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! 
‘Porcelain layerying on zirconia coping’ives 
Department of Fixed Prosthodontics and Dental Materials 
Tuscan School of Dental Medicine 
University of Florence and Siena, Italy 
Dean, Chair: Prof. Dr. Marco Ferrari, MD, DDS, Ph D
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GCem with Zirconia crowns after 36-48 months
GCem with Zirconia crowns after 60 months
LinkAce with Zirconia crowns after 12 months
Experimental primer is very effective
3Y-TZP Mechanical complications 
Materials and Methods 
Aim of the study: to evaluate the influence of different framework design on 
PFM Design 
Flat Design 
Ribbings Design 
fracture resistance of zirconia crowns layered with porcelain
3Y-TZP Mechanical complications 
Materials and Methods 
! 
3 groups (n=10) of crowns made on extracted bycuspids are prepared for full crowns. The three groups will have 
framework without any design (Group 1), with PFM Design (Group 2) and Ribbings Design (Group 3). 
All casts will be made with Aadva zirconia material. Initial will be used by a single technician for layering in a costant and 
uniform thickness. 
After being luted with GCem, each samples will be under continuos loading till fracture. The fracture resistance will be 
recorded and statistical analysis will be made. After fracture, each crown will be evaluated under SEM in order to detect the 
type of failures. 
! 
!
IADR-SEATTLE 2013 
#174948 
Fracture Resistance of three Porcelain-layered CAD-CAM Zirconia Frame Designs 
M. FERRARI1, A. VICHI2, A. GIOVANNETTI2, G. BONADEO3, C. RENGO4, and C. GORACCI3, 1Dental Materials and Fixed Prosthodontics - University of Siena, Tuscan School of Dental Medicine - University of Firenze and Siena, Livorno, 
Italy, 2Dental Materials and Fixed Prosthodontics - University of Siena, Tuscan School of Dental Medicine - University of Firenze and Siena, Grosseto, Italy, 3Dental Materials and Fixed Prosthodontics - University of Siena, Tuscan 
School of Dental Medicine - University of Firenze and Siena, Siena, Italy, 4Dental Materials and Fixed Prosthodontics - University of Siena, Tuscan School of Dental Medicine -University of Firenze and Siena, Napoli, Italy 
Objective: Chipping is the most frequent clinical failure of zirconia crowns. Causes of chipping have not been completely understood and different possible reasons have been considered. The study 
was aimed at evaluating the fracture resistance of 3 different CAD-CAM zirconia frame designs veneered with porcelain. 
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Dental Materials 2014! 
Fracture resistance of three porcelain-layered! 
CAD/CAM zirconia frame designs! 
Marco Ferrari, Agostino Giovannetti, Michele Carrabba,! 
Giovanni Bonadeo, Carlo Rengo, Francesca Monticelli,! 
Alessandro Vichi.!
Method: Thirty extracted sound premolars were divided into 3 groups (n=10). 
Silicon impressions of the crowns were taken. 
Chamfer preparations were performed, impressions were taken, and dies were prepared. 
Three zirconia frame designs (Aadva, GC) were realized: 1. reproduction of the abutment contour (flat design, FD); 2. wax-up as for 
porcelain-fused-to-metal crowns (PFM); 3. anatomically-guided, designed to keep constant the thickness of the overlying porcelain 
veneering (AG). 
! 
! 
! 
! 
! 
! 
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Porcelain veneering was made with pressure layering technique (Initial Zr, GC) 
using the previously obtained silicon impressions.
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Crowns were cemented utilizing a self-adhesive resin cement (G-Cem, GC). 
After a 24-hour water storage at 37°C, using a universal testing machine (1mm crosshead speed), 
crowned teeth were loaded in the central fossa with a round-tip stainless steel rod of 2 mm in 
diameter in a direction parallel to the longitudinal axis of the tooth. 
Loading was applied until fracture occurred and load at fracture was recorded in Newtons (N). 
! 
Digital photographs of the failed specimens were taken in order to assess failure patterns. 
! 
Between-group differences in fracture strength were statistically analyzed 
(One-Way Analysis of Variance, Tukey test, p<0.05)
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Results: Load at fractures differed significantly among the groups (p=0.004). 
AG exhibited significantly higher fracture resistance (1721,6±488,1 N) than PFM (1004,6±321,3 N) and FD (1179,5±536,2 N), that were comparable. 
Repairable failures occurred in 80% of AG, 70% of PFM, and 50% of FD specimens. 
!!!!!!!!!!!!!!!!!! 
Newton( FRACTURE(TEST( 
1179,563( 
1004,681( 
1721,664( 
2500" 
2000" 
1500" 
1000" 
500" 
0" 
I.LISC( II.BORD( III.RID(MAS( 
FAILURE&PATTERNS& 
50%$ 
100%$ 
80%$ 
60%$ 
40%$ 
20%$ 
Conclusion: Anatomically-guided zirconia frames resisted significantly higher loads than flat and PFM-like frame designs. 
70%$ 
80%$ 
50%$ 
30%$ 
20%$ 
0%$ 
I"LISC& II"BORD& III"RID&MAS& 
NR$ 
R$ 
GROUPS:( I*LISC( (( FRACTURE(MODE:( R:(restorable( FRACTURE(MODE(2:(separated(evalua@on(for(crown(and(tooth( 
(( II*BORD( NR:(non(restorable( CE:(cipping(with(zirconia(exposi@on( (( 
(( III*RID(MAS( (( (( (( (( C:(cipping(without(zirconia(axposi@on( (( 
FV:(ver@cal(fracture( (( 
FO:(orizontal(fracture( (( (( (( (( 
MEAN( SD( R( NR( 
I*LISC( 1179,563( 
536,25517 
72( I*LISC( 50%( 50%( 
II*BORD( 1004,681( 
321,32031 
78( II*BORD( 70%( 30%( 
III*RID(MAS( 1721,664( 
488,11936 
04( III*RID(MAS( 80%( 20%(
Clinical evaluation 
! 
3 groups of 20 samples each 
Single unit zirconia/porcelain crowns 
3 different anatomic designs 
Clinical parameters over time of clinical service 
such as chipping, marginal leakage, postop sensitivity 
! 
! 
! 
vs 
vs 
vs
Clinical trial of three framework designs of porcelain layered zirconia crowns: 18 months preliminary results. 
i-ZirK ™
Clinical evaluation
New Clinical trial 
! 
2 groups of 20 samples each 
Single unit zirconia/porcelain crowns 
1 different anatomic designs vs monolitic crowns 
Clinical parameters over time of clinical service 
such as chipping, marginal leakage, postop sensitivity 
! 
! 
! 
vs
Clinical eva!luation 
2 groups of 10 samples each 
Three- unit zirconia/porcelain bridges 
2 different anatomic designs 
Clinical parameters over time of clinical service 
such as chipping, marginal leakage, postop sensitivity 
! 
! 
! 
!
ORIGINAL ARTICLE J Adv Prosthodont 2011;3:57-62!DOI:10.4047/jap.2011.3.2.57 
The effect of ceramic thickness and number of firings on the color of a zirconium oxide based all 
ceramic system fabricated using CAD/CAM technology 
14 
Vinay Chila Bachhav*, MDS, Meena Ajay Aras, MDS 
! 
Department of Prosthodontics, Goa Dental College and Hospital, Bambolim, Goa, India 
PURPOSE. Ceramics have a long history in fixed prosthodontics for achieving optimal esthetics and various materials have been used to improve ceramic core strength. However, there is a lack of information on how color is 
affected by fabrication procedure. The purpose of this study was to evaluate the effects of various dentin ceramic thicknesses and repeated firings on the color of zirconium oxide all-ceramic system (LavaTM) fabricated using 
CAD/CAM technology. MATERIALS AND METHODS. Thirty disc-shaped cores, 12 mm in diameter with a 1 mm thickness were fabricated from zirconium oxide based all ceramic systems (LavaTM, 3M ESPE, St Paul, MN, USA) 
and divided into three groups (n = 10) according to veneering with dentin ceramic thicknesses: as 0.5, 1, or 1.5 mm. Repeated firings (3, 5, 7, or 9) were performed, and the color of the specimens was compared with the color 
after the initial firing. Color differences among ceramic specimens were measured using a spectrophotometer (VITA Easyshade, VITA Zahnfabrik, Bad S ̈ackingen, Germany) and data were expressed in CIELAB system 
coordinates. A repeated measures ANOVA and Bonferroni post hoc test were used to analyze the data (n = 10, α=.05). RESULTS. L*a*b* values of the ceramic systems were affected by the number of firings (3, 5, 7, or 9 firings) 
(P<.001) and ceramic thickness (0.5, 1, or 1.5 mm) (P<.001). Significant interactions were present in L*a*b* values between the number of firings and ceramic thickness (P<.001). An increase in number of firings result- ed in 
significant increase in L* values for both 0.5 mm and 1.5 mm thicknesses (P<.01, P=.013); however it decreased for 1 mm thickness (P<.01). The a* values increased for 1 mm and 1.5 mm thicknesses (P<.01), while it decreased 
for 0.5 mm specimens. The b* values increased sig- nificantly for all thicknesses (P<.01, P=.022). As the dentin ceramic thickness increased, significant reductions in L* values (P<.01) were record- ed. There were significant 
increases in both a* and b* values (P<.01) as the dentin ceramic thickness increased. CONCLUSION. The num- ber of firings and dentin ceramic thickness have a definite effect on the final color of all ceramic system tested. The 
mean ΔE value increased as the dentin ceramic thicknesses increased for zirconium-oxide based all ceramic specimens tested. However, the mean ΔE values were less than 3.7ΔE units which is rated as a match in the oral 
environment. [J Adv Prosthodont 2011;3:57-62] 
i-ZirK ™
Group 1 
Bar of 1,2 mm porcelain layered in one firing with 
porcelain thickness of 0.8 mm 
! 
Group 1II 
Bar of 0,8 mm porcelain layered in five firings with porcelain 
thickness of 1.2 mm 
Effect of repeated firings on flexural strength of veneered zirconia. 
Carabba M, Vichi A, Ferrari M 
Submitted to Dental Materials 
Group 1I 
Bar of 0,8 mm porcelain layered in one firing with 
porcelain thickness of 1.2 mm
Materials and Methods 
ISO Standard 6872:2008 - Dentistry - Ceramic materials
F – (Fresati) Grounded 
FR – (Fresati, rigenerati) Grounded and regenerated 
LR – (Lucidati, rigenerati) Untouched and regenerated 
L – (Lucidati) Untouched
i-ZirK™ InternalStains
Porcelain Layering On Zirconia Coping
Porcelain Layering On Zirconia Coping

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Porcelain Layering On Zirconia Coping

  • 1. ! ‘Porcelain layerying on zirconia coping’ives Department of Fixed Prosthodontics and Dental Materials Tuscan School of Dental Medicine University of Florence and Siena, Italy Dean, Chair: Prof. Dr. Marco Ferrari, MD, DDS, Ph D
  • 2.
  • 5. GCem with Zirconia crowns after 36-48 months
  • 6. GCem with Zirconia crowns after 60 months
  • 7. LinkAce with Zirconia crowns after 12 months
  • 8.
  • 9.
  • 10.
  • 11. Experimental primer is very effective
  • 12. 3Y-TZP Mechanical complications Materials and Methods Aim of the study: to evaluate the influence of different framework design on PFM Design Flat Design Ribbings Design fracture resistance of zirconia crowns layered with porcelain
  • 13. 3Y-TZP Mechanical complications Materials and Methods ! 3 groups (n=10) of crowns made on extracted bycuspids are prepared for full crowns. The three groups will have framework without any design (Group 1), with PFM Design (Group 2) and Ribbings Design (Group 3). All casts will be made with Aadva zirconia material. Initial will be used by a single technician for layering in a costant and uniform thickness. After being luted with GCem, each samples will be under continuos loading till fracture. The fracture resistance will be recorded and statistical analysis will be made. After fracture, each crown will be evaluated under SEM in order to detect the type of failures. ! !
  • 14. IADR-SEATTLE 2013 #174948 Fracture Resistance of three Porcelain-layered CAD-CAM Zirconia Frame Designs M. FERRARI1, A. VICHI2, A. GIOVANNETTI2, G. BONADEO3, C. RENGO4, and C. GORACCI3, 1Dental Materials and Fixed Prosthodontics - University of Siena, Tuscan School of Dental Medicine - University of Firenze and Siena, Livorno, Italy, 2Dental Materials and Fixed Prosthodontics - University of Siena, Tuscan School of Dental Medicine - University of Firenze and Siena, Grosseto, Italy, 3Dental Materials and Fixed Prosthodontics - University of Siena, Tuscan School of Dental Medicine - University of Firenze and Siena, Siena, Italy, 4Dental Materials and Fixed Prosthodontics - University of Siena, Tuscan School of Dental Medicine -University of Firenze and Siena, Napoli, Italy Objective: Chipping is the most frequent clinical failure of zirconia crowns. Causes of chipping have not been completely understood and different possible reasons have been considered. The study was aimed at evaluating the fracture resistance of 3 different CAD-CAM zirconia frame designs veneered with porcelain. i-ZirK ™ Dental Materials 2014! Fracture resistance of three porcelain-layered! CAD/CAM zirconia frame designs! Marco Ferrari, Agostino Giovannetti, Michele Carrabba,! Giovanni Bonadeo, Carlo Rengo, Francesca Monticelli,! Alessandro Vichi.!
  • 15. Method: Thirty extracted sound premolars were divided into 3 groups (n=10). Silicon impressions of the crowns were taken. Chamfer preparations were performed, impressions were taken, and dies were prepared. Three zirconia frame designs (Aadva, GC) were realized: 1. reproduction of the abutment contour (flat design, FD); 2. wax-up as for porcelain-fused-to-metal crowns (PFM); 3. anatomically-guided, designed to keep constant the thickness of the overlying porcelain veneering (AG). ! ! ! ! ! ! i-ZirK ™
  • 24.
  • 26. i-ZirK ™ Porcelain veneering was made with pressure layering technique (Initial Zr, GC) using the previously obtained silicon impressions.
  • 30. Crowns were cemented utilizing a self-adhesive resin cement (G-Cem, GC). After a 24-hour water storage at 37°C, using a universal testing machine (1mm crosshead speed), crowned teeth were loaded in the central fossa with a round-tip stainless steel rod of 2 mm in diameter in a direction parallel to the longitudinal axis of the tooth. Loading was applied until fracture occurred and load at fracture was recorded in Newtons (N). ! Digital photographs of the failed specimens were taken in order to assess failure patterns. ! Between-group differences in fracture strength were statistically analyzed (One-Way Analysis of Variance, Tukey test, p<0.05)
  • 31. i-ZirK ™ Results: Load at fractures differed significantly among the groups (p=0.004). AG exhibited significantly higher fracture resistance (1721,6±488,1 N) than PFM (1004,6±321,3 N) and FD (1179,5±536,2 N), that were comparable. Repairable failures occurred in 80% of AG, 70% of PFM, and 50% of FD specimens. !!!!!!!!!!!!!!!!!! Newton( FRACTURE(TEST( 1179,563( 1004,681( 1721,664( 2500" 2000" 1500" 1000" 500" 0" I.LISC( II.BORD( III.RID(MAS( FAILURE&PATTERNS& 50%$ 100%$ 80%$ 60%$ 40%$ 20%$ Conclusion: Anatomically-guided zirconia frames resisted significantly higher loads than flat and PFM-like frame designs. 70%$ 80%$ 50%$ 30%$ 20%$ 0%$ I"LISC& II"BORD& III"RID&MAS& NR$ R$ GROUPS:( I*LISC( (( FRACTURE(MODE:( R:(restorable( FRACTURE(MODE(2:(separated(evalua@on(for(crown(and(tooth( (( II*BORD( NR:(non(restorable( CE:(cipping(with(zirconia(exposi@on( (( (( III*RID(MAS( (( (( (( (( C:(cipping(without(zirconia(axposi@on( (( FV:(ver@cal(fracture( (( FO:(orizontal(fracture( (( (( (( (( MEAN( SD( R( NR( I*LISC( 1179,563( 536,25517 72( I*LISC( 50%( 50%( II*BORD( 1004,681( 321,32031 78( II*BORD( 70%( 30%( III*RID(MAS( 1721,664( 488,11936 04( III*RID(MAS( 80%( 20%(
  • 32. Clinical evaluation ! 3 groups of 20 samples each Single unit zirconia/porcelain crowns 3 different anatomic designs Clinical parameters over time of clinical service such as chipping, marginal leakage, postop sensitivity ! ! ! vs vs vs
  • 33. Clinical trial of three framework designs of porcelain layered zirconia crowns: 18 months preliminary results. i-ZirK ™
  • 34.
  • 35.
  • 37. New Clinical trial ! 2 groups of 20 samples each Single unit zirconia/porcelain crowns 1 different anatomic designs vs monolitic crowns Clinical parameters over time of clinical service such as chipping, marginal leakage, postop sensitivity ! ! ! vs
  • 38. Clinical eva!luation 2 groups of 10 samples each Three- unit zirconia/porcelain bridges 2 different anatomic designs Clinical parameters over time of clinical service such as chipping, marginal leakage, postop sensitivity ! ! ! !
  • 39. ORIGINAL ARTICLE J Adv Prosthodont 2011;3:57-62!DOI:10.4047/jap.2011.3.2.57 The effect of ceramic thickness and number of firings on the color of a zirconium oxide based all ceramic system fabricated using CAD/CAM technology 14 Vinay Chila Bachhav*, MDS, Meena Ajay Aras, MDS ! Department of Prosthodontics, Goa Dental College and Hospital, Bambolim, Goa, India PURPOSE. Ceramics have a long history in fixed prosthodontics for achieving optimal esthetics and various materials have been used to improve ceramic core strength. However, there is a lack of information on how color is affected by fabrication procedure. The purpose of this study was to evaluate the effects of various dentin ceramic thicknesses and repeated firings on the color of zirconium oxide all-ceramic system (LavaTM) fabricated using CAD/CAM technology. MATERIALS AND METHODS. Thirty disc-shaped cores, 12 mm in diameter with a 1 mm thickness were fabricated from zirconium oxide based all ceramic systems (LavaTM, 3M ESPE, St Paul, MN, USA) and divided into three groups (n = 10) according to veneering with dentin ceramic thicknesses: as 0.5, 1, or 1.5 mm. Repeated firings (3, 5, 7, or 9) were performed, and the color of the specimens was compared with the color after the initial firing. Color differences among ceramic specimens were measured using a spectrophotometer (VITA Easyshade, VITA Zahnfabrik, Bad S ̈ackingen, Germany) and data were expressed in CIELAB system coordinates. A repeated measures ANOVA and Bonferroni post hoc test were used to analyze the data (n = 10, α=.05). RESULTS. L*a*b* values of the ceramic systems were affected by the number of firings (3, 5, 7, or 9 firings) (P<.001) and ceramic thickness (0.5, 1, or 1.5 mm) (P<.001). Significant interactions were present in L*a*b* values between the number of firings and ceramic thickness (P<.001). An increase in number of firings result- ed in significant increase in L* values for both 0.5 mm and 1.5 mm thicknesses (P<.01, P=.013); however it decreased for 1 mm thickness (P<.01). The a* values increased for 1 mm and 1.5 mm thicknesses (P<.01), while it decreased for 0.5 mm specimens. The b* values increased sig- nificantly for all thicknesses (P<.01, P=.022). As the dentin ceramic thickness increased, significant reductions in L* values (P<.01) were record- ed. There were significant increases in both a* and b* values (P<.01) as the dentin ceramic thickness increased. CONCLUSION. The num- ber of firings and dentin ceramic thickness have a definite effect on the final color of all ceramic system tested. The mean ΔE value increased as the dentin ceramic thicknesses increased for zirconium-oxide based all ceramic specimens tested. However, the mean ΔE values were less than 3.7ΔE units which is rated as a match in the oral environment. [J Adv Prosthodont 2011;3:57-62] i-ZirK ™
  • 40. Group 1 Bar of 1,2 mm porcelain layered in one firing with porcelain thickness of 0.8 mm ! Group 1II Bar of 0,8 mm porcelain layered in five firings with porcelain thickness of 1.2 mm Effect of repeated firings on flexural strength of veneered zirconia. Carabba M, Vichi A, Ferrari M Submitted to Dental Materials Group 1I Bar of 0,8 mm porcelain layered in one firing with porcelain thickness of 1.2 mm
  • 41. Materials and Methods ISO Standard 6872:2008 - Dentistry - Ceramic materials
  • 42. F – (Fresati) Grounded FR – (Fresati, rigenerati) Grounded and regenerated LR – (Lucidati, rigenerati) Untouched and regenerated L – (Lucidati) Untouched
  • 43.