e d i e n t s :
A Tetrapotassiumpyrophosphate
Sodi ummetasi 1i c a t e x 5H20
Sodiumcarbonate
B Water
C Genopur ASA
KOH (85%)
D Genapol UD - 080
Manufacturing:
I One a f t e r another, t h e components o f A
I 1 S t i r one a f t e r another, t h e components
I11 A t l a s t D i s added.
7.00%
5,00%
3,00%
70,00%
5.00%
5,00%
5,00%
are added t o 8.
o f c t o I.
Cleaner f o r Meat P l a n t s
L i q u i d
I n g r e d i e n t s :
A Tetrapotassiumpyrophosphate
B Water
C Genopur ASA
KOH (65%)
D Hostapur SAS 60
Genapol UD - 080
Solvent GX 5
Manufacturing:
I Add one a f t e r another, t h e components o f A t o
I 1 C i s added t o Iby c o n t i n u i n g s t i r r i n g .
I11 A t l a s t t h e components o f D are added.
Potassium water g l a s (40 Be)
5,00%
76,00%
3,50%
3,50%
5.00%
2,00%
3,00%
2,00%
B.
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Detergents and Cleaning
Agents: Guide Formulations

he,Food and GeneralIndustrial Cleaners 15
Meat Packaaina Plant Cleaner Concentrate
An A l k a l i n e High Foaming Hypochlorite Hard Surface Cleaner
w i t h Improved S a l t Tolerance
Inaredi ent :
Oeioni zed Water
Hostapur SAS-60
Potassi um Hydroxide
Tetrapotassium Pyrophosphate
Mazon 98
Sodium Cumene Sulfonate (40%)
Sodium Hypochlorite (12.5%)
Oeioni zed Water
Wt.%
59.20
2.50
0.90
2.10
5.00
1.30
10.00
19.00
pH (as i s ) : 12.5-13.5
Appearance: Clear-to-translucent, s l i g h t l y viscous, l i g h t -
Speci f ic Gravity: 1.04
Charge t h e water t o a mixing vessel and s t a r t a g i t a t i o n .
yellow l i q u i d .
Procedure:
Charge t h e Hostapur, followed by t h e Potassium Hydroxide and
t h e Tetrapotassium Pyrophosphate. Apply cooling and then add
t h e Mazon 98 and t h e Sodium Cumene Sulfonate. When product
i s l e s s than 85 degrees F. add t h e Sodium Hypochlorite and t h e
balance o f t h e water.
Notes:
This formula i s designed t o be d i l u t e d t o 3-6 ounces per
g a l l o n i n hot water and t o be applied as a foam t o meat packing
house w a l l s and other surfaces. A f t e r an appropriate time, these
surfaces should be thoroughly rinsed.
Shelf s t a b i l i t y o f c h l o r i n e cleansers i s dependent upon t h e
absence o f t r a c e metals. Care should be taken t o insure good
q u a l i t y water and Sodium Hypochlorite.
Revision o f CB-102 t o provide greater s a l t tolerance.
SOURCE: PPG Industries, I n c . : Formula CB-102-A

16 Advanced CleaningProdccct Formulations
Steam Cleaners
C1eaner-Li ght Duty
Inaredients :
Sodi urn Metasi 1ia t e
Sodi um T r i p o lyphosphate
Trisodium Phosphate
Aerosol 22 Surfactant
T r i t o n CF-10
Inqredients:
Sodi urn Orthosi 1i c a t e
Sodium Carbonate
T r i sodi urn Phosphate
Aerosol 22 Surfactant
T r i t o n CF-10
C l eaner-Medi urn Duty
% by Weiaht
30.0
58.0
10.0
1 .o
1.o
% by Wei aht
33.0
20.0
44.0
1.5
1.5_ _
Cleaner-Heavy D u t y (For O i l y S o i l s )
% by WeiahtInaredients:
Aerosol 22 Surfactant 7.0~ ~~~
Sodium M e t a s i l i c a t e
Dowanol DE
Water
Inaredients:
Aerosol 0s Surfactant
Soda Ash
Sodi urn Hydroxide
Sodium M e t a s i l i c a t e (5H20)
Sodi um T r i polyphosphate
Cleaner-General Purpose
Use 0.5 t o 2.0 0 2 . t o 1 a a l l o n o f water.
35.0
3.0
55.0
% by Weight
10.0
35.0
15.0
30.0
10.0
_ _ _
Cleaner-Lipht Duty f o r S o f t Metals
Ingredients: % by Weiaht
Aerosol 0s Surfactant 7.14~ ~~~
Sodium Sesquicarbonate 92.86
Inpredients: % by Weiaht
Cleaner-General Purpose
Sodi um Metasi 1icate
Aerosol 22 Surfactant 5.0
Water 73-78
15-20
Aerosol 0s Surfactant 2- 3
Cleaner-Compound
Inaredi ents : % by Weiaht
Sodi urn Hydroxide 30.0
Borax 30.0
D i sodi um Phosphate 15.0
Aerosol C-61 Surfactant 5.0
Add t h e desired amount o f cleaner t o water which has been
preheated t o 140F.
SOURCE: Cytec I n d u s t r i e s I n c . : Suggested Formulations
Soda Ash 20.0

d-Liaonene Microemulsion Cleaner/Desreaser
Burco TME
Burco FAE
d-Li monene
Water
11 p a r t s
11 p a r t s
16 p a r t s
62 p a r t s
Mix i n order l i s t e d ; add water slowlv. Product w i l l
No co-solvent i s required when mixed i n proprortions given
thicken, then break as water i s added.
above. Produces a c l e a r product. Burco FAE imparts corrosion
resistance i n a d d i t i o n t o emulsion c h a r a c t e r i s t i c s .
but r a t i o s o f t h e other a c t i v e s must remain s i m i l a r t o the
above. Example :
To make a more concentrated product, l e s s water can be used,
TME
FAE
d-Limonene
Water
22 p a r t s
22 p a r t s
32 p a r t s
24 p a r t s
High a c t i v e products can reach a g e l - l i k e v i s c o s i t y , but can
be t h i nned w i t h Isopropanol and Butyl Propyl sol v.
SOURCE: Burlington Chemical Co., I n c . : Suggested Formulation
Concentrated d-Limonene Biodearadable Deareaser
A Natural All-Purpose Micro-Emulsion Cleaner o r Concentrate
Inaredi ent :
d-Limonene. Grade M
Mazclean EP
Deionized Water
Wt.%
30.00
20.00
50.00
pH (as i s ) : 9.0-10.0
Appearance: Clear, l i g h t - y e l l o w l i q u i d
S p e c i f i c Gravity: 0.97
Odor: Sweet Orange
Procedure:
Charge t h e d-Limonene and Mazon 245-103 t o an apprDopriate
mixing vessel and s t a r t a g i t a t i o n . Under good a g i t a t i o n , slowly
add t h e water and mix u n t i l s o l u t i o n i s c l e a r .
Notes :
duty use, product should be sprayed "as i s " onto t h e o i l y
substrate, followed by a water r i n s e .
SOURCE: PPG I n d u s t r i e s , Inc.: Formulation CS-101
This formulation may be used "as i s " o r d i l u t e d . For heavy-

Degreasers 19
Solvent Deareasi rig
The s o l u b i l i t y o f Aerosol OT Surfactant i s extremely high i n
a l l solvents used f o r degreasing. I t w i l l d i s s o l v e e a s i l y a t
room temperature i n most cases. I f heating i s required f o r
s o l u b i l i z a t i o n , t h e s o l u t i o n w i l l be s t a b l e upon r e t u r n t o room
temperature.
As an example, Aerosol OT-75% i s soluble t o over 50% a t room
temperature i n carbon t e t r a c h l o r i d e , b u t naphtha solvent requires
heating. Both are c l e a r s o l u t i o n s a t room temperature. The
presence o f t h e water i n Aerosol OT-75% p o r t i o n i s an a i d i n
t h e removal o f any water-soluble p a r t i c l e s present i n t h e work
being degreased.
Formulations such as:
Aerosol GPG o r OT-75%
High Flash Naphtha
0.5%
99.5%
can be used f o r l i g h t - d u t y cleaning, t h e solvent removing t h e
o i l s , waxes, etc. and t h e Aerosol OT a i d i n g not o n l y i n t h e
penetration o f t h e covering material, b u t a l s o i n d r a i n i n g .
This type o f cleaner can be sprayed on, brushed on, o r t h e
work can be immersed i n t o i t followed by a r i n s e .
Heavy-Duty Degreasing:
To remove heavy l u b r i c a t i n g and preservative o i l s and
greases, many solvents may be used t o s p e c i f i c needs. Aerosol
GPG Surfactant w i l l be found t o be soluble i n a l l o f these
solvents. A t y p i c a l formulation used i s :
Kerosene
1- 3%
97-99%
Preparation i s by simple mixing. T r i - o r tetrachloroethylene,
high f l a s h naphtha o r other s u i t a b l e solvents can be s u b s t i t u t e d
f o r t h e kerosene.
Carbonaceous deposits can be removed by d i p p i n g i n formula-
t i o n s such as:
Kerosene
Perchloroethylene
Carbon Tetrachloride
Cresyl ic Acid
40%
30%
16%
10%
4%
Normally, 3 g a l l o n s o f t h e above are added t o 1 g a l l o n of
water which, f l o a t i n g on t h e surface, minimizes l o s s o f solvent.
The work t o be cleaned i s immersed i n t h e solvent phase f o r
time periods o f a few minutes t o several hours, i f required,
t o o b t a i n cleanliness. Upon removal from t h e solvent layer, and
a s h o r t r i n s e i n t h e aqueous l a y e r , t h e cleaned a r t i c l e s are
rinsed, d r i e d o r c a r r i e d onto t h e next operation.
SOURCE: Cytec I n d u s t r i e s , Inc.: Suggested Formulations

Dishwashing Detergents 21
C1ear L i q u i d D ishwash
W i t c o l a t e AE-3
Witco 1298 S o f t Acid
Sodi um Hydroxide, 50%
W i tconate SXS L i q u i d
W i tcami de 5195
Phosphoric Acid
Water
% by Weiqht
12.5
19.0
5.2
13.5
2.5
q.s. t o pH = 6.4-6.8
q.s. t o 100
Blending Procedure
Formula 108
B1end ingredients in t h e order shown, m i x i ng thoroughly
Non-Chlori nated Machine D i shwashi na Compound, L i q u i d
% by Weight
Water, D.I. 79.5
Sodi um Tripolyphosphate 2.0
Versene 220, Powder 1.0
Sodium Gluconate 1 .o
Sodium M e t a s i l i c a t e , Pentahydrate 7.0
Caustic Soda 50% 8.5
Petro ULF L i q u i d 1.0
Blending Procedure:
Formula 109
Blend i n g r e d i e n t s i n t h e order shown, mixing thoroughly
Clear, Colorless Manual Dish Wash
Water, D.I.
W i t c o l a t e ES-3
Rewoteric AM 8-14
Ethanol
Sodium Chloride
% by Weiqht
57.5
31.2
5.0
3.0
3.3
Blending Procedure:
Comment :
B1end ingredi ents in t h e order 1isted. Dissolve completely
Rewoteric AM 8-14; Grease c u t t e r and foam booster.
Formula 132

22 Advanced Cleaning Roduct Formulations
Dish Washina Agent
Clear, l i q u i d , 25% WAS
Alkanesulphonate:ethersulfate=4.1
Ingredients:
A Hostapur SAS 60
B Water
Genapol ZRO l i q u i d
Preservative
Dye
Perfume
Hoe S 3924
Manufacturing:
One a f t e r another, t h e components o f B are added t o A.
Tests:
V i s c o s i t y (mPas) : 90
Cloud p o i n t : <-5C
33.36%
17.90%
47.50%
0.10%
q.s.
0.20%
1.00%
Dish Washin A ent
c l e a r , liquid: 2:% WAS
alkanesulphonate:ethersulphate=4.1
Ingredients :
A Hostapur SAS 60
B Water
Preservative
W e
Perfume
Hoe S 3924
Manufacturing:
One a f t e r another, t h e components o f B are added
Tests
V i s c o s i t y (mPas): 410
33.30%
17.90%
44.50%
0.10%
q.s.
0.20%
4.00%
t o A.
Dish Washing Aaent
alkanesulphonate:ethersulphate=4.1
Ingredients:
A Hostapur SAS 60 40.00%
Genapol ZRO l i q u i d 21.40%
B Water 30.30%
Preservative O.lO%
Dye q.s.
Perfume 01.20%
Manufacturing:
Tests:
One a f t e r another, t h e components o f 0 are added t o A.
SOURCE: Hoechst Aktiengesellschaft: Detergents and Cleaningal

DishwashingDetergents 23
Dish Washi na Agent
alkanesulphonate:ethersulphate=4:1
I n a r e d i e n t s :
A Hostapur SAS 60
8 Water
Preservative
Dye
Perfume
Hoe S 3924
Manufacturing:
Tests:
One a f t e r another, t h e components o f 0 are added
Powder f o r Automatic Dishwashina Machines
40.00%
21.40%
34.30%
0.10%
q.s.
0.20%
4.00%
t o A.
A Genapol 2908
B Sodiummetasilicate x 5H20
C Sodiumcarbonate
Sodi umdichloroi socyanurate
Thermphos NW
Manufacturi no:
1;. 00%
52.00%
10.00%
2.00%
35.00%
I Spray A on 0 .
I 1 One a f t e r another, t h e components o f C a r e added t o 1.
A p p l i c a t i o n :
1-2 g detergent/L dishwashing l i q u o r

24 Advanced Cleoning Product Formulations
Dishwashing Deteraent. Medium Viscositv. Basis Marlon A-A
%
Marlon A 350 30.0
Marl inat 242/70 5.7
D i o n i l OC 1.o
Na cumene sulphonate 40 1.o
Balance water, fragrance, dyestuff, preservative,
sodium c h l o r i d e t o 100
Dishwashing DeterQent. Medium Viscositv. Basis Marlon A-B
%
Marl inat 242/70 4.3
Marlon A 365 18.5
Balance water, fragrance, d y e s t u f f , preservative,
D ishwashi na Detergent, Medi urn V i m s i t y . B a s i s Marlon AS3-A
%
Marlon AS3 10.5
Caustic soda, 50% (approx.) 2.6
Marl ip a l 013/120 2.7
D i shwashi n Q Detergent, Medi urn Viscosity. Bas4s Marlon AS3-B
%
Marlon AS3 4.5
Caustic soda, 50% (approx.) 1.1
M a r l i n a t 242/70 4.5
Balance water, fragrance, dyestuff, perservative,
Cleaning Agents f o r Household Purposes

M w h i n g Detergents 25
D i shwashi nq Detergent, Medi um V i s c o s i t y . Basis Marlon PS-A
%
Marlon PS 65 49.0
Marlamid DF 1218 3.0
Ethanol * 4.0
Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e ,
Marl in a t 242/70 11.5
A c t i v e m a t t e r : 43.0%
D i shwashi ng Detergent, Medi um V i s c o s i t y , Basis Marlon PS-B
%
Marlon PF 40 71.3
Marlamid DF 1218 1 . 5
A c t i v e m a t t e r : 30.0%
D i shwashi ng Detergent, Medium V i scos t y . Basis Marlon Compounds-A
%
Marlon AFO 40 46.3
Marlamid D 1885 1.5
A c t i v e m a t t e r : 20.0%
D i shwashi ng Detergent, Medi um V i s c o s i t y , Basis Marlon Compounds-B
%
Marlon AFO 50 30.0
A c t i v e m a t t e r : 15.0%
Cleaning Agents for Household Purposes

D i shwashi n Q Deteraent . Powdered. SDrav M i x i na Process-A
%
Marlox FK 64 1.o
Sodium tripolyphosphate 40.0
Sodium m e t a s i l i c a t e pentahydrate 35.0
Sodium carbonate, dehydrated 22.0
Sodium dichloroisocyanurate 2.0
A p p l i c a t i o n : Use 3-5 g/1 water (depending on water hardness)
D i shwashi ng Detergent, Powdered, Spray M i x i ng Process-I3
Marlox B 24/80
Sodium tripolyphosphate
Sodium m e t a s i l i c a t e pentahydrate
Sodium m e t a s i l i c a t e , dehydrated
Sodium carbonate, dehydrated
Sodi um d i c h l o r o i socyanurate
Phosphonate HEDP, e.g. Sequion 10
Sodi um hydroxide
A c t i v e matter: 1.0
A p p l i c a t i o n : Use 3-5 g/1 water
Na 2
%
1.o
25.0
25.0
20.0
15.0
2.0
2.0
10.0
(depending on water hardness)
D i shwashi ng Detergent, Powder, Phosphate-Free, Spray M i x i ng
Process-A
Marlox MO 154
Sodi um c i t r a t e d i hydrate
Sodium d i s i l i c a t e granulate
Polycarboxylate, e.g. Sokalan PA 40 granulate
Sodium perborate monohydrate
Tetraacetylethylenediami ne (TAED)
Enzyme Esperase
Sodium sesquicarbonate
%
2.5
35.0
25.0
5 . 0
15.0
4.0
2.0
t o 100
Dishwashing Detergents, Powder, Phosphate-Free, Spray Mixing
Process-I3
Marlox MO 154
Polycarboxylate, e.g. Permulsin SP
Phosphonate HEDP, e.g. Sequion 10 Na 2
Sodi um metasi 1i c a t e
%
2.0
15.0
10.0
5.0
t o 100
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents

DishwashtnLDeterpent (4096 Sol ids)-A
Witconate 1260 S l u r r y
W i t c o l ate LES-6OA
W i tcami de 128T
Water
% by W e i m
37.0
17.5
4.0
34.0
Blending Procedure:
Blend ingredients i n t h e order shown. mixing thoroughly
Dishwashing Deteraent (40% Solids)-8
W i tconate 45LX
Witcolate LES-6OA
W i tcamide 128T
Water
% bv Weiqht
59.0
6.0
17.5
4.0
16.5
Blending Procedure:
between each addition.
Formula 105
Blend ingredients i n t h e order shown. mixing thoroughly
Hand D i shwashi ng L i q u i d
W i tconate AOS
Witcolate S-1285C
Witcamide 128T
Water
% by Weiaht
60.0
10.0
4.0
26.0
Blending Procedure:
Formula 106
Blend ingredi ents in the order shown, m i x i ng thorough1y

28 Advanced Cleaning R&t Formulations
Dish Wash w/Ami ne Oxide/LABS/SLES
Water, D . I .
Witconate 30DS
Varox 1770
W i t c o l ate SE-5
Blending Procedure:
between each a d d i t i o n . Add Ethanol as needed t o
Typical Properties:
Viscosity, cps: 620
Solids: 16.8%
pH: 9.12
Formula 117
Add ingredients i n order shown and d i s s l v e
Dish Wash w / h i ne Oxide/LABS/ALES
Water, 0.1.
W i tconate 30DS
Varox 1770
Witcolate LES-6OA
Ethanol
% by Weiqht
62.9
13.7
5.3
18.1
ompl e t e l y
lower v i s c o s i t y .
% by Weiaht
70.0
13.8
3.1
8.2
5.0
B1endi ng Procedure:
between each a d d i t i o n . A c i d i f y w i t h C i t r i c Acid t o pH = 6.5.
Typical Properties:
Viscosity, cps: 4
Solids: 10.1%
pH: 6.68
Formula 118
Dish Wash w/Ami ne Oxide/LABS
Water, D . I .
W i tconate 30DS
Varox 1770
Ethanol
% by Weiaht
69.8
20.3
4.9
5.0
Blending Procedure:
Typical Properties:
Viscosity, cps: 4
Solids: 7.8%
pH: 9.16
Formula 119

High-Performance Hand Dish Detergent
Formula DW-0013
Water
SXS, 40
Caustic Soda, 50%
Dodecylbenzene s u l f o n i c Acid
Rhodapex NA-61
A1 kamide DC-212/S
Rhodacal A-246/L
Rhodasurf 25-9
C i t r i c Acid (50%). t o pH 8
Ethanol SD-3A
Preservative
Fragrance
Dye
Wt.%
3.0
6.6
25.0
8.0
3.0
10.0
6.0
Q.S.
2.0
0.1
To 100
-
Procedure
Add t h e ingredients i n t h e order l i s t e d w i t h mixing. Mix
u n t i l uniform a f t e r each a d d i t i o n . C i t r i c Acid and Caustic Soda
are used f o r pH adjustment.
Physical ProDerties
Appearance: Clear gold l i q u i d , dyed t o preference
pH. as i s : 8
Viscosity: 400 cps
M i l d L i a u i d Hand Dish Detergent
Water
Caustic Soda (50%)
Dodecylbenzene s u l f o n i c acid
Miranol CS Conc.
A1kamide DC-212/S
Rhodasurf 25-9
Cheelox BF-13
C i t r i c Acid (50%). t o pH 8
Fragrance
Dye
Wt.%
To 100
3
12
15
3
3
0.2
Q . S .
-
-
Procedur e
u n t i l uniform a f t e r each addition. C i t r i c a c i d and c a u s t i c
soda are used f o r pH adjustment. Dissolve t h e dye i n water
before a d d i t i o n .
Phvsical Properties
Appearance: Clear gold l i q u i d , dyed t o preference
pH. as i s : 8
V i s c o s i t y : 150 cps
Add t h e ingredients i n t h e order l i s t e d w i t h mixing. Mix
SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formulas

30 Advanced Cleaning Product Formulations
S t a r t i n g Formulations f o r Home Machine Dishwashinq Detergents
8.7% Phosphorous(A)
Compounds:
BASF S u r f a c t a n t *
Sodium t r i p o l y p h o s p h a t e
B r i t e s i 1 H24 hydrous sodium s i 1i c a t e * *
Sodium s u l f a t e
Sodium carbonate
C h l o r i n a t e d isocyanurate***
Water
8.7% Phosphorous(B1
Coflpounds :
B r i t e s i l H24 hydrous sodium s i l i c a t e * *
Sodi um s u l f a t e
Sodium carbonate
C h l o r i n a t e d isocynaurate***
Sodium t r i p o l y p h o s p h a t e hexahydrate
Nonphosphate
Compounds2
Sokalan PABOCL
B r i t e s i l ti24 hydrous sodium s i l i c a t e * *
C h l o r i n a t e d t r i s o d i u m phosphate
Sodium carbonate
?4 b y WSi¶h_t.
3
34
17
15
19
2
10
% -by__W!sht
3
17
1 4 . 5
20
1 . 5
44
”/._ bY. W!%lb t
4 . 0
2****
20
1 2 . 5
30
1 . 5
30
* P l u r o n i c , P l u r a f a c , and I n d u s t r o l s u r f a c t a n t
**Other r a t i o s o f Si02 can be used. L i q u i d s i l i c a t e s can a l s o
be used i n p l a c e o f powders.
***Such as ACL-59.
****Active
M i x i n g Procedures:
gent, t h e f o l l o w i n g process i s suggested f o r t h e mixing of raw
mater ia1s :
1 . Spray a m i x t u r e o f t h e s u r f a c t a n t and water ( o r s u r f a c t a n t ,
To achieve maximum c h l o r i n e s t a b i l i t y o f t h e formulated d e t e r -
water, and l i q u i d s i l i c a t e ) onto t h e phosphate b u i l d e r s , soda
ash, o r m i x t u r e t h e r e o f . S t i r continuously w h i l e spraying.
w i t h simul-T h i s process r e s u l t s i n h y d r a t i o n o f t h e b u l d e r s
taneous adsorption o f t h e s u r f a c t a n t .
2. Add t h e c h l o r i n e - c o n t a i n i n g compound and any f i l
m i x t u r e and continue mixing u n t i l t h e e n t i r e m i x
homogeneous. A d r y , f r e e - f l o w i n g granular produc
obtained w i t h t h i s method.
SOURCE: BASF Corp.: Suggested Formulations
e r s t o t h e
u r e i s
should be

-washing Detergents 31
L i g h t Duty L i q u i d Deteraents
L i q u i d detergents based on P i l o t Calsoft, Calsuds and Calfoam
s u r f a c t a n t s produce safe, e f f e c t i v e suds w i t h e x c e l l e n t grease-
c u t t i n g p r o p e r t i e s f o r hand dishwashing. Detergents containing
Calamide C are e s p e c i a l l y m i l d t o s e n s i t i v e skin.
Water
C a l s o f t L-60
Calfax DB-45
Cal foam EA-603
Calamide C
C i t r i c Acid
Perfume
Ammonium Chloride
Dye
Calsuds A
Cal foam ES-303
Water*
C i t r i c Acid
Perfume and Color
C a l s o f t L-40
Cal foam EA-603
Calamide C
P i l o t SXS-40
Water*
C i t r i c Acid
Perfume and Color
Calsuds CD-6
Cal foam EA-603
P i l o t SXS-40
Cal s o f t LAS-99
Water*
C i t r i c Acid
Perfume and Color
P i l o t Formula #LDL-010-01
% bv Weipht
61 .OO
19.80
9.90
5.00
3.00
0.10
0.10
0.10
1 .oo
P i l o t Formula #LDL-013-01
% by Weiaht
70.00
10.00
20.00
Q.S. pH 7
Q . S .
P i 1o t Formul a #LDL-005-01
% bv Weiaht
40.00
10.00
6.00
12.50
26.50
Q.S. pH 7
Q . S .
P i 1o t Formula #LDL-015-01
% bv Weight
25.00
10.00
8.80
6.00
50.20
Q.S. pH 7
Q . S .
*May be o p a c i f i e d by r e p l a c i n g 1% o f water w i t h 1% l a t e x
opaci f ie r . Opaci f i e r should be d i 1uted w i t h water before
a d d i t i o n .
SOURCE: P i 1o t Chemi c a l Co. : Household C1eaner Formula t i on8

32 Advanced CleaningPromcct Formulations
L i g h t Duty Liauid. Premium Hand Dishwash
Water, D . I .
W i t c o l a t e SE-5
W i tconate 1260 S1u r r y
W i tcami de 128T
Petro LEA L i q u i d
Sodium S u l f a t e
Ethanol
Formal i n
Perfume, Dye
% by Weight
30.2
36.7
5.0
1.9
2.6
1.8
0.1
q . s .
21.7
Blending Procedure:
using C i t r i c Acid.
Typical P r o p e r t i es :
Blend i n g r e d i e n t s i n t h e order l i s t e d . Adjust pH = 6.5-7.0
Appearance: Clear L i q u i d
Formula 113
L i g h t Duty L i q u i d
Water, D. I.
W i t c o l a t e SE-5
Witconate 1260 S l u r r y
W i tcami de 128T
Petro LEA L i q u i d
Sodium Chloride
Formal in
Perfume, Dye
Economy Hand D i shwash
% by Weiqht
73.6
8.3
13.5
1.9
1.o
0.6
1.o
0.1
q . s .
81ending Procedure:
using C i t r i c Acid.
Typi c a l P r o p e r t i es :
Blend i n g r e d i e n t s i n t h e order l i s t e d . Adjust pH = 6.5-7.0
Appearance: C1ear L iqui d
Formula 115

LXshwashing Detergents 33
Water
Caustic Soda (50%)
L i a u i d Hand Dish Detergent
Formula DW-0016
Wt.% Wt.% Wt.%
To 100 To 100 To 100
2.5 3.3 4.1
Dodecylbenzene sui f o n i c a c i d 10 13
Rhodapex NA-61 4.5 4.5
A1kamide DC 212/S 1 2
Cheelox BF-13 0.5 0.5
C i t r i c Acid (50%), t o pH 8 Q.S. Q . S .
Sodium c h l o r i d e 1 1
Fragrance - -
Dye
Opaci f ie r (Morton) - -
- -
16
5
3
0.5
Q.S.
1
Procedur e
Add t h e ingredients i n t h e order l i s t e d , w i t h mixing. Mix
u n t i l uniform a f t e r each addition. C i t r i c a c i d and c a u s t i c soda
are used f o r pH adjustment. Sodium c h l o r i d e b u i l d s v i s c o s i t y .
Dissolve i t i n water before a d d i t i o n .
Dissolve t h e dye i n water before a d d i t i o n . I f o p a c i f i e r i s
used, i t should be d i l u t e d w i t h water before addition. A l l pH
adjustments must be completed before t h e o p a c i f i e r i s added.
Phvsical ProDertieg
Appearance: Liquid, colored and o p a c i f i e d t o preference
pH. as i s : 8
Viscosity: 200-400 cps
Speci f ic Gravi t y : 1.02+-0.05
pH, 1%: 7.2
SOURCE: Rhone-Poulenc Surfactants & S p e c i a l t i e s : Formula

Mechanical D ishwashi ng Detergent
Chlorinated
Formula DW-0009
Sodium Carbonate ( L t . Density)
Antarox BL-330
Sodium Tripolyphosphate. Powder
Sodium M e t a s i l i c a t e Pentahydrate
Clearon CDB (FMC)
Wt.%
41 . O
2.0
34.0
20.0
3.0
ProcedurQ
Add t h e sodium carbonate t o t h e mixer. Spray on t h e Antarox
EL 330. Add t h e remaining ingredients i n t h e order l i s t e d . Mix
u n t i 1 uniform.
Phvsical ProDertieg
Appearance: White, free-flowing powder
pH (1%): 11.2
Uechanic a l D ishwashing DeterQent L isuid
Formula DW-0010
Igepal CO-730
Gantrez AN-149
Potassium Hydroxide (45% Active)
Sodium S i l i c a t e (46% Active)
Antarox BL-330
Tetrapotassium Pyrophosphate (60% Active)
Water
Wt.%
0.5
1.o
3.0
17.0
3.0
63.3
12.2
Proctndur e
1. Add Gantrez AN-149 t o Igepal CO-730/water mixture and s t i r
a t room temperature u n t i l dissolved. Heat t o 45-50C i f not
t o t a l l y i n s o l u t i o n .
2. Maintain heat a t 45C and add r e s t o f ingredients i n d i v i d u a l l y .
Physical P r o m r t ieg
pH (as i s ) : 13.2
pH (1%): 10.4
V i s c o s i t y : 1060 cps
SOURCE: Rhone-Poulenc S p e c i a l t i e s 6 Surfactants: Formulas

L i a u i d
Formula DW-0008
Rhodacal A-246/L
Rhodapex MA-460
Alkamide DC-212/S
Sodium Xylene Sulfonate (40%)
O p a c i f i e r (Morton)
Water
C i t r i c Acid t o pH 6.5-7.5
Perfume and Color
Wt.%
60.0
10.0
5.0
4.0
1.0
20.0
Q . S .
P.S.
Procedure
1. Charge water and sodium xylene sulfonate t o vessel equipped
w i t h a g i t a t i o n .
u n t i 1 uniform.
2. Add Rhodacal A-246/L and Rhodapex MA-360 t o vessel and mix
3. Add Alkamide DC-212/S and mix as above.
4. Adjust pH 6.5-7.5 w i t h c i t r i c acid.
5. Add o p a c i f i e r ( o p t i o n a l ) , perfume and colorant, as desired.
Physical P r o m r t i e s :
Appearance: Clear gold l i q u i d , dye and opacify t o preference.
pH, as i s : 6.5-7.5
S p e c i f i c Gravity: 1.02-1.04
V i s c o s i t y : 200-300 cps
SOURCE: Rhone-Poulenc Surfactants EL S p e c i a l t i e s : Formula

S t a r t i n a Formulations f o r Commercial Machine Dishwashing
Deteraents
Nonchlorine/Noncaustic
BASF Surfactant*
Sodium carbonate
Water
Noncaustic
BASF Surfactant*
Sodium carbonate
Chlorinated isocyanurate**
Water
C h l o r i n e K a u s t i c
BASF Surfactant*
Sodium carbonate
Chlorinated isocyanurate**
Sodium hydroxide (90%)
Water
*Pluronic, Plurafac, I n d u s t r o l surfactant
**Such as ACL-59
% by Weight
3
34
22
11
25
5
% bv Weiaht
3
31.5
20
31.5
1.5
12.5
% bv Weiqht
3
34
18
22.5
2.5
15
5
M i x i ng Procedures :
1. Thoroughly mix t h e phosphate and carbonate.
2. I n a separate container, mix t h e surfactant and water. Next,
spray th'is l i q u i d onto the phosphate/carbonate mixture. Mix
continuously w h i l e spraying, and continue mixing u n t i l t h e
l i q u i d i s completely adsorbed and t h e mixture i s homogeneous.
3. Add t h e m e t a s i l i c a t e , s u l f a t e , and/or caustic and mix.
4. F i n a l l y , add t h e c h l o r i n a t e d cyanurate and mix thoroughly.
Note:
maximum c h l o r i n e s t a b i l i t y .
SOURCE: BASF Corp.: Suggested Formulations
The mixing sequence given above i s necessary f o r maintaining

5. General Purpose Cleaners
37

38 Advanced CleaningRoduct Formulatioiu
A11 Purpose Cleaner
Mackam 2CSF
T r i sodium Polyphosphate
KOH (45%)
Low Rosin T a l l O i l F a t t y Acid
Deioni zed Water
Weight.%
10.0
5.0
5.0
4.0
10.0
66.0
Procedure:
1. Dissolve Tetrapotassi um Pyrophosphate and T r i sodi um Po
2. Add KOH.
3. Disperse T a l l O i l F a t t y Acid.
4. Cool t o 50C and slowly add Mackam 2CSF.
phosphate a t 70C.
PhosDhate Free A l l PurDose Cleaner
Mackamine C-10
Caustic Soda (50%)
Mackam 2CYSF
Tetrasodium EDTA (40%)
Deioni zed Water
Y-
Weight .%
22.0
9.0
2.0
4.0
1.o
62.0
Procedure:
1. Add Sodium M e t a s i l i c a t e and Tetrasodium EOTA t o water and
2. Add Mackamine C-10 and Caustic Soda (50%).
3. Add Mackam 2CYSF and blend u n t i l c l e a r .
heat t o 60C.
Bathroom T i l e Cleaner
Sodium Hypochlorite (35%)
Mackamine LO
Tetrasodi um EDTA
Deioni zed Water
Procedure:
Add components t o water and blend u n t i l c
SOURCE: McIntyre Qroup Ltd.: Suggested Formu
Wei aht .%
4.7
5.0
1.o
89.3
ear.
a t i one

Water
Sodi um Carbonate
Tetrasodium EDTA, 40%
W i t c o l a t e 7031
Sodium Chloride
C i t r i c Acid, 50%
A l l Purgose Cleaner
% bv Weiqht
61.2
5.0
6.0
15.0
10.8
2.0
9.s. t o pH=11.0-11.5
Blending Procedure:
Typical Properties:
V i s c o s i t y , cps: Water t h
S o l i d s : 25.6%
pH, as i s : 11.2
Blend i n g r e d i e n t s i n t h e order l i s t e d .
n
SOURCE: Witco Corp.: Formula 518
All-PurDose Cleaner
Eastman E8 solvent
Na4EDTA*
Nonionic s u r f a c t a n t * *
Isopropyl alcohol
Water
*Tetrasodi um e t h y l enedi ami n e t e t r a c e t a t e
**Such as Neodol 23-7 alcohol ethoxylate
N-95 ethoxylated nonylphenol (Texaco).
Hard-surface Cleaner
Eastman DB solvent
Anionic surfactant***
N a4EDTA* ***
Ammonium Hydroxide (28%)
Water
2.
2
1
90
39%)
S h e l l ) o r Sulfon
% bv Weisht
3.2
7
3
5
3
C
% bv Weiaht
7.0
1 .o
1.25
2.0
88.75
***Such as Rhodapex CO-433 (Rhone-Poulenc)
****Tetrasodium ethylenediaminetetraacetate (39%)
SOURCE: Eastman.Chemica1 Co.: Eastman EB and D0 Solvents f o r
Cleaners: Suggested Formulations
GeneralPurpose Cleaners 39

A11-Purpose C1eaner-A
%
Marl i p a l 24/90 7.5
Methoxypropanol 6.0
Sodium carbonate 3.0
N i t r i l o t r i a c e t a t e , 40% 0 . 4
Active matter: 7.5%
V i s c o s i t y : L i q u i d
A11-PUrDOSe C l e a n e r 4
%
M a r l i p a l 1012/6 1.o
M a r l i n a t 242/28 10.0
Sodium carbonate 3.0
Sodium c i t r a t e dihydrate 1.5
Sodium t a r t r a t e 1.5
Active matter: 3.8%
V i s c o s i t y : Low
Al1-PUrDOSe Cleaner. w i t h Y i c r o b i c i d a l Prooerties. Liauid-B
Marl ip a l 013/99
Warlazin KC 21/50
Nit ri1o t riacetate, 40%
Sodium carbonate
%
8.0
5.0
0.5
3.0
t o 100
Active matter: 9.7%
SOURCE: Huls America, Inc.: Basic Formulations o f Detergents

GeneralPurpose Cleaners 41
A-Jl-Purpose Cleaner, Liquid-A
Marlon PS 65
Marl ip a l 013/69
Coconut f a t t y a c i d
C i t r i c terpene
Methoxypropanol
Sodium carbonate
Sodium c i t r a t e d i h y d r a t e
Ethylenediamine t e t r a a c e t a t e , 40%
Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e
A l l -Pu_rpose C1eaner , L iqui d-6
Marl ip a l 013/69
C i t r i c terpene
Methoxypropanol
Sodi um carbonate
C i t r i c a c i d
N i t r i l o t r i a c e t a t e , 40%
KNA cumene sulphonate 40
%
3.0
1 .o
0.2
2.0
3.0
3.0
3.0
0 . 2
t o 100
'16
5 . 0
0.2
5 . 0
3.0
1 .o
0 . 2
1 . o
t o 100
All-Purpose CleaKer, w i t h - M i c r o b i c i d a l Properties, Liquid-A
Marl ip a l 013/99
N i t r i l o t r i a c e t a t e , 40%
Lonzabac 12.30
Sodium carbonate
KNA cumene sulphate 40
%
7.5
2.0
3.0
3.0
2.0
t o 100

42 Advanced Cleaningproduct Formulations
All-Purpose Cleaner, Pastv-A
Marlon AS3
Caustic soda, 50% (approx.)
Marl inat 242/28
Marl ip a l 013/30
Tylose CBR 10000
Titanium d i o x i d e
Sodium c h l o r i d e (approx.)
Balance water, fragrance, p r e s e r v a t i v e
A11-Purpose Cleaner ,
Marlon PF 40
M i lip a l 013/30
Marlamid DF 1218
Tylose CBR 10000
Titanium d i o x i d e
Sodium c h l o r i d e (approx.)
Balance water, fragrance, p r e s e r v a t i v e
96
10.0
2.6
15.5
3.0
4.0
0.1
2.0
t o 100
Pastv-B
%
45.0
2.0
2.0
4.0
0.1
8.0
t o 100
All-Purpose Cleaner, W i t h Soap, High Viscosity-A
%
Marlon PF 40 5.0
O l e i c a c i d 10.0
Caustic potash, 50%* (approx.) 3.9
Potassium carbonate* 1 .o
Ethylenediamine t e t r a a c e t a t e , 40% 0.2
Balance water, fragrance, d y e s t u f f , p r e s e r v a t i v e t o 100
All-Purpose Cleaner. W i t h Soap. High Viscositv-B
Marl ip a l 24/79
Marl ip a l 242/28
O l e i c Acid
Caustic potash, 50%* (approx.)
Ethylenedi amine t e t r a a c e t a t e , 40%
Ethanol*
96
2.0
5.0
8.0
3.1
1.5
0.2
1.5
t o 100
SOURCE: Huls America, Inc.: Basic Formulations o f Detergents
and Cleaning Agents f o r Household Products

General Purpose Cleaners 43
D-Lilnonene Emulsifiable Concentrate
Formul a HS-0094
Component
D-Li monene
Rhodacal I PAM
Igepal CQ-720
T r i ethanol ami ne
Wt.%
80.0
1 5 . 0
4 . 0
1 .o
Procedure
Phvsical Prooerti es
Blend ingredients i n order l i s t e d and m i x u n t i l uniform.
Appearance: Clear, yellow l i q u i d
V i s c o s i t y : t10 cps
pH, as i s : 10.0
Note: Product forms milky white emulsions when d i l u t e d w i t h
water.
D-Limonene All-PurDose Cleaner
Formula HS-0033
Comoonent:
Water
Sodium Metasilicate-Pentahydrate
Miranol FBS
Rhodasurf 91-6
Cheelox BF-13
A1kamide DC-212/M
D-Li monene
Wt.%
73.5
2.0
10.0
3.5
5.0
3.0
2.0
Procedur e
Blend ingredients i n order l i s t e d and m i x u n t i l uniform.
Phvsicsl Pronerties
Appearance: S l i g h t l y hazy, yellow l i q u i d
pH, as i s : 1.25
V i s c o s i t y : <I0 cps
SOURCE: Rhone-Poulenc Surfactants 81 Specialties: Formulas

44 Advanced Cleaning Rorluct Formulations
General C1eaners
Cleaner-Household
I n s r e d ients:
Dodecylbenzene Sul fonate T r i ethanol ami ne S a l t
Aerosol A-103 Surfactant
Lauric Diethanolamide
Sodium Xylene Sulfonate
Mix a l l o f t h e above together a t one time.
A1k a line Cleaner
I n s r e d ients:
Sodium Metasi 1icate
Caustic Soda
Tetrasodi um Pyrophosphate
T r i sodi um Phosphate
L i a u i d Hand Cleaner
Insredients:
Aerosol A-102 Surfactant
Mineral O i l
Coconut O i l
n-Propanol o r Isopropanol
Triethanolamine
Germicide
Water
% by Weiaht
8 . 0
4.0
4.0
2.0
7 6 . 0
% bv Wei aht
5 . 0
50.0
5.0
7 . 0
3 3 . 0
% by Weiaht
60.0
10.0
5 . 0
5 . 0
0.5
0.1
19.4
Germicidal C1eaner
Inaredi ents: % bv Weiaht
Aerosol 22, Aerosol 0s. Aerosol A-102 Surfactant
o r mixture 10.0
Tetrapotassium Pyrophosphate 7.0
Dowicide 32 5 . 0
Isopropanol 3 . 0
Water 7 5 . 0
SOURCE: Cytec I n d u s t r i e s Inc.: Suggested Formulations

Hiph-Performance General Purpose Cleaner Concentrate
Formula HS-0038
Water
STPP (Anhydrous Granular)
Rhodapon UB
Rhodapon BOS
A1codet HSC-1000
Butoxyethanol
Miranol FBS
Procedur e
Blend ingredients i n order 1
Phvsical ProDertles
Appearance: Clear, l i g h t ye1
pH, as i s : 9 . 4
sted
ow 1
and mix unt
q u i d
Heavy-Dutv Cleaner Powder
Formula HS-0039
Wt.%
65.0
6.0
13.0
5.0
5.0
4 . 0
2 . 0
1 uniform.
Trisodium Phosphate o r Sodium Carbonate
Sodium S i 1icate
Rhodacal DS-10
Fragrance
Procedur g
uniform.
Physical ProDerti es
Add ingredients i n order l i s t e d t o powder blender
Appearance: Whi t e , f ree-f 1owi ng powder
pH, 1% Solution: 10.8
Wt.96
40
10
20
30
Q.S
Mix u n t i l
SOURCE: Rhone-Poulenc Surfactants & Specialties: Formulas

46 Advanced CleaningPr&t Formulations
N e u t r a l A11-PurDose C1eaner, w i t h Pearlescence
High V i scosi t y - A
Marlon PS 65
Marl inat 242/28
Marlamid DF 1218
Marlamid PG 20
Cellobond HEC l O O O O O A
E f f e c t ,
96
7.5
4.5
1.o
2.0
0.7
t o 100
N e u t r a l All-PUrDOSe Cleaner, w i t h Pearlescence E f f e c t .
H iah V i scosi ty-B
M a r l i n a t OFK 30
Marl in a t 242/28
Marlamid DF 1218
Marl ip a l 24/90
Marlamid PG 20
Cellobond HEC lOOOOOA
Balance water, fragrance,
96
5.0
2.0
1.o
I .o
1.o
0.9
d y e s t u f f , p r e s e r v a t i v e t o 100
A1l-PUrDOSe Cleaner, w i t h A c e t i c A c i d - A
M a r l i p a l 1012/6
M a r l i n a t 242/28
Sodium c i t r a t e d i h y d r a t e
A c e t i c a c i d *
Sodi um c h l o r i d e (approx. )
V i s c o s i t y : low
A11-PUrDOSe Cleaner. w i t h A c e t i c Acid-B
Marlon PS 65
A c e t i c acid*
V i s c o s i t y : 1i q u i d
96
1.5
15.0
1.o
2.0
6.5
to 100
s6
5.0
6.0
t o 100
SOURCE: Huls America, Inc. : Basic Formulations o f Detergents and
Cleaning Agents f o r Household Purposes

Non-PhosDhate A l l PurDose Cleaner
Components:
Water
45% KOH
Burcosperse AP L i q u i d
Sodium Xylene Sulfonates 40%
Sodi um C i t r a t e
Dodecylbenzene S u l f o n i c Acid
Burco TME
Butyl Propasol
Varsol o r Mineral S p i r i t s
% by Weight
77.15
0.75
3.00
3.40
1.oo
1.75
6 . 0 0
6 . 0 0
0.95
Procedure:
Add components i n t h e order l i s t e d . Blend u n t i l uniform
O i l S D l i t t i n s General PurDose Cleaner
Components:
Water
Burco ADS-40
Burco TME
Burco LAA-38
Burco EHS
% by Wei Qht
82.5
5.0
2.5
5.0
2.5
2.5
Procedure:
Add components i n t h e order l i s t e d . Blend u n t i l f u l l y diss-
olved between each addition.
This i s a use as i s formulation f o r heavy duty cleaning. For
l i g h t e r duty applications, d i l u t i o n w i t h water may be possible.
This formulation w i l l suspend o i l t o a s s i s t w i t h removal. The
suspended o i l w i l l then f l o a t f o r easy removal.
SOURCE: B u r l ington Chemical Co., I n c . : Suggested Formulations

Scouri ng Cleaner, Mediurn V i scosi tv-A
Marlon PS65
Marl ipal 013/30
Sodium sulphate
Calcium carbonate, e.g. Durcal 40
Balance water, dyestuff, fragrance, preservative
Active matter: 5.5%
Scouring Cleaner. Mediurn V i scosi t y - B
Marlon PS 65
M a r l i p a l 013/30
Marl inat 242/28
Sodium carbonate
Calcium carbonate, e.g. Durcal 40
Balance water, d y e s t u f f , fragrance, preservative
Active matter: 5.8%
Scouring Cl-eaner. Powder-A
Marlon ARL
Sodi um d i c h l o r o i socyanurate
Calci um carbonate powder (abrasive)
Active matter: 4.0%
%
4.3
2.7
1.5
50.0
t o 100
%
3.5
3.0
2 . 0
1.5
5 0 . 0
t o 100
%
5.0
5.0
1.o
t o 100
Scouring Cleaner, Powder-B
%
Marlon ARL 5.0
Sodium carbonate, dehydrated 5.0
Sodium tripolyphosphate 2.0
Calcium carbonate powder (abrasive) t o 100
Active matter: 4.0%

A n t i f o g Compositions f o r A p p l i c a t i o n t o C l o t h
Special wiping c l o t h s impregnated w i t h Aerosol OT Surfactant
are used t o clean and t o prevent fogging o f eye glasses, b i n -
oculars, goggles, eyepieces i n gas masks, and automobile, t r a i n ,
plane, and boat windshields. Such wiping c l o t h s are prepared by
impregnating c o t t o n f l a n n e l w i t h Aerosol OT Surfactant s o l u t i o n s
followed by a run through squeeze r o l l s t o remove t h e excess
1iquor .
a t 25% s o l i d s and one formulation a t 50% s o l i d s are as f o l l o w s :
Three successful formulations containing Aerosol OT Surfactant
Ingredients-1 :
Aerosol OT-75% Surfactant ( l b . )
Varsol No. 2 Petroleum Solvent ( g a l . )
Isopropyl Alcohol ( g a l . )
Water ( g a l . )
Inaredi ents-2 :
Water ( g a l . )
I n ~ r e d i e n t s - 3 :
Water (gal . )
Inqredients-4:
Water ( g a l . )
25% S o l u t i o n
113
15
3
19
25% S o l u t i o n
113
6
6
25
25% S o l u t i o n
113
-
8
29
50% S o l u t i o n
66
2
3
-
The solvents and water are mixed a t 80F t o 1OOF. The Aerosol
OT-75% Surfactant i s added slowly w i t h continued mixing. A f t e r
t h e Aerosol OT has dissolved, a l l s o l u t i o n s w i l l remain c l e a r
and l i q u i d a t temperatures as low as 5OF. No scumming o f t h e
surface w i l l occur because o f evaporation d u r i n g a normal run
o f c l o t h through t h e bath. The s o l u t i o n s t h a t are allowed t o
stand should be covered t o prevent l o s s o f solvent.
The optimum amount o f Aerosol OT Surfactant t o be l e f t on t h e
c l o t h i s 40-50%, based on t h e weight o f t h e c l o t h . However, a
range o f 25-50% w i l l g i v e s a t i s f a c t o r y r e s u l t s .

Glass CleanerslPolishes 51
A n t i f o g Compositions f o r D i r e c t Application t o Glass
Aerosol OT Surfactant i s used i n special formulations t h a t are
applied d i r e c t l y t o glass surfaces t o prevent fogging under ad-
verse weather conditions. Some o f these formulations g i v e dur-
able f i l m s t h a t stand up under severe t e s t s . An example o f an
excel l e n t "Anti fog" paste i s as follows:
Aerosol OT-75% Surfactant
Gum Tragacanth
Petrolatum
Water
10.7 l b .
2.0 l b .
2.0 l b .
85.3 l b .
Heat t h e water t o 18OF and add t h e Aerosol OT-75% slowly
w i t h mixing. S i f t i n powdered gum tragacanth. Continue mixing
u n t i l a l l gum i s dispersed, cool t o 105F, and add petrolatum.
Application o f A n t i f o g Paste:
Dampen t h e corner of a piece o f c l o t h w i t h paste and rub
over e n t i r e glass surface. Before f i l m becomes dry, p o l i s h w e l l
w i t h clean p o r t i o n o f t h e c l o t h .
A spray bomb o f A n t i f o g may be prepared as follows:
Aerosol OT-75% Surfactant
Butyl Cellosolve Solvent
Propel 1ant
10 p a r t s
10 p a r t s
80 p a r t s
Aerosol OT Surfactant may a l s o be cast i n t o s t i c k form.
Softening agents such as glycerine o r ethylene g l y c o l are
incorporated t o s i m p l i f y a p p l i c a t i o n t o t h e glass surface.
Such s t i c k s , usually two t o f o u r inches long and one-half inch
i n diameter, are sold i n k i t s f o r a p p l i c a t i o n t o goggles,
w i ndshie l d w i pes and bthroom m i r r o r s .
SOURCE: Cytec I n d u s t r i e s , Inc.: Suggested Formulations

52 Advonced Cleoning product FormulotiOnr
Water, D . I .
Isopropanol
Adogen 66
Varox 365
Emcol 4500
Anti-Foggina. A n t i - S t a t i c Glass Cleaner
% bv We
Blending Procedure:
Combine ingredients i n t h e order shown and mix thorough
I f product i s hazy, a d d i t i o n a l Isopropanol can be used t o
c l a r i f y t h e s o l u t i o n . Gentle heating can be used t o f a c i l -
i i t a t e mixing o f t h e Emcol 4500.
Use I n s t r u c t i o n s :
sht
0.0
9.0
0.1
0.5
0.4
Y.
Apply f i n i s h e d product t o a t o w e l l e t e (Kimwipe, e t c . ) and
wipe onto t h e glass. Allow t o dry.
Product Informat
Product:
Varox 365
Adogen 66
Emcol 4500
This formulat
on :
B e n e f i t :
Wetting agent, degreaser. and detergent
A n t i - s t a t i c agent
Wetting agent, coupler, and detergent
on presents a t h i n b a r r i e r between t h e water
vapor ( i . e . , fog, steam, e t c . ) and t h e glass which w i l l prevent
fogging. The a b i l i t y t o lower t h e surface tension o f t h e
water prevents t h e c l i n g i n g o f i n d i v i d u a l water d r o p l e t s t o t h e
glass; t h e r e f o r e l i g h t i s not scattered as much as i t i s when
passing through i n d i v i d u a l droplets.
Formula 708
Annoniated Glass Cleaner
Water
W i t c o l a t e 2310
Butyl Cel l o s o l v e
Aqua Ammonia, 26 Be'
% by Weight
94.0
3.0
2.0
2.0
Blending Procedure:
Formula 704
Blend ingredients i n t h e order shown, mixing thoroughly

Glass CleanersfPolbhes 53
Glass C1eaners
Ammonia
Formula GC-0017
Water
Rhodacal DSB
Butoxyethanol
Dye
Economical Heavy-Duty
Wt.% Wt.%
94.60 88.70~~
0.15 0.30
5.00 10.00
0.25 1.oo
- -
ProcedurQ
Blend ingredients i n order l i s t e d and mix u n t i l uniform.
Phvsica1 Prooerties
Appearance: Clear l i q u i d , dye t o preference
pH (as i s ) : 10.5
pH (1%): 9.0
S p e c i f i c G r a v i t y : 0.99
10.8
9.7
0.99
t10 cps
G1ass C1eaners
Vinegar
Formula GC-0018
Water
Rhodacal DSB
Butoxyethanol
Acetic Acid
Dye
Economical Heavv-Duty
Wt.% Wt.%
94.85 89.70
0.15 0.30
5.00 10.00
To pH=4 To pH=4
- -
ProcedurQ
Blend ingredients i n order l i s t e d and mix u n t i l uniform.
Physical Prooerti eg
Appearance: Clear l i q u i d , dye t o preference
pH (as i s ) : 4.0 4.0
pH (1%): 3.5 3.5
Speci f ic Gravity: 0.99 0.99
V i scosl t y : t10 cps t10 cps
SOURCE: Rhone-Poulenc Surfactants 6 S p e c i a l t i e r : Formulas

Glassware and B o t t l e Cleaners
B o t t l e Cleaner (Alkaline-Powder)
Inaredi ents:
Aerosol OT-8 Surfactant
Sodium NTA Powder
Cyanamer A-100L Polyacrylamide
Tetrasodium Pyrophosphate
B o t t l e Cleaner (Acid-Powder)
Inaredients:
NTA Acid
Sodium Dihydrogen Phosphate
Sodium Hydrogen S u l f a t e
B o t t l e Cleaner (A1 k a line-Powder)
Inaredients:
Sodium NTA Powder
Tetrasodi um Pyrophosphate
% by Weiaht
2.0
20.0
5.0
8.0
65.0
% by Weiaht
2 . 0
20.0
58.0
20.0
% bv Weiaht
5-1 0
1- 2
20.0
8.0
60-66
B o t t l e C1eaner ( A c i d-Li quid)
Inaredients:
Aerosol GPG Surfactant
NTA Acid
Water
% by Weiaht
5.0
t o pH 3.0 or l e s s
20.0
75.0
B o t t l e C1eaner (Acid-Liqui d l
Inaredi ents:
NTA Acid
Water
% bv Weight
10.0. .
20.0
t o pH 3.0 o r l e s s
70.0
B o t t l e Cleaner (Hiahly Alkaline)
% bv WeiahtInaredi ents :
Aerosol 0s Surfactant 10.0
Aerosol 22 Surfactant 2.0
Sodium NTA 20.0
Sodi um Hydroxi de ( 1 0%) 68.0

Glass CleanerslPolishes 55
Water, D . I .
Isopropanol
Varox 365
Methylene B1ue
Household Window Cleaner
% by Weight
89.3
10.0
0.7
q . s .
Blending Procedure:
between each addition.
Typical Properties:
Viscosity, cps: 4
Solids: 0.2%
pH: 7.4
Formula 706
Prerniurn Household W i ndow C1eaner
Water, D . I .
Isopropanol
Varox 1770
Methylene 81ue
% by Weight
89.4
10.0
0 . 6
q . s .
Blending Procedure:
Typical Properties:
Solids: 0.23%
pH: 6.2
Formula 707

Low VOC Antistat/Cleaner f o r Glass
I n q r e d i e n t :
Versaf 1ex 7000
Isopropanol
Neodol 25-35 (58%)
Water, Fragrance, and Preservative
%w/w
1 .oo
5.00
0.50
0.15
q . s .
Procedure:
1. Dissolve Versaflex 7000 i n water.
2 . Add ammonium hydroxide and Neodol 25-35, and mix.
3. Add isopropanol and mix.
4. Add fragrance and preservative.
SOURCE: National Starch and Chemical Co.: Reference: #8069:32
A n t i -Fog G1ass C1g a s
I n q r e d ients:_
Water
Monawet MO-70R
IPA
Procedure:
Blend i n order l i s t e d and package.
% by We-
93.0
2.0
5.0
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulation
G1ass C1eaner
Eastman EB solvent
Isopropyl alcohol
Nonionic s u r f a c tant*
Water
% by We-
3.0
5.0
0.1
91.9
*Such as T e r g i t o l 15-S-7, Cll-C15 secondary alcohol e t h o x y l a t e
(Union Carbide) o r Genapol 24-L-60 l i n e a r alcohol ethoxylate
(Hoechst Celanese).
SOURCE: Eastman Chemical Co.: Eastman EB and DB Solvents f o r
Cleaners: Suggested Formulation

Glass CleaturslPolisks 57
T r a d i t i o n a l Consumer Glass Cleaner
Ammoniated Anionic Non-Streaki na G1ass C1eaner-Inaredient : Wt.%
Deionized Water 94.05
2-Butoxyethanol 5.70
Avanel S-70 0.25
C . I . D i r e c t Blue #86 Q.S.
Monoethanolami ne t o pH 10.5-11.5
pH (as i s ) : 10.5-11.5
Appearance: Clear, l i g h t - b l u e l i q u i d
Odor: Sweet, ethereal
Charge under a g i t a t i o n most o f t h e water, t h e 2-butoxyethanol.
Procedure:
and t h e Avanel S-70 i n t o t h e mixing vessel. I n a separate
vessel, under a g i t a t i o n , dissolve t h e dye i n t h e balance of
t h e water. Add t h e dye s o l u t i o n t o t h e batch. Adjust p H t o
10.5-11.5 w i t h Monoethanolamine.
Notes :
This formulation incorporates a novel anionic surfactant i n t o
a t r a d i t i o n a l ammoniated glass cleaner.
On prolonged storage, g l y c o l ethers have been shown t o form
peroxy compounds which can adversely a f f e c t t h e dyes normally
used i n glass cleaners. Morpholine, Ammonia, o r other v o l a t i l e
amines may be used i n place o f t h e Monoethanolamine.
Formula CG-101
Consumer Aci d G1ass C1eaner
Acid Anionic Non-Streaking Glass Cleaner
I n s r e d ient : Wt.%
Deioni zed Water 89.70
2-Butoxyethanol 10.00
Avanel S-70 0.30
Color Q.S.
Acetic Acid t o p H 3.5-4.0
pH (as i s ) : 3.5-4.0
Appearance: Clear 1i q u i d
Odor: Sweet, ethereal
Charge under a g i t a t i o n most o f the water, t h e 2-butoxyethanol,
Procedure:
and t h e Avanel S-70 i n t o the mixing vessel. I n a separate
vessel, under a g i t a t i o n , dissolve the dye i n t h e balance o f
the water. Add t h e dye s o l u t i o n t o t h e batch. Adjust p H t o
3.5-4.0 w i t h Acetic Acid.
Notes:
This formulation i s p a r t i c u l a r l y e f f e c t i v e a t removing
o i l . greases and other atmospheric contaminants from glass
surfaces.
On prolonged storage, g l y c o l ethers have been shown t o
form peroxy compounds which can adversely a f f e c t t h e dyes
normally used i n glass cleaners. Dyes should be thoroughly
screened f o r s h e l f s t a b i l i t y i n t h e f i n i s h e d product p r i o r t o
adoption i n t o t h e f i n i s h e d formulation.
Formula CG-102

Hard swface Cleaners 59
Abrasive Cleaner-1
A Hostapur SAS 60
Genapol UD-030
B Water (40-5OC)
C Preservative
D C a l i b r i t e SL
Tests:
Perfume
V i s c o s i t y (mPas): 1700 ( B r o o k f i e l d RVT)
pH: 1 0 , O
Abrasive C1eaner-2
1.n qr e dients :
A Hostapur SAS 60
Genapol UD-030
B Water (40-50C)
C Preservative
Perfume
Tests:
V i s c o s i t y (mPas): 2800 ( B r o o k f i e l d RVT)
pH: 1 0 , O
Abrasive C1eaner-3
I n s r e d i e n t s :
A Hostapur SAS 60
Genapol UD-030
B Water (40-5OC)
C Preservative
Perfume
4.50%
5.40%
59.00%
0.10%
0.20%
30.00%
4.50%
5.40%
49.00%
0.10%
0.20%
40.00%
4.50%
5.40%
39.00%
0.10%
0.20%
50.00%
Tests:
Manufacturing(l,2,3):
I One a f t e r another, t h e components o f A are added t o 0.
I1 A t 30C t h e components o f C a r e added t o I.
I11 A t l a s t , s t i r D to 11.
any longer. Modern l i q u i d products a r e based on calcium
carbonate.
V i s c o s i t y (mPas) : 6400 (Brookf ie l d RVT)
pH: 1 0 , O O
Abrasive powders, based on s i l i c i u m dioxyde a r e n o t common

60 Advanced Cleaningproduct Forrnulaiions
Concentrated L i q u i d Household Hard-surface Cleaner
P i ne O i 1 A11-Purpose D i l u t a b l e Concentrate
Inaredi ent :
Deioni zed Water
Macol TD-12
Macol TD-3
Mazamide 80
Macol 40
Pine O i l
Sodium Xylene Sulfonate (40%)
Wt.96
79.30
5.00
2.50
0.50
4.00
0.20
3.00
2.00
3.50
pH (as i s ) : 12.5-13.5
Appearance: Clear, l i g h t - y e l l o w l i q u i d
Speci f ic Gravity: 1.03
Procedure:
Charge t h e Macol TD-12, Macol TD-3. and Macol 48 and m i x u n t i l
product i s c l e a r and f r e e o f " f i s h eyes." Charge t h e Pine O i l
and mix 5 minutes. Charge t h e remaining ingredients and mix
u n t i l c l e a r .
Notes:
This i s a concentrated household hard-surface cleaner
designed t o be used a t a d i l u t i o n o f 1-3 ounces per gallon.
Formula CH-103
All-PurDose Household Spray Cleaner
Ready t o Use A l k a l i n e Hard Surface Spray Cleaner
Ineredi ent :
Deioni zed Water
Macol TD-12
Sodi um C i t r a t e
Macol 48
Wt.96
95.15
1.oo
0.25
0.60
3.00
pH (as i s ) : 9.5-10.5
Procedure:
Charge t h e Macol TD-12 and mix u n t i l dissolved and f r e e o f
" f i s h eyes.'' Charge t h e remaining ingredients and m i x u n t i l
c l e a r .
Notes :
This i s an all-purpose household cleaner designed t o be
used "as i s " from a spray b o t t l e .
Formula CH-104

Advanced cleaning product formulations Vol. 4

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