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WATER QUALITYWATER QUALITY
PARAMETERSPARAMETERS
By
Prof.A. Balasubramanian
Centre for Advanced Studies in Earth Science
University of Mysore, India
Importance of Water:Importance of Water:
ď‚—Water is an essential commodity
to all life
ď‚—Without water, there can be no
life.
ď‚—Every living thing--plants, animals,
and people--must have water to
live.
ď‚—Water is used in almost all
activities of life support systems
ď‚—Water is a major abiotic factor in
the environment
Natural water:Natural water:
ď‚—The endless circulation of water
between atmosphere, lithosphere,
hydrosphere and biosphere is
known as hydrologic cycle.
ď‚—We get water from Precipitation of
water vapor in the atmosphere
World’s Water Distribution:World’s Water Distribution:
ď‚—Earth has tremendous amount of
water
Three fourth’s of the earth surface is
covered by water
97% of World’s water is in the seas and
oceans. This water is saline.
ď‚—Only 3% is present on the continents.
This water is fresh.
ď‚—The distribution of water over land is
uneven.
Water is everywhere:Water is everywhere:
ď‚—Water is a common substance.
ď‚—It fills the oceans, rivers, and
lakes.
ď‚—It is in the ground and also in
the air we breathe.
ď‚—Water is used for drinking, all
domestic purposes, agriculture,
industrial applications, cleaning
and recreation.
Quality determines its Usage:Quality determines its Usage:
ď‚—Water has its own taste, color,
smell and constituents.
ď‚—Not all water can be used for all
purposes.
ď‚—Eg. Sea water can not be used
by us for drinking.
ď‚—The suitability of water for
different purposes is
determined by its quality
parameters.
Quantity and quality:Quantity and quality:
ď‚—On an average, each person in a
developed country uses about
260 litres of water a day in the
home.
ď‚—The Quality of water is equally
important than quantity.
ď‚—Even if present in huge
amounts, we can not use salt
water in many life support
activities.
Characteristics ofCharacteristics of
Water:Water:
ď‚—Water is a good solvent
ď‚—Water never occurs in its pure
form
ď‚—All waters contain some dissolved
substances
ď‚—The quality of water is determined
by these substances.
ď‚—It has the ability to dissolve many
inorganic and organic substances.
Water Quality Parameters:Water Quality Parameters:
Water has its own
ď‚—Physical properties
ď‚—Chemical composition and
ď‚—Biological Properties
Physical Properties:Physical Properties:
ď‚—Temperature
ď‚—Colour
ď‚—Odor
ď‚—Turbidity
ď‚—Electrical Conductivity
Temperature (T) of Water:Temperature (T) of Water:
ď‚—Essential for all environmental
studies
ď‚—Controls many ecological
processes including chemical
reactions.
ď‚—T of surface water varies from
space and time
ď‚—T of groundwater varies not only
with reference to space and time
but also with reference to depth.
Temperature of Water:Temperature of Water:
ď‚—Measured using Thermometers
ď‚—It ranges from 0 to 100 degree Celsius
ď‚—Unit of measurement is degree
Celsius
ď‚—The temperature of Surface water is
influenced by the atmospheric
conditions
ď‚—The temperature of groundwater is
controlled by the thermal
characteristics of bedrocks and the
depth.
Color of water:Color of water:
ď‚—The color of water is due to the
suspended particles and organic
matter
ď‚—Ranges form light to dark
brown
ď‚—Brownish color in water comes
due to the presence of iron
ď‚—Greenish color in pond water is
seen due to the presence of
organic substances including
algae
OdorOdor::
ď‚—Pure water is odorless
ď‚—When water dissolves other
substances, the odor is
determined by them
ď‚—Mostly decayed organic
substances give fouling smell
ď‚—Inorganic substances give earthy
smell
Turbidity:Turbidity:
ď‚—Muddiness in water
ď‚—Comes due to suspended
particles from clay, silt and
organic matter
ď‚—Controls the transparency of
water
ď‚—Transparency is measured using
Secchi Disc
ď‚—Water Turbidity is measured
using Nephelometer
Electrical Conductivity(EC):Electrical Conductivity(EC):
ď‚—Ability of a substance to conduct an
electrical current.
ď‚—The presence of charged ionic
species makes water conductive.
ď‚—It is measured using EC meters.
ď‚—Directly related to temperature of
water.
ď‚—Unit of measurement is mmhos/cm
at std temperatures. Ranges from
100-1,00,000
ď‚—Pure water is less conductive
Chemical properties:Chemical properties:
ď‚—pH
ď‚—Total Dissolved Solids(TDS)
ď‚—Major ions
ď‚—Minor or trace elements
ď‚—Hardness
ď‚—Salinity
ď‚—Alkalinity
pH of water:pH of water:
ď‚—Refers to the effective
concentration of hydrogen ions in
water
ď‚—It ranges from 0 to 14. Measured
using pH meters
ď‚—Water is said to be acidic( less than
7)
or alkaline ( above 7) depending on
the relative concentration of
hydrogen ions from the neutral
value which is 7.
Total DissolvedTotal Dissolved
Solids(TDS):Solids(TDS):
ď‚—Concentration of non-volatile
substances present in colloidal or
molecular state
ď‚—Total of all ions present in water,
expressed in ppm or mg/L
ď‚—Increases due to dissolution of more
mineral substances by water on its
path
ď‚—TDS determines the suitability of
water for our use and consumption.
Quality of Water :Quality of Water :
ď‚—Total dissolved solids(ppm)
ď‚—< 1000 fresh water
ď‚—1000-10,000 brackish water
ď‚—10,000 to 1,00,000 saline
ď‚—> 1,00,000 hypersaline or
brine
Classification of DissolvedClassification of Dissolved
constituents:constituents:
ď‚—Basis of concentrations-
mg/L
ď‚—Charges( positive or
negative)
ď‚—Level of Toxicity ( toxic or
non-toxic)
Based on Concentrations:Based on Concentrations:
ď‚—Major ions( > 10 mg/L)
â—¦ Mostly Bicarbonate, calcium, Magnesium,
Chloride, sodium, sulphate and silicon
ď‚—Minor ions ( 0.1-10 mg/L)
â—¦ Mostly Carbonate, fluoride, nitrate, potassium,
iron, strontium, boron.
ď‚—Trace elements( < 0.1 mg/L)
â—¦ Mostly Aluminium, Arsenic, Barium, Bromide,
Cadmium, Chromium, Cobalt, Copper, Lead,
Zinc, Nickel, Phosphate, Silver, Tin and
Vanadium.
Based on ionic Charges:Based on ionic Charges:
ď‚—Major ions
ď‚—Positively charged = Cations
ď‚—Negatively charged = anions
Major Cations in water:Major Cations in water:
ď‚—Calcium
ď‚—Magnesium
ď‚—Sodium
ď‚—Potassium
( Source: lithosphere)
Major Anions in Water:Major Anions in Water:
ď‚—Bicarbonate
ď‚—Carbonate
ď‚—Chloride
ď‚—Sulphate
ď‚—Nitrate
ď‚—Phosphate
Trace elements in water:Trace elements in water:
ď‚—Play a significant role in the use
of water
ď‚—Some are essential elements for
health & growth
ď‚—Some are injurious to health
and toxic also.
ď‚—Deficiency or excess intake of
some of these elements may
cause serious health problems
to life.
Hardness:Hardness:
ď‚—Hardness of water is defined as its
content of metallic ions which react
with sodium soaps to produce a
residue
ď‚—Expressed as total concentration of
Calcium and Magnesium in ppm.
ď‚—Total hardness= 2.5 Ca + 4.1 Mg.
ď‚—Softwater (Temporary)
ď‚—Hardwater (permanent ).
Salinity of Water:Salinity of Water:
ď‚—Comes due to sodium
and chloride
ď‚—Sea water contains
35,000 ppm or mg/L of
dissolved salts
Alkalinity of water:Alkalinity of water:
ď‚—Combined effect of Bicarbonates
and Carbonates with calcium
ions
ď‚—It has a direct relationships with
pH.
ď‚—Carbonates will be noticeable
for water having a pH of more
than 8.2
Biological Properties:Biological Properties:
ď‚—Dissolved Oxygen (DO)
ď‚—Biochemical Oxygen
Demand(BOD)
ď‚—Chemical oxygen
Demand(COD)
ď‚—Microorganisms-Bacterial
counts
Dissolved Oxygen(DO):Dissolved Oxygen(DO):
ď‚—Is related to the solubility of air in water
at 0 deg. C
ď‚—Solubility of oxygen in water decreases
with high temperatures
ď‚—Important property for aquatic
organisms
ď‚—Surface water bodies should have enough
DO
ď‚—If DO depletes, it will be difficult to many
aquatic organisms for their survival.
Biochemical OxygenBiochemical Oxygen
Demand(BOD):Demand(BOD):
ď‚—Is a measure of the biodegradable
material
ď‚—It is determined by incubating a water
sample and measuring the decrease in
dissolved oxygen as bacteria decompose
these materials.
Chemical OxygenChemical Oxygen
Demand(COD):Demand(COD):
ď‚—Is determined by chemical
oxidation of water with
dichromate
Water Quality Parameters:Water Quality Parameters:
ď‚—Limits the suitability of water
for different purposes
ď‚—Drinking
ď‚—Domestic consumption
ď‚—Agriculture
ď‚—Industrial Processes
ď‚—Cleaning and Recreation.
Water QualityWater Quality
StandardsStandards
ď‚—Permissible limits
ď‚—United States Public Health Drinking
Water Standards(USPH)
ď‚—Indian Standards Institution (ISI)
ď‚—World Health Organization (WHO)
Thank You

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Water quality parameters

  • 1. WATER QUALITYWATER QUALITY PARAMETERSPARAMETERS By Prof.A. Balasubramanian Centre for Advanced Studies in Earth Science University of Mysore, India
  • 2. Importance of Water:Importance of Water: ď‚—Water is an essential commodity to all life ď‚—Without water, there can be no life. ď‚—Every living thing--plants, animals, and people--must have water to live. ď‚—Water is used in almost all activities of life support systems ď‚—Water is a major abiotic factor in the environment
  • 3. Natural water:Natural water: ď‚—The endless circulation of water between atmosphere, lithosphere, hydrosphere and biosphere is known as hydrologic cycle. ď‚—We get water from Precipitation of water vapor in the atmosphere
  • 4. World’s Water Distribution:World’s Water Distribution: ď‚—Earth has tremendous amount of water ď‚—Three fourth’s of the earth surface is covered by water ď‚—97% of World’s water is in the seas and oceans. This water is saline. ď‚—Only 3% is present on the continents. This water is fresh. ď‚—The distribution of water over land is uneven.
  • 5. Water is everywhere:Water is everywhere: ď‚—Water is a common substance. ď‚—It fills the oceans, rivers, and lakes. ď‚—It is in the ground and also in the air we breathe. ď‚—Water is used for drinking, all domestic purposes, agriculture, industrial applications, cleaning and recreation.
  • 6. Quality determines its Usage:Quality determines its Usage: ď‚—Water has its own taste, color, smell and constituents. ď‚—Not all water can be used for all purposes. ď‚—Eg. Sea water can not be used by us for drinking. ď‚—The suitability of water for different purposes is determined by its quality parameters.
  • 7. Quantity and quality:Quantity and quality: ď‚—On an average, each person in a developed country uses about 260 litres of water a day in the home. ď‚—The Quality of water is equally important than quantity. ď‚—Even if present in huge amounts, we can not use salt water in many life support activities.
  • 8. Characteristics ofCharacteristics of Water:Water: ď‚—Water is a good solvent ď‚—Water never occurs in its pure form ď‚—All waters contain some dissolved substances ď‚—The quality of water is determined by these substances. ď‚—It has the ability to dissolve many inorganic and organic substances.
  • 9. Water Quality Parameters:Water Quality Parameters: Water has its own ď‚—Physical properties ď‚—Chemical composition and ď‚—Biological Properties
  • 11. Temperature (T) of Water:Temperature (T) of Water: ď‚—Essential for all environmental studies ď‚—Controls many ecological processes including chemical reactions. ď‚—T of surface water varies from space and time ď‚—T of groundwater varies not only with reference to space and time but also with reference to depth.
  • 12. Temperature of Water:Temperature of Water: ď‚—Measured using Thermometers ď‚—It ranges from 0 to 100 degree Celsius ď‚—Unit of measurement is degree Celsius ď‚—The temperature of Surface water is influenced by the atmospheric conditions ď‚—The temperature of groundwater is controlled by the thermal characteristics of bedrocks and the depth.
  • 13. Color of water:Color of water: ď‚—The color of water is due to the suspended particles and organic matter ď‚—Ranges form light to dark brown ď‚—Brownish color in water comes due to the presence of iron ď‚—Greenish color in pond water is seen due to the presence of organic substances including algae
  • 14. OdorOdor:: ď‚—Pure water is odorless ď‚—When water dissolves other substances, the odor is determined by them ď‚—Mostly decayed organic substances give fouling smell ď‚—Inorganic substances give earthy smell
  • 15. Turbidity:Turbidity: ď‚—Muddiness in water ď‚—Comes due to suspended particles from clay, silt and organic matter ď‚—Controls the transparency of water ď‚—Transparency is measured using Secchi Disc ď‚—Water Turbidity is measured using Nephelometer
  • 16. Electrical Conductivity(EC):Electrical Conductivity(EC): ď‚—Ability of a substance to conduct an electrical current. ď‚—The presence of charged ionic species makes water conductive. ď‚—It is measured using EC meters. ď‚—Directly related to temperature of water. ď‚—Unit of measurement is mmhos/cm at std temperatures. Ranges from 100-1,00,000 ď‚—Pure water is less conductive
  • 17. Chemical properties:Chemical properties: ď‚—pH ď‚—Total Dissolved Solids(TDS) ď‚—Major ions ď‚—Minor or trace elements ď‚—Hardness ď‚—Salinity ď‚—Alkalinity
  • 18. pH of water:pH of water: ď‚—Refers to the effective concentration of hydrogen ions in water ď‚—It ranges from 0 to 14. Measured using pH meters ď‚—Water is said to be acidic( less than 7) or alkaline ( above 7) depending on the relative concentration of hydrogen ions from the neutral value which is 7.
  • 19. Total DissolvedTotal Dissolved Solids(TDS):Solids(TDS): ď‚—Concentration of non-volatile substances present in colloidal or molecular state ď‚—Total of all ions present in water, expressed in ppm or mg/L ď‚—Increases due to dissolution of more mineral substances by water on its path ď‚—TDS determines the suitability of water for our use and consumption.
  • 20. Quality of Water :Quality of Water : ď‚—Total dissolved solids(ppm) ď‚—< 1000 fresh water ď‚—1000-10,000 brackish water ď‚—10,000 to 1,00,000 saline ď‚—> 1,00,000 hypersaline or brine
  • 21. Classification of DissolvedClassification of Dissolved constituents:constituents: ď‚—Basis of concentrations- mg/L ď‚—Charges( positive or negative) ď‚—Level of Toxicity ( toxic or non-toxic)
  • 22. Based on Concentrations:Based on Concentrations: ď‚—Major ions( > 10 mg/L) â—¦ Mostly Bicarbonate, calcium, Magnesium, Chloride, sodium, sulphate and silicon ď‚—Minor ions ( 0.1-10 mg/L) â—¦ Mostly Carbonate, fluoride, nitrate, potassium, iron, strontium, boron. ď‚—Trace elements( < 0.1 mg/L) â—¦ Mostly Aluminium, Arsenic, Barium, Bromide, Cadmium, Chromium, Cobalt, Copper, Lead, Zinc, Nickel, Phosphate, Silver, Tin and Vanadium.
  • 23. Based on ionic Charges:Based on ionic Charges: ď‚—Major ions ď‚—Positively charged = Cations ď‚—Negatively charged = anions
  • 24. Major Cations in water:Major Cations in water: ď‚—Calcium ď‚—Magnesium ď‚—Sodium ď‚—Potassium ( Source: lithosphere)
  • 25. Major Anions in Water:Major Anions in Water: ď‚—Bicarbonate ď‚—Carbonate ď‚—Chloride ď‚—Sulphate ď‚—Nitrate ď‚—Phosphate
  • 26. Trace elements in water:Trace elements in water: ď‚—Play a significant role in the use of water ď‚—Some are essential elements for health & growth ď‚—Some are injurious to health and toxic also. ď‚—Deficiency or excess intake of some of these elements may cause serious health problems to life.
  • 27. Hardness:Hardness: ď‚—Hardness of water is defined as its content of metallic ions which react with sodium soaps to produce a residue ď‚—Expressed as total concentration of Calcium and Magnesium in ppm. ď‚—Total hardness= 2.5 Ca + 4.1 Mg. ď‚—Softwater (Temporary) ď‚—Hardwater (permanent ).
  • 28. Salinity of Water:Salinity of Water: ď‚—Comes due to sodium and chloride ď‚—Sea water contains 35,000 ppm or mg/L of dissolved salts
  • 29. Alkalinity of water:Alkalinity of water: ď‚—Combined effect of Bicarbonates and Carbonates with calcium ions ď‚—It has a direct relationships with pH. ď‚—Carbonates will be noticeable for water having a pH of more than 8.2
  • 30. Biological Properties:Biological Properties: ď‚—Dissolved Oxygen (DO) ď‚—Biochemical Oxygen Demand(BOD) ď‚—Chemical oxygen Demand(COD) ď‚—Microorganisms-Bacterial counts
  • 31. Dissolved Oxygen(DO):Dissolved Oxygen(DO): ď‚—Is related to the solubility of air in water at 0 deg. C ď‚—Solubility of oxygen in water decreases with high temperatures ď‚—Important property for aquatic organisms ď‚—Surface water bodies should have enough DO ď‚—If DO depletes, it will be difficult to many aquatic organisms for their survival.
  • 32. Biochemical OxygenBiochemical Oxygen Demand(BOD):Demand(BOD): ď‚—Is a measure of the biodegradable material ď‚—It is determined by incubating a water sample and measuring the decrease in dissolved oxygen as bacteria decompose these materials.
  • 33. Chemical OxygenChemical Oxygen Demand(COD):Demand(COD): ď‚—Is determined by chemical oxidation of water with dichromate
  • 34. Water Quality Parameters:Water Quality Parameters: ď‚—Limits the suitability of water for different purposes ď‚—Drinking ď‚—Domestic consumption ď‚—Agriculture ď‚—Industrial Processes ď‚—Cleaning and Recreation.
  • 35. Water QualityWater Quality StandardsStandards ď‚—Permissible limits ď‚—United States Public Health Drinking Water Standards(USPH) ď‚—Indian Standards Institution (ISI) ď‚—World Health Organization (WHO)