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ANATEXIS AND URANIUM PROTORE IN
THE WOLLASTON DOMAIN,
SASKATCHEWAN
 McKechnie, Christine L. 1
 Annesley, Irvine R. 1, 2, and Ansdell, Kevin M.1




                                             1
                                              Department of Geological Sciences, University of
  Goldschmidt 2012                           Saskatchewan
     June 2012                               2
                                                 JNR Resources Inc., Saskatoon, SK
Outline
 • Geological Setting
 • Pegmatite Mineralogy and Geochemistry
 • Model for Granitic Pegmatite/Leucogranite
   Generation
 • U protore?

The aim of this project was to determine whether
  these [granitic pegmatites and leucogranites]
represent a distinct target for uranium exploration
 in Saskatchewan and/or if the mineralization is
 somehow related to unconformity-type uranium
                      deposits
Regional Geology
•   Hearne Province
•   Deformed and metamorphosed
    during the Paleoproterozoic
    (ca. 1.9-1.8 Ga) Trans-Hudson
    Orogeny (THO)
•   ~ 25 km SE of the
    Mesoproterozoic Athabasca
    Basin
•   In the Eastern Wollaston
    Domain, which consists of:
     • Archean orthogneisses
        (mostly granitic)
     • Paleoproterozoic Wollaston
        Group metasedimentary
        rocks
     • Hudsonian granites,
        amphibolites, migmatites,
        leucogranites, and granitic
        pegmatites
•   Study area shown in red box
Fraser Lakes Geology
•   NE-SW regional
    fabric
•   Zone A is in a NNE-                                                                      es
                                                                          up s s
                                                                        ro nei
                                                                      G g
    plunging synformal                                              on ary
                                                                  st t
    and Zone B is in an                                      o lla en
                                                          W dim
    NNE-plunging                                           ta
                                                              se
                                                         e
    antiformal fold nose                                m




                                                                                            se nta p
                                                                                        e is e o u
                                                                                                  ry
•   5 km section of a                                                           r                                                er
                                                                                                                               iv r




                                                                                     gn edim Gr
                                                                         li e                                                 R ie
                                                                       In                                                 on I nl




                                                                                       as o n
    complexly folded




                                                                                              s
                                                                  te                                                    ns te
                                                               ni




                                                                                     et st
                                                             a                                                        oh a ni




                                                                                    m olla
    electromagnetic                                     Gr                                                           J r
                                                                                                                       G
                                                   es




                                                                                     W
                                               k
    (EM) conductor (i.e.                rL
                                           a
                               as
                                    e
                                                                                                                                 o   ne
    graphitic pelitic        Fr                                                                                               rZ
                                                                                                                        a
    gneisses) is                                   Fraser Lakes
                                                                                                                     She     ai n
                                                      Zone B                                                     lls      om
    adjacent to Zones A                                                                                        Fa      eD
                                                                                                                         ak
                                                                                                          le           rL
    and B                  Fraser Lakes Zone A                                                         ed            e
                                                                                                  Ne
                                                                                                                 t
                                                                                                               Pe


                                                                                                                     After Ray, 1979
Fraser Lakes Geology




 After Ko, 1971
Granitic pegmatites and
    leucogranites
•   Granitic pegmatites and
    leucogranites with
    variable amounts of quartz,
    feldspar, biotite, and other
    minerals
•   Overall coarse grained to
    pegmatitic
•   Variable width (cm to dm scale)
•   Complexly zoned (igneous AFC
    processes)
•   Multiple generations of
    granitic pegmatites
•   1850-1780 Ma U-Pb
    chemical ages (CHIME)
    for magmatic uraninite
Mineralogy
     Highly Variable!




 * Magmatic and/or peritectic minerals
Group A and Group B Granitic
 Pegmatites/Leucogranites
   Group A Intrusives                 Group B Intrusives
• Contain abundant uraninite,       • Monazite-rich w/ zircon, thorite,
  thorite, and zircon and minor       allanite, and xenotime
  allanite                          • Intrude the central part of the
• Intrude the western part of the     antiformal fold nose
  antiformal fold nose
Major element
 geochemistry
• Group A intrusives tend to
  be more Si-rich than
  Group B intrusives, with
  significant overlap
• Group B intrusives overlap
  with pelitic gneisses
• Controlled by sample
  mineralogy
  • (i.e. high SiO2 = quartz-rich;
   low SiO2= higher
   mafics/oxide content)
• Controlled by host rock
 composition
  • Archean granitic
   orthogneisses vs. Wollaston
   Group metasedimentary
   gneisses
Trace element geochemistry
• The two groups
 also have
 dissimilar trace
 element
 geochemistry
 related to their
 accessory
 mineral contents
  • U- plus Th-
    rich (Group A)
  • Th- and
    LREE-rich
    (Group B)
REE Geochemistry
   Group A Intrusives            Group B Intrusives
• Generally flat or slightly   • Generally show LREE
 HREE-enriched patterns,        enriched patterns, higher
 low total REE content,         total REE content, and
 variable Eu anomalies          strong –Eu anomalies
Metamorphic Mineral Assemblages
    in host migmatitic pelitic gneisses
• Garnet
• Biotite
• Cordierite
• Sillimanite
• Spinel
• Quartz
• Plagioclase
• K-feldspar
• Rutile
• Myrmekite
•   NO prograde
    muscovite

Upper amphibolite
to granulite facies
   peak thermal
  metamorphism
    during THO
Granitic Pegmatites /
 Leucogranites –
 Partial melting at depth vs. in-
 situ?
• Migmatites in close association with
  the radioactive intrusives
• Leucosomes tend to be boudinaged,
  but also form small pegmatitic veins
• Crystallized melt occasionally
  forms thin rims around minerals,
  and locally larger blobs
• Biotite frequently shows
  degradation due to partial melting
Model for Fraser Lakes Zone B granitic
    pegmatites/leucogranite-hosted mineralization
    schematic mid-crustal cross-sections
• Primary magmatic U (+/-Th, REE) mineralization within late-tectonic granitic
     pegmatites and leucogranites; 1850-1780 Ma (related to THO)
•    Partial melting of metasedimentary gneisses (i.e. Wollaston Group equivalent)
     at depth during peak thermal metamorphism (THO)
•    Melt migrated upwards along the structural discontinuity/contact between
     Archean and Wollaston Group, undergoing igneous assimilation-fractional
     crystallization (cross-section A)
•    Melts concentrated preferentially in antiformal fold noses
•    Similarities to Rössing and Husab (formerly Rössing South) uranium deposits in
     Namibia (cross-section B)




A) Modified from Ray, 1979                                B) Extract Resources, 2009
Granitoid-hosted U mineralization




After Parslow and Thomas, 1982   after Cuney, 2005
Alteration of granitic
pegmatites/leucogranites and
remobilization of U, Th, Pb
Post-Crystallization
Alteration (during cooling)
•Chlorite (Chl)
•Epidote (Ep)
•Sericite (Ser)
•Quartz (Qtz)


Hydrothermal Alteration
•Fluorite (Fl)
•Chlorite (Chl)
•Hematite (Hem)
•Clay minerals
•Sausserite
•Carbonate (Cal)
•Quartz (Qtz)
•With secondary hydrothermal
U-Th-REE minerals
U protore?
• Chlorite, clay (including illite), and
    hematite alteration found drill core;
    similar to that of basement-hosted
    unconformity-type U deposits
•   Erosion to an estimated depth of
    150-200 m below the Athabasca/
    basement unconformity
•   Brittle faulting cross-cuts the
    mineralized zone
      • Conduit for fluid and heat flow?
•   Uranium (and other metals)
    remobilized along fractures away
    from primary magmatic uraninite
•   Alteration of monazite may have
    also led to uranium remobilization
•   Drilling has yet to intersect a
    basement-hosted unconformity-
    type U deposit in the area – does
    not mean it does not exist
                                            Modified from Ray, 1979
Unconformity-type uranium deposits: possible
model
  Evaporated Sea Water: high salinity fluids [Cl]
                          Richard et al. (2011)
                          Geochim. Comsochim. Acta 75, 2792-2810
                          Mercadier et al., (2012) Geology              Sea

                                                            Basin 1.75-1.5 Ga         ty
percolation into the                                                                mi
                                              1.4–1.1 Ga UO2                   n for
basement with leaching                                                       co
Mercadier et al. (2010)                       +/- REEs, Au, Cu,           Un
Lithos 115, 121-136                           Co, Ni, As…                Basement 2.8 - 1.7 Ga
                                      ore
                                                                  [U]crust ~ 1.7 ppm
                                                                                       × 105 !!!
                                                                  [U]ore ~ 20%
                                                      UO2 > 20%
       Abundant U source
(e.g. monazites, uraninites)                                              Up to 200.000 t U at
        Hecht & Cuney (2000)                    Fraser Lakes              approx. 20%: Giant
 Mineral. Deposita 35, 791-795                  Zone B                    uranium deposits of
                 Salinity [U]: 10-6 to 10-2 mol/L, pH:3-4.5                   high grade
                 Richard et al. (2012), Nature Geoscience

      cf. presentations of Michel Cathelineau, 2011 and Mercadier et al., 2012
Conclusions
•   Structurally controlled, basement-hosted magmatic U and Th mineralization (+/-
    REE mineralization)

•   Hosted by Hudsonian granitic pegmatites and leucogranites intruding at/near
    the highly deformed contact between Wollaston Group metasediments and
    Archean orthogneisses

•   Formed by partial melting of metasedimentary rocks in the middle to lower crust
    followed by transport and assimilation-fractional crystallization

•   Similarities to Rössing and Husab (Rössing South) granitoid-hosted U deposits

•   Granitic pegmatites experienced post-crystallization alteration and
    remobilization of U and Th and other metals

•   The magmatic U mineralization is potential protore for basement-hosted
    unconformity-type uranium deposits in the Fraser Lakes area (yet-to-be
    discovered) and elsewhere in the Wollaston Domain and Athabasca Basin

•   Magmatic U mineralization may represent a new type of economic uranium
    deposit in northern Saskatchewan
Questions?

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McKechnie et al. 2012 Goldschmidt talk

  • 1. ANATEXIS AND URANIUM PROTORE IN THE WOLLASTON DOMAIN, SASKATCHEWAN McKechnie, Christine L. 1 Annesley, Irvine R. 1, 2, and Ansdell, Kevin M.1 1 Department of Geological Sciences, University of Goldschmidt 2012 Saskatchewan June 2012 2 JNR Resources Inc., Saskatoon, SK
  • 2. Outline • Geological Setting • Pegmatite Mineralogy and Geochemistry • Model for Granitic Pegmatite/Leucogranite Generation • U protore? The aim of this project was to determine whether these [granitic pegmatites and leucogranites] represent a distinct target for uranium exploration in Saskatchewan and/or if the mineralization is somehow related to unconformity-type uranium deposits
  • 3. Regional Geology • Hearne Province • Deformed and metamorphosed during the Paleoproterozoic (ca. 1.9-1.8 Ga) Trans-Hudson Orogeny (THO) • ~ 25 km SE of the Mesoproterozoic Athabasca Basin • In the Eastern Wollaston Domain, which consists of: • Archean orthogneisses (mostly granitic) • Paleoproterozoic Wollaston Group metasedimentary rocks • Hudsonian granites, amphibolites, migmatites, leucogranites, and granitic pegmatites • Study area shown in red box
  • 4. Fraser Lakes Geology • NE-SW regional fabric • Zone A is in a NNE- es up s s ro nei G g plunging synformal on ary st t and Zone B is in an o lla en W dim NNE-plunging ta se e antiformal fold nose m se nta p e is e o u ry • 5 km section of a r er iv r gn edim Gr li e R ie In on I nl as o n complexly folded s te ns te ni et st a oh a ni m olla electromagnetic Gr J r G es W k (EM) conductor (i.e. rL a as e o ne graphitic pelitic Fr rZ a gneisses) is Fraser Lakes She ai n Zone B lls om adjacent to Zones A Fa eD ak le rL and B Fraser Lakes Zone A ed e Ne t Pe After Ray, 1979
  • 5. Fraser Lakes Geology After Ko, 1971
  • 6. Granitic pegmatites and leucogranites • Granitic pegmatites and leucogranites with variable amounts of quartz, feldspar, biotite, and other minerals • Overall coarse grained to pegmatitic • Variable width (cm to dm scale) • Complexly zoned (igneous AFC processes) • Multiple generations of granitic pegmatites • 1850-1780 Ma U-Pb chemical ages (CHIME) for magmatic uraninite
  • 7. Mineralogy Highly Variable! * Magmatic and/or peritectic minerals
  • 8. Group A and Group B Granitic Pegmatites/Leucogranites Group A Intrusives Group B Intrusives • Contain abundant uraninite, • Monazite-rich w/ zircon, thorite, thorite, and zircon and minor allanite, and xenotime allanite • Intrude the central part of the • Intrude the western part of the antiformal fold nose antiformal fold nose
  • 9. Major element geochemistry • Group A intrusives tend to be more Si-rich than Group B intrusives, with significant overlap • Group B intrusives overlap with pelitic gneisses • Controlled by sample mineralogy • (i.e. high SiO2 = quartz-rich; low SiO2= higher mafics/oxide content) • Controlled by host rock composition • Archean granitic orthogneisses vs. Wollaston Group metasedimentary gneisses
  • 10. Trace element geochemistry • The two groups also have dissimilar trace element geochemistry related to their accessory mineral contents • U- plus Th- rich (Group A) • Th- and LREE-rich (Group B)
  • 11. REE Geochemistry Group A Intrusives Group B Intrusives • Generally flat or slightly • Generally show LREE HREE-enriched patterns, enriched patterns, higher low total REE content, total REE content, and variable Eu anomalies strong –Eu anomalies
  • 12. Metamorphic Mineral Assemblages in host migmatitic pelitic gneisses • Garnet • Biotite • Cordierite • Sillimanite • Spinel • Quartz • Plagioclase • K-feldspar • Rutile • Myrmekite • NO prograde muscovite Upper amphibolite to granulite facies peak thermal metamorphism during THO
  • 13. Granitic Pegmatites / Leucogranites – Partial melting at depth vs. in- situ? • Migmatites in close association with the radioactive intrusives • Leucosomes tend to be boudinaged, but also form small pegmatitic veins • Crystallized melt occasionally forms thin rims around minerals, and locally larger blobs • Biotite frequently shows degradation due to partial melting
  • 14. Model for Fraser Lakes Zone B granitic pegmatites/leucogranite-hosted mineralization schematic mid-crustal cross-sections • Primary magmatic U (+/-Th, REE) mineralization within late-tectonic granitic pegmatites and leucogranites; 1850-1780 Ma (related to THO) • Partial melting of metasedimentary gneisses (i.e. Wollaston Group equivalent) at depth during peak thermal metamorphism (THO) • Melt migrated upwards along the structural discontinuity/contact between Archean and Wollaston Group, undergoing igneous assimilation-fractional crystallization (cross-section A) • Melts concentrated preferentially in antiformal fold noses • Similarities to Rössing and Husab (formerly Rössing South) uranium deposits in Namibia (cross-section B) A) Modified from Ray, 1979 B) Extract Resources, 2009
  • 15. Granitoid-hosted U mineralization After Parslow and Thomas, 1982 after Cuney, 2005
  • 16. Alteration of granitic pegmatites/leucogranites and remobilization of U, Th, Pb Post-Crystallization Alteration (during cooling) •Chlorite (Chl) •Epidote (Ep) •Sericite (Ser) •Quartz (Qtz) Hydrothermal Alteration •Fluorite (Fl) •Chlorite (Chl) •Hematite (Hem) •Clay minerals •Sausserite •Carbonate (Cal) •Quartz (Qtz) •With secondary hydrothermal U-Th-REE minerals
  • 17. U protore? • Chlorite, clay (including illite), and hematite alteration found drill core; similar to that of basement-hosted unconformity-type U deposits • Erosion to an estimated depth of 150-200 m below the Athabasca/ basement unconformity • Brittle faulting cross-cuts the mineralized zone • Conduit for fluid and heat flow? • Uranium (and other metals) remobilized along fractures away from primary magmatic uraninite • Alteration of monazite may have also led to uranium remobilization • Drilling has yet to intersect a basement-hosted unconformity- type U deposit in the area – does not mean it does not exist Modified from Ray, 1979
  • 18. Unconformity-type uranium deposits: possible model Evaporated Sea Water: high salinity fluids [Cl] Richard et al. (2011) Geochim. Comsochim. Acta 75, 2792-2810 Mercadier et al., (2012) Geology Sea Basin 1.75-1.5 Ga ty percolation into the mi 1.4–1.1 Ga UO2 n for basement with leaching co Mercadier et al. (2010) +/- REEs, Au, Cu, Un Lithos 115, 121-136 Co, Ni, As… Basement 2.8 - 1.7 Ga ore [U]crust ~ 1.7 ppm × 105 !!! [U]ore ~ 20% UO2 > 20% Abundant U source (e.g. monazites, uraninites) Up to 200.000 t U at Hecht & Cuney (2000) Fraser Lakes approx. 20%: Giant Mineral. Deposita 35, 791-795 Zone B uranium deposits of Salinity [U]: 10-6 to 10-2 mol/L, pH:3-4.5 high grade Richard et al. (2012), Nature Geoscience cf. presentations of Michel Cathelineau, 2011 and Mercadier et al., 2012
  • 19. Conclusions • Structurally controlled, basement-hosted magmatic U and Th mineralization (+/- REE mineralization) • Hosted by Hudsonian granitic pegmatites and leucogranites intruding at/near the highly deformed contact between Wollaston Group metasediments and Archean orthogneisses • Formed by partial melting of metasedimentary rocks in the middle to lower crust followed by transport and assimilation-fractional crystallization • Similarities to Rössing and Husab (Rössing South) granitoid-hosted U deposits • Granitic pegmatites experienced post-crystallization alteration and remobilization of U and Th and other metals • The magmatic U mineralization is potential protore for basement-hosted unconformity-type uranium deposits in the Fraser Lakes area (yet-to-be discovered) and elsewhere in the Wollaston Domain and Athabasca Basin • Magmatic U mineralization may represent a new type of economic uranium deposit in northern Saskatchewan

Editor's Notes

  1. Area was Multiply deformed and metamorphosed about 1.8 Ga during the THO End of this slide – next slide we’ll focus in on the local Fraser Lakes area
  2. Refolded fold structure – polyphase folding – defined by lithological units and EM conductor Superimposed ductile-brittle (E-W) and brittle structures (NNE and NNW) Hint that pink is Archean, grey, yellow and blue metasediments, intrusives (pink-pegmatites)
  3. Refolded fold structure – polyphase folding – defined by lithological units and EM conductor Superimposed ductile-brittle (E-W) and brittle structures (NNE and NNW) Hint that pink is Archean, grey, yellow and blue metasediments, intrusives (pink-pegmatites)
  4. Late tectonic to post tectonic pegmatites Unmineralized pegmatites tend to be later, but not always the case
  5. Predominantly peraluminous Classified as s-type granitoids
  6. Add circles red and blue around u and th pegmatites make th and lree blue
  7. Introduce title and that it is a cross-section Melt Transfer zone Bottom part gt rich Mid crd + gt Upper crd Gt in pegmatites – coming from deeper, gt-sill-crd host rock, middle to upper zone
  8. Combine with previous slide (not sure how I am doing that yet!)???