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Synthesis and
Characterization of
Triphenylethylene
Derivatives with
Aggregation-Induced
Emission
Characteristics
Presented by : Muhammad Faisal
10060607-084
INTRODUCTION
• Aggregation Induced Emission (AIE) Property
• Organic luminescent materials with AIE properties
• Applications of AIE in the areas of
– Electroluminescence devices
– Chemosensors
• Limited in number due to complicated and difficult preparation.
• Triphenylethylene carbazole and triphenylethylene derivatives
EXPERIMENTAL
• SYNTHESIS:
– The derivatives were easily prepared by a three-step reaction, including
the Suzuki and Wittig–Horner reactions.
• CHARACTERIZATION:
– Structural Identification
– Thermal Properties
– Photopysical and Electrochemical Properties
– Aggregation Induced Emission Properties
RESULTS & DISCUSSION
Thermal properties:
RESULTS & DISCUSSION
Photophysical and Electrochemical Properties:
RESULTS & DISCUSSION
Aggrigation Induced Emission Properties:
CONCLUSION
• We have developed New class of AIE compounds……
• Blue light emitters
• Maximum fluorescence emission wavelength 443-461
nm.
• Glass transition temperature range, 86-129 °C…..
• Decomposition temperature, 432-534 °C…..
• HOMO levels are between5.61-5.66 eV….
• ΔEg values range is 3.18-3.22 eV….
• The compounds (BN)2Bt and (BB)2Bt exhibited vibronic
fine-structure PL spectra when the water fraction was less
than 70%

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Synthesis and characterization of triphenylethylene derivatives with aggregation induced emission characteristics

  • 1. Synthesis and Characterization of Triphenylethylene Derivatives with Aggregation-Induced Emission Characteristics Presented by : Muhammad Faisal 10060607-084
  • 2. INTRODUCTION • Aggregation Induced Emission (AIE) Property • Organic luminescent materials with AIE properties • Applications of AIE in the areas of – Electroluminescence devices – Chemosensors • Limited in number due to complicated and difficult preparation. • Triphenylethylene carbazole and triphenylethylene derivatives
  • 3. EXPERIMENTAL • SYNTHESIS: – The derivatives were easily prepared by a three-step reaction, including the Suzuki and Wittig–Horner reactions. • CHARACTERIZATION: – Structural Identification – Thermal Properties – Photopysical and Electrochemical Properties – Aggregation Induced Emission Properties
  • 5. RESULTS & DISCUSSION Photophysical and Electrochemical Properties:
  • 6. RESULTS & DISCUSSION Aggrigation Induced Emission Properties:
  • 7. CONCLUSION • We have developed New class of AIE compounds…… • Blue light emitters • Maximum fluorescence emission wavelength 443-461 nm. • Glass transition temperature range, 86-129 °C….. • Decomposition temperature, 432-534 °C….. • HOMO levels are between5.61-5.66 eV…. • ΔEg values range is 3.18-3.22 eV…. • The compounds (BN)2Bt and (BB)2Bt exhibited vibronic fine-structure PL spectra when the water fraction was less than 70%