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HOT WORK

ON DRUMS & TANKS

D E P A R T M E N T O F
L A B O U R
OCCUPATIONAL SAFETY T E T A R I M A H I
& H E A LT H S E R V I C E
2
CONTENTS

ABOUT THIS BOOKLET......................................... 3

1 WHY ACCIDENTS HAPPEN ................................ 4

2 WHAT TO LOOK OUT FOR ................................. 6

3 HOW TO CLEAN TANKS AND DRUMS ................. 9

4 HOW TO INERT DRUMS AND TANKS ................. 20

5 SAFETY HINTS FOR HOT WORK ....................... 25

6 ALTERNATIVES TO HOT WORK........................ 27

7 SUMMARY AND ADDITIONAL REMINDERS ........ 29

8 THE EMPLOYER’S RESPONSIBILITIES .............. 33

APPENDIX 1: SOME DANGEROUS SUBSTANCES .. 35

APPENDIX 2: ACCIDENT REPORTS ..................... 38

Published: March 1988
ISBN 0-477-03420-9
ABOUT THIS

BOOKLET

This booklet describes the safety procedures that
should be followed by anyone who plans to do hot
work — that is, welding, gas cutting, brazing or
soldering — on any fuel tank, drum, container or
pipe that has previously contained a combustible
substance.
If you do this type of work, whether as part of your
job or simply as a hobby, it is vital that you
understand the dangers involved and faithfully
follow the procedures described here.
This booklet is primarily concerned with hot work
on tanks, drums and vessels with a capacity of less
than 2,500 litres. Some mention is made of the
specialised procedures required when working on
larger vessels, but no one should attempt this
complex and dangerous work without previous
training and experience.
Many people have been injured or killed by
exploding drums or tanks — few of those cases are
reported in Appendix 2 of this booklet. All these
accidents have followed a similar pattern and all
could have been avoided if the proper precautions
had been taken. Don’t make the mistake of
thinking accidents always happen to someone else.
When you have read this booklet, we suggest you
keep it handy in your workshop for future
reference. We also suggest you bring it to the
attention of your colleagues or friends who do this
type of work. A little time spent studying it could
prevent a lot of unnecessary suffering.
3
1 WHY ACCIDENTS

HAPPEN

Any combustible material in a tank, drum or
similar container can give off vapour or fumes
when you apply heat to it. Mixed with air in the
right proportions these fumes can explode
violently when the critical temperature is
reached or when ignited by a spark from a
welding or cutting torch. Sometimes even a
spark from a mechanical tool will be enough to
ignite highly explosive vapours such as petrol.
If a tank or drum explodes while you are
working on it, you are likely to suffer multiple
injuries:
•	 The shock wave or blast produced by the
rise in pressure may damage your ear
drums, lungs and circulatory system.
•	 Fragments from the vessel become missiles
which can cause penetrating and damaging
wounds.
•	 You may be hurled against a wall or hard
object and suffer broken bones and further
internal injuries.
As you will see from the accident reports
(pp.38-39), these injuries may be fatal.
You should realise that even a minute amount
of a combustible substance may generate
enough vapour to cause an explosion. Sludge or
scale deposits in a drum or tank may seem
harmless enough but they may well release
explosive vapours when the surface is heated.
4
You should also realise that even if a drum has
been empty and exposed to the weather for years,
it may still contain hazardous substances in the
seams or crevices. Never assume it is safe for hot
work — always take the precautions described
here.
5
2 WHAT TO

LOOK OUT FOR

You may already know the more obviously
dangerous substances — petrol is certainly the
commonest. But there are many other substances
which are not usually thought of as explosive but
which can be under certain circumstances.
Flammable or explosive vapours may be present in
a vessel that has held any of the following:
(a) Any volatile liquid that releases flammable
vapour at atmospheric pressure.

Examples: petrol, acetone, white spirit.

(b) A non-volatile oil or solid that releases
flammable vapour when heated (some of these
substances undergo thermal cracking).
Examples: diesel oil, tar, greases, linseed oil,
tallow, soap.
(c) An acid that reacts with metals to form
hydrogen.

Examples: sulphuric acid, nitric acid,

hydrochloric acid.

(d) A combustible solid, finely divided particles of
which may be present in the form of an
explosive dust cloud.
Examples: fibreglass, milk powder, sulphur.
There are also many chemical compounds that
decompose when heated, forming potentially
hazardous vapours. A list of some common
industrial chemicals and dusts that pose explosion
hazards is given in Appendix 1 of this booklet.
6
Always try to identify which substance a container
has held so that you can take any special
precautions needed. Remember, however, that
labels do not always correctly indicate the
contents, as a container may have been used to
store other substances. It is wise to treat the
contents of all containers as potentially dangerous
and act accordingly.
A special warning must be given to workers who
weld pesticide spraying equipment. Many
insecticides (see Appendix 1) decompose when
subjected to heat, producing highly toxic
phosgene gas. Inhaling this gas, which has a
sweet hay-like smell in low concentrations, will
make you seriously ill.
Before hot work is carried out on spray equipment
it must be thoroughly cleaned by steaming, as
explained in the following section of this booklet.
Traces of substance in
seams of drum . . .
Volatilise when
heat is applied
7
Explosive concentration
is reached and vapour
ignites
Petrol tank contains
flammable vapours at
normal temperatures
Acids may react with the metals Mixed with air in the right
in containers, producing highly proportions, many dusts will
explosive hydrogen gas explode when ignited
8
3 HOW TO CLEAN

TANKS AND DRUMS

There are three important points to remember:
(a) Use only the cleaning methods described here.
If the substance is soluble, use the washing
method. For non-soluble substances, use either
the boiling or steaming method. Other cleaning
methods may be recommended but you need
some expertise to know whether they are
effective for particular substances. Your safety
may be at risk if you use a different method from
the ones in this booklet.
(b) Cleaning must be thorough. Don’t try to take
shortcuts — it’s your safety that’s at stake. If the
cleaning must be done by someone else, it is in
your interest to ensure that the person is fully
aware of the hazards and the precautions to be
taken. An untrained person must be supervised
by someone with knowledge of, and experience
in, the work. If contractors are engaged, you
should ensure they are suitably qualified for the
work.
(c) You must check for the presence of residues in
the tank or drum after carrying out the cleaning
procedures. If residues are present, you must
take the additional steps described here before
you begin hot work.
PREPARATORY STEPS
If you are going to work on a vehicle fuel tank, it
9
must be thoroughly drained of oil and petrol and
removed from the vehicle. Make sure there are no
ignition sources present (e.g. Iighted cigarettes,
spark-producing electric motors). Never drain a
petrol tank over a pit or depression in the ground.
If you are working on a drum or similar container,
all caps, bungs or lids must be removed. If you
have to use tools to do so, make sure they are a
nonsparking type (e.g. those made of bronze).
Dispose of all residues carefully. If the container
has held a corrosive substance, wear rubber or
PVC gloves and a face shield or goggles to protect
your eyes from splashes.
Remove bungs, tops, etc.
before cleaning
Do not empty fuel tanks over
pits or holes in the ground
10
WASHING WITH WATER
Fill the container with water and drain it,
repeating several times. This method is suitable
only for water-soluble substances. It is particularly
suitable for acids such as hydrochloric or
sulphuric acid as it eliminates the hazard of
hydrogen produced by the reaction of acid on
metal.
Washing will not remove petrol, oil, grease and
many other potentially hazardous substances
(refer to the list in Appendix 1 to see whether
washing is appropriate). It is not recommended
for any container that has held a solvent, whether
combustible or not. For these substances, you
must use either the boiling or steaming methods.
Whenever you are unsure about the effectiveness
of washing, or you cannot positively identify the
substance, always boil or steam the container.
Washing with water is suitable only for soluble substances
11
Washing will not remove oils, greases and many organic
compounds
12
BOILING
You will need a vat or tank which can be
maintained at boiling temperature for at least half
an hour. Usually a longer period of boiling is
required and the tank must be selected
accordingly.
The item to be cleaned must be completely
immersed in the boiling water so that the water
fills as well as surrounds it. It is essential to add a
proprietary degreasing detergent (not a household
detergent) to the water, particularly if the tank has
held petrol, paraffin, diesel oil or grease.
Commercially available products usually contain
substances such as sodium metasilicate, sodium
hydroxide (caustic soda) or sodium carbonate
(washing soda) and emulsifying agents.
Strong alkalis such as caustic soda will attack
aluminium and its alloys, producing hydrogen. If
you have to treat such a container, make sure you
use one of the weaker alkaline cleansers. You
should wear overalls, a PVC apron and gloves and
safety glasses or a face shield to avoid getting
splashes of strong alkaline cleansers on your skin
or in your eyes.
You will need fabric or leather gloves when you
are handling containers that have been steamed
or boiled as the metal becomes very hot.
13
Drum or tank should be
completely immersed in
boiling water, with an
industrial detergent added,
and boiled for at least half an
hour
14
STEAMING
Steaming volatilises oils and greases and is
particularly suitable for tanks or drums which have
held these substances.
You must have a suitable source of low-pressure
steam. Make sure there is an outlet for the steam
so that pressure does not build up and
condensates and sludge can drain away. If there is
only one opening, place the tank or drum with the
opening downwards so that condensate can
escape.
The time required for steaming varies considerably.
As a minimum, you should allow 30 minutes of
continuous steaming after every part of the item
has become too hot to touch. Steaming for less
than 30 minutes is likely to be inadequate. Check
the condensate at regular intervals. If contaminated
with oil or other material it indicates that cleansing
is still incomplete. Some items may need to be
steamed for 2-3 hours.
If you are steaming a large tank which has held a
highly flammable substance, you will need to take
precautions to prevent the accumulation of static
electricity. The tank and steam pipe should be
earthed and the steam pipe should be electrically
bonded to the tank.
Steaming is particularly suitable
for tanks or drums which have
held oil or grease. Allow at least
30 minutes of steaming after
the metal has become too hot
to touch
15
When steaming a large tank, the tank and steam pipe should be
earthed, and the steam pipe should be electrically bonded to the
tank
Drums should be inverted so that condensate and sludge can
drain out
16
CHECKING AFTER CLEANING
After cleaning, the inside of the container must be
checked for residual vapours or solids. Specially
designed can or barrel safety torches are available
and may be used for visual inspection. Make sure,
however, that the equipment is safe for use in
flammable atmospheres.
An instrument known as an explosimeter can be
used to check for flammable vapours, but the
absence of a reading does not necessarily mean
that a tank or drum is safe to weld. This is because
the meter only checks the vapour at atmospheric
temperature. During welding, surfaces become
very hot and any oil or grease present will be
vaporised, forming an explosive atmosphere.
If cleaning has been thorough and you can detect
no trace of solid residues or vapours by sight or
smell, the item can be considered safe for hot
work. To be absolutely sure, you should replace
the air in the vessel by water, steam or an inert gas
— this is explained in the next section of the
booklet.
If flammable vapours or sludge deposits are
detected in the vessel after cleaning, you must
repeat the cleaning or make sure the vessel is
inerted before you carry out hot work. You can also
use either trichloroethylene or 1.1.1.
trichloroethane to wash out stubborn oil sludge
deposits but these substances have a narcotic
effect and must be used with caution and only in
well-ventilated areas. If you use this method it
must be followed by a further cycle of steaming,
because of the possible fire or toxic hazards.
If there is a batch of containers to be worked on
and someone else is doing the cleaning, it is a
17
wise precaution to have a second, experienced
person examine each one and certify it as safe for
hot work.
The Dangerous Goods Act and Regulations require
tanks that have held certain classes of dangerous
goods to be tested and certified as gas-free by a
competent person before hot work is carried out
on them.
If you can still smell the A can or barrel inspection
substance, the steaming or torch will help you check for
washing should be repeated solid residues
The explosimeter tests for
flammable atmospheres —
but you should be aware of
its limitations
18
Tanks which have held certain classes of dangerous goods must
be tested and certified as gas-free before hot work is carried out
on them
CLEANING METHODS NOT TO BE USED
The following methods are not recommended for
removing flammable materials from a tank, drum
or similar vessel.
(a) Blowing out with compressed air. This may
remove volatile liquids which produce fumes
but will not remove solids or other deposits
capable of producing fumes.
(b) Cleansing with trichloroethylene or 1.1.1
trichloroethane — except as indicated earlier.
These are good solvents for removing many
flammable substances but there are others
they will not remove. They must be used with
great care.
(c) Cleansing with carbon tetrachloride. This
solvent is inherently toxic and may form
poisonous phosgene gas when heat is applied.
It may also react with the metal of the tank or
drum. Carbon tetrachloride has proved an
ineffective cleansing agent on a number of
occasions and explosions have followed.
19
4 HOW TO INERT

DRUMS AND TANKS

Sometimes it is not possible to remove all
combustible material from a vessel. In this case it
is necessary to ensure that the material is made
non-explosive and non-flammable. The method
normally used is to replace the air in the vessel
with water or an inert gas.
You may also use one of the inerting methods
described below as an additional safeguard after
cleaning.
FILLING WITH WATER
This is the easiest method for most vehicle fuel
tanks and drums.
If you are using electric welding gear to make a
repair, you can replace the air by completely
filling the vessel with water. You should fit a vent
to relieve any pressure generated by steam.
If you are making a repair by oxy-acetylene
welding, brazing or soldering near an opening in
the vessel, fill the vessel with water, leaving a
small free air space at the point where the repair
is to be made. Remember, the vessel must be
cleaned as thoroughly as possible beforehand.
This is a very useful technique when you have to
repair a joint between a short filling pipe and a
fuel tank.
20
If gas welding, fill the tank or drum with water up to the point
where the welding is being performed
If electric arc welding, fill the tank completely with water — but
keep welding gear dry
21
Plug
Rubber tubing
Slit 25 mm long
Cork shaped to
suitable size
Open-ended tube
A simple non-return valve will
relieve pressure generated by
steam
CONTINUOUS STEAMING
The procedure is basically the same as for steam
cleaning except that you allow steam to continue
flowing through the tank during the welding
operation. You should use a stand pipe, if
necessary, to make sure the steam flows the full
length of the tank.
In the continuous steaming method, steam flows through the
tank while the welding or cutting is being carried out
22
FILLING WITH CARBON DIOXIDE
A heavier than air gas, carbon dioxide does not
support combustion and may be used to inert a
tank when it is not practicable to fill it with water.
You need to ensure that all the air in the tank is
displaced and that the carbon dioxide does not leak
from an exit point at the bottom of the tank. To
prevent excessive loss of carbon dioxide or the
buildup of pressure, the filling opening should be
fitted with a simple non-return valve.
Carbon dioxide is supplied as a bottled gas in liquid
form. If the cylinder is inverted with the valve open,
the gas freezes into solid snow-like pellets known as
‘dry ice’. These gradually vaporise back into a gas
— there is no liquid form of carbon dioxide at
atmospheric pressure.

As a general guide you should add at least 0.5 kg of

dry ice per 250 litre of tank capacity to ensure the

tank is completely filled.

Dry ice is very cold and should only be handled with

gloves or tongs.

Note: This method is only suitable for small tanks —

up to about 1,000 litres in capacity. In larger tanks

the CO2
gas will be so cold and heavy that only the

atmosphere at the bottom of the tank will be

inerted.

FILLING WITH NITROGEN
Nitrogen is used to inert the atmosphere inside
large tanks — for example in the oil industry — but
this is a specialised application. Its use is only
recommended for people with the necessary
expertise.
Nitrogen is slightly lighter than air and tends to rise.
When this method is used, it is essential to ensure
23
that the tank is completely filled with the gas. A
light flow of gas must be maintained throughout
the welding operation and any breaks in between.
It must be stressed that while carbon dioxide and
nitrogen are not toxic, neither gas will support
life. No one should enter a tank containing either
gas without breathing apparatus. The area in the
vicinity must be provided with good natural or
mechanical ventilation.
24
5 SAFETY HINTS

FOR HOT WORK

It is assumed in this booklet that you are already
familiar with the correct procedures for welding,
brazing or gas cutting. If you are in any doubt, you
should obtain a copy of the Occupational Safety
& Health booklet Welding Safety.
Here are the main safety rules to observe:
CLOTHING
•	 Always wear industrial overalls and eye
protection during welding and cutting work.
Keep overalls fastened up to your neck and
round your wrists.
•	 Wear safety footwear if you are handling heavy
drums or tanks.
Wear gloves or gauntlets while arc welding to
protect against shock, burns and radiation burns.
EQUIPMENT
•	 Make sure all equipment is in good order.
•	 Make sure flashback arrestors are fitted to gas
welding gear.
•	 Beware of leaking hoses and connections
which are not gas-tight.
•	 Check insulation of all cables on electric arc
welding gear.
•	 Do not arc weld in wet conditions.
•	 Use an isolating transformer with all portable
electrical equipment.
25
•	 Make sure welding screens are erected to
protect others from ultraviolet radiation.
VENTILATION
•	 Make sure your work area is well ventilated.
The ultraviolet light from welding converts
oxygen in the air around you to ozone, which
initiates the lungs. There are also toxic
substances in fluxes, filler rods, coatings and
cleaning agents. Other poisonous fumes are
produced by welding or cutting metal coated
with paint, resin or varnish.
BURNS
•	 Always cool down hot metal or mark it with
chalk if there is a chance someone could
accidentally touch it.
FIRE PREVENTION
•	 Keep a fire extinguisher handy, particularly
when working on containers with a coating of
flammable material such as paint.
•	 Keep the work area free of flammable liquids
and wastes or piles of rubbish in which sparks
could smoulder.
26
6 ALTERNATIVES

TO HOT WORK

One way to avoid the dangers associated with hot
work on drums and tanks is to consider
alternative methods not involving heat.
Mechanical drum opening tools are an excellent
alternative to gas cutting. Resembling large tin
snips, they remove the tops from drums quickly,
efficiently and without risk to the operator.
Because they cut close to the inside of the drum,
they leave no dangerous jagged edges.
As an added precaution, particularly if the drum
has held a highly flammable solvent, you should
fill the drum with water first.
For repairing small holes, proprietary compounds
of the ‘cold solder’ type may be a suitable
alternative to soldering or brazing.
A drum opening tool avoids
the need for hot work. A highly
recommended item
27
Proprietary compounds such as “cold solder” may be an
alternative to soldering or brazing
28
7 SUMMARY AND

ADDITIONAL

REMINDERS

The message of this booklet can be summarised
as follows:
•	 Severe explosions and fires may occur when
welding, cutting, brazing or soldering is carried
out on fuel tanks, drums and similar vessels
that have previously held flammable materials.
•	 Many substances not usually thought of as
explosive or flammable may be dangerous.
•	 The only way for hot work to be done safely is
for the vessel to be thoroughly cleaned by
washing, boiling or steaming as appropriate
and the interior carefully checked for residual
traces of the substance.
•	 As an additional precaution, the tank should
be inerted by filling it with water, steam or an
inert gas.
•	 Hot work has its own set of hazards. Make
sure you know and follow the safety rules at
all times.
•	 Always wear and use the protective clothing
and equipment appropriate to the task.
•	 Avoid hot work on potentially dangerous
drums wherever possible, e.g. by using
mechanical tools.
29
Here are some additional safety reminders:
•	 If one compartment of a two-compartment
tank has to be repaired or cut, both
compartments need to be made safe. The
common example is a tractor fuel tank, which
contains a main compartment for oil and a
small one for petrol.
•	 Never use an empty drum, tank or container
as a work platform or as a support for hot
work. The torch flame or sparks may ignite
vapours or solid residues inside it. Either use a
proper support or clean the container first as
described in this booklet.
•	 As well as the explosion risks described here,
you should also remember the risk of fires. A
sudden spurt of flames from filler pipes or
other openings can obviously be dangerous.
Another danger is that burning material, e.g.
flammable liquids may be sprayed on to the
clothing of people nearby.
•	 Never enter a tank or vat to carry out cleaning
or hot work. Any work in confined spaces is
extremely dangerous and should not be
attempted by inexperienced people. The
special precautions necessary are outside the
scope of this booklet but information is
available from OSH offlces.
30
Don’t use a drum as a work
platform unless it has first been
cleaned
Similarly, don’t use it as a support for hot work
31
Summary of Procedures Prior to Beginning Hot Work on
Drums and Tanks
DRAIN TANK
Remove caps,
bungs, etc
CLEAN TANK
Washing
Boiling
Steaming
Residues cannot
be removed or as
added protection
INSPECT TANK
Visual
inspection
Vapour test
Residues or
vapours absent
Residues or
vapours
present
CLEAN TANK
Washing
Boiling
Steaming
Solvent
INERT TANK
Water
Steam
CO2 or N2
(Specialist
applications
only)
TANK READY
32
8 THE EMPLOYER’S

RESPONSIBILITIES

Employers are reminded of their legal
responsibilities towards workers who are required
to carry out the cleaning of tanks, drums, vats, or
similar vessels prior to hot work, or to perform
hot work on such vessels.
•	 Workers must not carry out this work unless
they have been adequately instructed as to the
dangers likely to arise and the precautions to
be taken. Where necessary, the worker must
be adequately supervised by a person with
sufficient knowledge of and expertise in the
work.
•	 All workers must be provided with the
necessary protective clothing and equipment,
including eye protection, gloves, suitable
footwear, overalls and aprons if appropriate.
Workers have an obligation to wear and use
these items.
•	 First aid facilities must be provided and be
readily accessible to workers. First aid kits
should be suitably stocked to deal with the
types of injuries possible in this work, i.e.
burns, scalds, chemical splashes, eye injuries,
cuts and abrasions.
33
Employers must supply protective clothing and equipment and
workers must use it
34
APPENDIX 1:

SOME DANGEROUS

SUBSTANCES

The following is a brief list of common industrial
chemicals which may be stored in drums and
tanks and which pose fire, explosion or other
hazards to people carrying out hot work.
The list is not complete and you are urged to treat
all chemicals as potentially dangerous.
Substances marked with an asterisk are soluble in
water and may be removed by washing with water.
If you are washing out substances such as
cyanide, take care in disposing of the wastes. Do
not allow them to enter normal water drains. All
such waste must be disposed of in accordance
with local bylaws.
CHEMICALS
Acetone
Acrylonitrile
Amyl acetate
Amyl alcohol
Ammonia and compounds
Calcium hypochlorite Carbon disulphide
Chlorates and perchlorates of sodium, potassium
and ammonium
Chloroform
35
Cyanides
Dichloromethane
Formaldehyde
Glycol ethers and glycol ether acetates
Hydrochloric acid
Isopropyl alcohol
Kerosene
Methyl alcohol
Methyl ethyl ketone
Mineral turpentine
Nitric acid
Phenol
Hydrocarbon solvents (e.g. pentane, hexane
heptane, octane)
Sodium hypochlorite
Styrene
Sulphuric acid
1.1.1. Trichloroethane
Toluene
Turpentine
White spirit
Xylene
EXPLOSIVE DUSTS
The following is a list of dusts which present a
strong to severe explosion hazard. Again it is not
a comprehensive list, and it is wise to treat all
dusts as potentially explosive.
Aluminium/resin mix
Barley/maize/lucerne mix
Cardboard
Casein
36
Coal
Cocoa
Cornflour
Cotton waste
Flour
Icing sugar
Leather
Milk powder
Paper/wood/resin mix
Plastic powder
Resin
Spice mixes
Stock feed
Sulphur
Wheat
Wood
INSECTICIDES
The following are common members of the
organochlorine group of insecticides. These
produce highly toxic phosgene gas when
subjected to heat.
Aldrin
Dieldrin
DDT
Benzene hexachloride (BHC)
Chlordane
Lindane
Methoxychlor
37
APPENDIX 2:

ACCIDENT

REPORTS

The Department of Labour investigated, over a
typical 6-month period, accidents where hot work
had been undertaken on containers holding
flammable or combustible materials. Brief details
of those accidents are given below:
•	 An engineer was killed when a 6000-litre tank
exploded when he lit a welding torch to repair
a seam in the tank. The tank was moved 30
metres in the explosion, and an observer who
was standing 2 metres away was thrown to the
ground by the blast. The tank had been
flushed with water for three days prior to the
explosion but this did not remove all the
explosive substances.
•	 A worker was attempting to remove the lid of a
200-litre container that had previously
contained lacquer thinners. The drum, which
had both bungs in place when the worker
applied heat to the lid, hit the roof of the
building 6 metres up. The worker received
bruising to his hand.
•	 While removing a cleaning bung from a 70-litre
stainless steel boat fuel tank, a worker passed
a heated soldering iron over the bung hole.
The petrol fumes ignited, throwing the worker
on the floor.
•	 A worker, who had a few moments spare time,
38
began cutting a 200-litre drum to makes a
barbecue. He was unaware of the contents of
the drum, which exploded when the torch
began the cut. He received minor injuries in
the incident.
•	 A worker passed a gas torch to his colleague
over the open lid of a bitumen tank, causing
an explosion. The worker, who was on top of
the tank, received 10% burns to his face and
left hand and his leg was broken in three
places. The worker on the other side of the
tank escaped injury.
•	 A welding contractor was attempting to fit a
tap into a 5000 litre tank. A cut had been
started in one end of the tank when it
exploded. The tank was turned around and
flipped over. The opposite end of the tank was
blown approximately 42 metres, soaring over
a stand of trees 12 metres high and landing in
a vacant section. The contractor received
cracked ribs, a dislocated shoulder, injuries to
his collar bone and severe bruising all oyer the
body.
There has been no let-up in accidents and many
more examples could be given. Remember, all
accidents of this type are potentially fatal. Don’t
let it happen to you!
39

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Hot Work Drum and Tanks

  • 1. HOT WORK ON DRUMS & TANKS D E P A R T M E N T O F L A B O U R OCCUPATIONAL SAFETY T E T A R I M A H I & H E A LT H S E R V I C E
  • 2. 2 CONTENTS ABOUT THIS BOOKLET......................................... 3 1 WHY ACCIDENTS HAPPEN ................................ 4 2 WHAT TO LOOK OUT FOR ................................. 6 3 HOW TO CLEAN TANKS AND DRUMS ................. 9 4 HOW TO INERT DRUMS AND TANKS ................. 20 5 SAFETY HINTS FOR HOT WORK ....................... 25 6 ALTERNATIVES TO HOT WORK........................ 27 7 SUMMARY AND ADDITIONAL REMINDERS ........ 29 8 THE EMPLOYER’S RESPONSIBILITIES .............. 33 APPENDIX 1: SOME DANGEROUS SUBSTANCES .. 35 APPENDIX 2: ACCIDENT REPORTS ..................... 38 Published: March 1988 ISBN 0-477-03420-9
  • 3. ABOUT THIS BOOKLET This booklet describes the safety procedures that should be followed by anyone who plans to do hot work — that is, welding, gas cutting, brazing or soldering — on any fuel tank, drum, container or pipe that has previously contained a combustible substance. If you do this type of work, whether as part of your job or simply as a hobby, it is vital that you understand the dangers involved and faithfully follow the procedures described here. This booklet is primarily concerned with hot work on tanks, drums and vessels with a capacity of less than 2,500 litres. Some mention is made of the specialised procedures required when working on larger vessels, but no one should attempt this complex and dangerous work without previous training and experience. Many people have been injured or killed by exploding drums or tanks — few of those cases are reported in Appendix 2 of this booklet. All these accidents have followed a similar pattern and all could have been avoided if the proper precautions had been taken. Don’t make the mistake of thinking accidents always happen to someone else. When you have read this booklet, we suggest you keep it handy in your workshop for future reference. We also suggest you bring it to the attention of your colleagues or friends who do this type of work. A little time spent studying it could prevent a lot of unnecessary suffering. 3
  • 4. 1 WHY ACCIDENTS HAPPEN Any combustible material in a tank, drum or similar container can give off vapour or fumes when you apply heat to it. Mixed with air in the right proportions these fumes can explode violently when the critical temperature is reached or when ignited by a spark from a welding or cutting torch. Sometimes even a spark from a mechanical tool will be enough to ignite highly explosive vapours such as petrol. If a tank or drum explodes while you are working on it, you are likely to suffer multiple injuries: • The shock wave or blast produced by the rise in pressure may damage your ear drums, lungs and circulatory system. • Fragments from the vessel become missiles which can cause penetrating and damaging wounds. • You may be hurled against a wall or hard object and suffer broken bones and further internal injuries. As you will see from the accident reports (pp.38-39), these injuries may be fatal. You should realise that even a minute amount of a combustible substance may generate enough vapour to cause an explosion. Sludge or scale deposits in a drum or tank may seem harmless enough but they may well release explosive vapours when the surface is heated. 4
  • 5. You should also realise that even if a drum has been empty and exposed to the weather for years, it may still contain hazardous substances in the seams or crevices. Never assume it is safe for hot work — always take the precautions described here. 5
  • 6. 2 WHAT TO LOOK OUT FOR You may already know the more obviously dangerous substances — petrol is certainly the commonest. But there are many other substances which are not usually thought of as explosive but which can be under certain circumstances. Flammable or explosive vapours may be present in a vessel that has held any of the following: (a) Any volatile liquid that releases flammable vapour at atmospheric pressure. Examples: petrol, acetone, white spirit. (b) A non-volatile oil or solid that releases flammable vapour when heated (some of these substances undergo thermal cracking). Examples: diesel oil, tar, greases, linseed oil, tallow, soap. (c) An acid that reacts with metals to form hydrogen. Examples: sulphuric acid, nitric acid, hydrochloric acid. (d) A combustible solid, finely divided particles of which may be present in the form of an explosive dust cloud. Examples: fibreglass, milk powder, sulphur. There are also many chemical compounds that decompose when heated, forming potentially hazardous vapours. A list of some common industrial chemicals and dusts that pose explosion hazards is given in Appendix 1 of this booklet. 6
  • 7. Always try to identify which substance a container has held so that you can take any special precautions needed. Remember, however, that labels do not always correctly indicate the contents, as a container may have been used to store other substances. It is wise to treat the contents of all containers as potentially dangerous and act accordingly. A special warning must be given to workers who weld pesticide spraying equipment. Many insecticides (see Appendix 1) decompose when subjected to heat, producing highly toxic phosgene gas. Inhaling this gas, which has a sweet hay-like smell in low concentrations, will make you seriously ill. Before hot work is carried out on spray equipment it must be thoroughly cleaned by steaming, as explained in the following section of this booklet. Traces of substance in seams of drum . . . Volatilise when heat is applied 7
  • 8. Explosive concentration is reached and vapour ignites Petrol tank contains flammable vapours at normal temperatures Acids may react with the metals Mixed with air in the right in containers, producing highly proportions, many dusts will explosive hydrogen gas explode when ignited 8
  • 9. 3 HOW TO CLEAN TANKS AND DRUMS There are three important points to remember: (a) Use only the cleaning methods described here. If the substance is soluble, use the washing method. For non-soluble substances, use either the boiling or steaming method. Other cleaning methods may be recommended but you need some expertise to know whether they are effective for particular substances. Your safety may be at risk if you use a different method from the ones in this booklet. (b) Cleaning must be thorough. Don’t try to take shortcuts — it’s your safety that’s at stake. If the cleaning must be done by someone else, it is in your interest to ensure that the person is fully aware of the hazards and the precautions to be taken. An untrained person must be supervised by someone with knowledge of, and experience in, the work. If contractors are engaged, you should ensure they are suitably qualified for the work. (c) You must check for the presence of residues in the tank or drum after carrying out the cleaning procedures. If residues are present, you must take the additional steps described here before you begin hot work. PREPARATORY STEPS If you are going to work on a vehicle fuel tank, it 9
  • 10. must be thoroughly drained of oil and petrol and removed from the vehicle. Make sure there are no ignition sources present (e.g. Iighted cigarettes, spark-producing electric motors). Never drain a petrol tank over a pit or depression in the ground. If you are working on a drum or similar container, all caps, bungs or lids must be removed. If you have to use tools to do so, make sure they are a nonsparking type (e.g. those made of bronze). Dispose of all residues carefully. If the container has held a corrosive substance, wear rubber or PVC gloves and a face shield or goggles to protect your eyes from splashes. Remove bungs, tops, etc. before cleaning Do not empty fuel tanks over pits or holes in the ground 10
  • 11. WASHING WITH WATER Fill the container with water and drain it, repeating several times. This method is suitable only for water-soluble substances. It is particularly suitable for acids such as hydrochloric or sulphuric acid as it eliminates the hazard of hydrogen produced by the reaction of acid on metal. Washing will not remove petrol, oil, grease and many other potentially hazardous substances (refer to the list in Appendix 1 to see whether washing is appropriate). It is not recommended for any container that has held a solvent, whether combustible or not. For these substances, you must use either the boiling or steaming methods. Whenever you are unsure about the effectiveness of washing, or you cannot positively identify the substance, always boil or steam the container. Washing with water is suitable only for soluble substances 11
  • 12. Washing will not remove oils, greases and many organic compounds 12
  • 13. BOILING You will need a vat or tank which can be maintained at boiling temperature for at least half an hour. Usually a longer period of boiling is required and the tank must be selected accordingly. The item to be cleaned must be completely immersed in the boiling water so that the water fills as well as surrounds it. It is essential to add a proprietary degreasing detergent (not a household detergent) to the water, particularly if the tank has held petrol, paraffin, diesel oil or grease. Commercially available products usually contain substances such as sodium metasilicate, sodium hydroxide (caustic soda) or sodium carbonate (washing soda) and emulsifying agents. Strong alkalis such as caustic soda will attack aluminium and its alloys, producing hydrogen. If you have to treat such a container, make sure you use one of the weaker alkaline cleansers. You should wear overalls, a PVC apron and gloves and safety glasses or a face shield to avoid getting splashes of strong alkaline cleansers on your skin or in your eyes. You will need fabric or leather gloves when you are handling containers that have been steamed or boiled as the metal becomes very hot. 13
  • 14. Drum or tank should be completely immersed in boiling water, with an industrial detergent added, and boiled for at least half an hour 14
  • 15. STEAMING Steaming volatilises oils and greases and is particularly suitable for tanks or drums which have held these substances. You must have a suitable source of low-pressure steam. Make sure there is an outlet for the steam so that pressure does not build up and condensates and sludge can drain away. If there is only one opening, place the tank or drum with the opening downwards so that condensate can escape. The time required for steaming varies considerably. As a minimum, you should allow 30 minutes of continuous steaming after every part of the item has become too hot to touch. Steaming for less than 30 minutes is likely to be inadequate. Check the condensate at regular intervals. If contaminated with oil or other material it indicates that cleansing is still incomplete. Some items may need to be steamed for 2-3 hours. If you are steaming a large tank which has held a highly flammable substance, you will need to take precautions to prevent the accumulation of static electricity. The tank and steam pipe should be earthed and the steam pipe should be electrically bonded to the tank. Steaming is particularly suitable for tanks or drums which have held oil or grease. Allow at least 30 minutes of steaming after the metal has become too hot to touch 15
  • 16. When steaming a large tank, the tank and steam pipe should be earthed, and the steam pipe should be electrically bonded to the tank Drums should be inverted so that condensate and sludge can drain out 16
  • 17. CHECKING AFTER CLEANING After cleaning, the inside of the container must be checked for residual vapours or solids. Specially designed can or barrel safety torches are available and may be used for visual inspection. Make sure, however, that the equipment is safe for use in flammable atmospheres. An instrument known as an explosimeter can be used to check for flammable vapours, but the absence of a reading does not necessarily mean that a tank or drum is safe to weld. This is because the meter only checks the vapour at atmospheric temperature. During welding, surfaces become very hot and any oil or grease present will be vaporised, forming an explosive atmosphere. If cleaning has been thorough and you can detect no trace of solid residues or vapours by sight or smell, the item can be considered safe for hot work. To be absolutely sure, you should replace the air in the vessel by water, steam or an inert gas — this is explained in the next section of the booklet. If flammable vapours or sludge deposits are detected in the vessel after cleaning, you must repeat the cleaning or make sure the vessel is inerted before you carry out hot work. You can also use either trichloroethylene or 1.1.1. trichloroethane to wash out stubborn oil sludge deposits but these substances have a narcotic effect and must be used with caution and only in well-ventilated areas. If you use this method it must be followed by a further cycle of steaming, because of the possible fire or toxic hazards. If there is a batch of containers to be worked on and someone else is doing the cleaning, it is a 17
  • 18. wise precaution to have a second, experienced person examine each one and certify it as safe for hot work. The Dangerous Goods Act and Regulations require tanks that have held certain classes of dangerous goods to be tested and certified as gas-free by a competent person before hot work is carried out on them. If you can still smell the A can or barrel inspection substance, the steaming or torch will help you check for washing should be repeated solid residues The explosimeter tests for flammable atmospheres — but you should be aware of its limitations 18
  • 19. Tanks which have held certain classes of dangerous goods must be tested and certified as gas-free before hot work is carried out on them CLEANING METHODS NOT TO BE USED The following methods are not recommended for removing flammable materials from a tank, drum or similar vessel. (a) Blowing out with compressed air. This may remove volatile liquids which produce fumes but will not remove solids or other deposits capable of producing fumes. (b) Cleansing with trichloroethylene or 1.1.1 trichloroethane — except as indicated earlier. These are good solvents for removing many flammable substances but there are others they will not remove. They must be used with great care. (c) Cleansing with carbon tetrachloride. This solvent is inherently toxic and may form poisonous phosgene gas when heat is applied. It may also react with the metal of the tank or drum. Carbon tetrachloride has proved an ineffective cleansing agent on a number of occasions and explosions have followed. 19
  • 20. 4 HOW TO INERT DRUMS AND TANKS Sometimes it is not possible to remove all combustible material from a vessel. In this case it is necessary to ensure that the material is made non-explosive and non-flammable. The method normally used is to replace the air in the vessel with water or an inert gas. You may also use one of the inerting methods described below as an additional safeguard after cleaning. FILLING WITH WATER This is the easiest method for most vehicle fuel tanks and drums. If you are using electric welding gear to make a repair, you can replace the air by completely filling the vessel with water. You should fit a vent to relieve any pressure generated by steam. If you are making a repair by oxy-acetylene welding, brazing or soldering near an opening in the vessel, fill the vessel with water, leaving a small free air space at the point where the repair is to be made. Remember, the vessel must be cleaned as thoroughly as possible beforehand. This is a very useful technique when you have to repair a joint between a short filling pipe and a fuel tank. 20
  • 21. If gas welding, fill the tank or drum with water up to the point where the welding is being performed If electric arc welding, fill the tank completely with water — but keep welding gear dry 21
  • 22. Plug Rubber tubing Slit 25 mm long Cork shaped to suitable size Open-ended tube A simple non-return valve will relieve pressure generated by steam CONTINUOUS STEAMING The procedure is basically the same as for steam cleaning except that you allow steam to continue flowing through the tank during the welding operation. You should use a stand pipe, if necessary, to make sure the steam flows the full length of the tank. In the continuous steaming method, steam flows through the tank while the welding or cutting is being carried out 22
  • 23. FILLING WITH CARBON DIOXIDE A heavier than air gas, carbon dioxide does not support combustion and may be used to inert a tank when it is not practicable to fill it with water. You need to ensure that all the air in the tank is displaced and that the carbon dioxide does not leak from an exit point at the bottom of the tank. To prevent excessive loss of carbon dioxide or the buildup of pressure, the filling opening should be fitted with a simple non-return valve. Carbon dioxide is supplied as a bottled gas in liquid form. If the cylinder is inverted with the valve open, the gas freezes into solid snow-like pellets known as ‘dry ice’. These gradually vaporise back into a gas — there is no liquid form of carbon dioxide at atmospheric pressure. As a general guide you should add at least 0.5 kg of dry ice per 250 litre of tank capacity to ensure the tank is completely filled. Dry ice is very cold and should only be handled with gloves or tongs. Note: This method is only suitable for small tanks — up to about 1,000 litres in capacity. In larger tanks the CO2 gas will be so cold and heavy that only the atmosphere at the bottom of the tank will be inerted. FILLING WITH NITROGEN Nitrogen is used to inert the atmosphere inside large tanks — for example in the oil industry — but this is a specialised application. Its use is only recommended for people with the necessary expertise. Nitrogen is slightly lighter than air and tends to rise. When this method is used, it is essential to ensure 23
  • 24. that the tank is completely filled with the gas. A light flow of gas must be maintained throughout the welding operation and any breaks in between. It must be stressed that while carbon dioxide and nitrogen are not toxic, neither gas will support life. No one should enter a tank containing either gas without breathing apparatus. The area in the vicinity must be provided with good natural or mechanical ventilation. 24
  • 25. 5 SAFETY HINTS FOR HOT WORK It is assumed in this booklet that you are already familiar with the correct procedures for welding, brazing or gas cutting. If you are in any doubt, you should obtain a copy of the Occupational Safety & Health booklet Welding Safety. Here are the main safety rules to observe: CLOTHING • Always wear industrial overalls and eye protection during welding and cutting work. Keep overalls fastened up to your neck and round your wrists. • Wear safety footwear if you are handling heavy drums or tanks. Wear gloves or gauntlets while arc welding to protect against shock, burns and radiation burns. EQUIPMENT • Make sure all equipment is in good order. • Make sure flashback arrestors are fitted to gas welding gear. • Beware of leaking hoses and connections which are not gas-tight. • Check insulation of all cables on electric arc welding gear. • Do not arc weld in wet conditions. • Use an isolating transformer with all portable electrical equipment. 25
  • 26. • Make sure welding screens are erected to protect others from ultraviolet radiation. VENTILATION • Make sure your work area is well ventilated. The ultraviolet light from welding converts oxygen in the air around you to ozone, which initiates the lungs. There are also toxic substances in fluxes, filler rods, coatings and cleaning agents. Other poisonous fumes are produced by welding or cutting metal coated with paint, resin or varnish. BURNS • Always cool down hot metal or mark it with chalk if there is a chance someone could accidentally touch it. FIRE PREVENTION • Keep a fire extinguisher handy, particularly when working on containers with a coating of flammable material such as paint. • Keep the work area free of flammable liquids and wastes or piles of rubbish in which sparks could smoulder. 26
  • 27. 6 ALTERNATIVES TO HOT WORK One way to avoid the dangers associated with hot work on drums and tanks is to consider alternative methods not involving heat. Mechanical drum opening tools are an excellent alternative to gas cutting. Resembling large tin snips, they remove the tops from drums quickly, efficiently and without risk to the operator. Because they cut close to the inside of the drum, they leave no dangerous jagged edges. As an added precaution, particularly if the drum has held a highly flammable solvent, you should fill the drum with water first. For repairing small holes, proprietary compounds of the ‘cold solder’ type may be a suitable alternative to soldering or brazing. A drum opening tool avoids the need for hot work. A highly recommended item 27
  • 28. Proprietary compounds such as “cold solder” may be an alternative to soldering or brazing 28
  • 29. 7 SUMMARY AND ADDITIONAL REMINDERS The message of this booklet can be summarised as follows: • Severe explosions and fires may occur when welding, cutting, brazing or soldering is carried out on fuel tanks, drums and similar vessels that have previously held flammable materials. • Many substances not usually thought of as explosive or flammable may be dangerous. • The only way for hot work to be done safely is for the vessel to be thoroughly cleaned by washing, boiling or steaming as appropriate and the interior carefully checked for residual traces of the substance. • As an additional precaution, the tank should be inerted by filling it with water, steam or an inert gas. • Hot work has its own set of hazards. Make sure you know and follow the safety rules at all times. • Always wear and use the protective clothing and equipment appropriate to the task. • Avoid hot work on potentially dangerous drums wherever possible, e.g. by using mechanical tools. 29
  • 30. Here are some additional safety reminders: • If one compartment of a two-compartment tank has to be repaired or cut, both compartments need to be made safe. The common example is a tractor fuel tank, which contains a main compartment for oil and a small one for petrol. • Never use an empty drum, tank or container as a work platform or as a support for hot work. The torch flame or sparks may ignite vapours or solid residues inside it. Either use a proper support or clean the container first as described in this booklet. • As well as the explosion risks described here, you should also remember the risk of fires. A sudden spurt of flames from filler pipes or other openings can obviously be dangerous. Another danger is that burning material, e.g. flammable liquids may be sprayed on to the clothing of people nearby. • Never enter a tank or vat to carry out cleaning or hot work. Any work in confined spaces is extremely dangerous and should not be attempted by inexperienced people. The special precautions necessary are outside the scope of this booklet but information is available from OSH offlces. 30
  • 31. Don’t use a drum as a work platform unless it has first been cleaned Similarly, don’t use it as a support for hot work 31
  • 32. Summary of Procedures Prior to Beginning Hot Work on Drums and Tanks DRAIN TANK Remove caps, bungs, etc CLEAN TANK Washing Boiling Steaming Residues cannot be removed or as added protection INSPECT TANK Visual inspection Vapour test Residues or vapours absent Residues or vapours present CLEAN TANK Washing Boiling Steaming Solvent INERT TANK Water Steam CO2 or N2 (Specialist applications only) TANK READY 32
  • 33. 8 THE EMPLOYER’S RESPONSIBILITIES Employers are reminded of their legal responsibilities towards workers who are required to carry out the cleaning of tanks, drums, vats, or similar vessels prior to hot work, or to perform hot work on such vessels. • Workers must not carry out this work unless they have been adequately instructed as to the dangers likely to arise and the precautions to be taken. Where necessary, the worker must be adequately supervised by a person with sufficient knowledge of and expertise in the work. • All workers must be provided with the necessary protective clothing and equipment, including eye protection, gloves, suitable footwear, overalls and aprons if appropriate. Workers have an obligation to wear and use these items. • First aid facilities must be provided and be readily accessible to workers. First aid kits should be suitably stocked to deal with the types of injuries possible in this work, i.e. burns, scalds, chemical splashes, eye injuries, cuts and abrasions. 33
  • 34. Employers must supply protective clothing and equipment and workers must use it 34
  • 35. APPENDIX 1: SOME DANGEROUS SUBSTANCES The following is a brief list of common industrial chemicals which may be stored in drums and tanks and which pose fire, explosion or other hazards to people carrying out hot work. The list is not complete and you are urged to treat all chemicals as potentially dangerous. Substances marked with an asterisk are soluble in water and may be removed by washing with water. If you are washing out substances such as cyanide, take care in disposing of the wastes. Do not allow them to enter normal water drains. All such waste must be disposed of in accordance with local bylaws. CHEMICALS Acetone Acrylonitrile Amyl acetate Amyl alcohol Ammonia and compounds Calcium hypochlorite Carbon disulphide Chlorates and perchlorates of sodium, potassium and ammonium Chloroform 35
  • 36. Cyanides Dichloromethane Formaldehyde Glycol ethers and glycol ether acetates Hydrochloric acid Isopropyl alcohol Kerosene Methyl alcohol Methyl ethyl ketone Mineral turpentine Nitric acid Phenol Hydrocarbon solvents (e.g. pentane, hexane heptane, octane) Sodium hypochlorite Styrene Sulphuric acid 1.1.1. Trichloroethane Toluene Turpentine White spirit Xylene EXPLOSIVE DUSTS The following is a list of dusts which present a strong to severe explosion hazard. Again it is not a comprehensive list, and it is wise to treat all dusts as potentially explosive. Aluminium/resin mix Barley/maize/lucerne mix Cardboard Casein 36
  • 37. Coal Cocoa Cornflour Cotton waste Flour Icing sugar Leather Milk powder Paper/wood/resin mix Plastic powder Resin Spice mixes Stock feed Sulphur Wheat Wood INSECTICIDES The following are common members of the organochlorine group of insecticides. These produce highly toxic phosgene gas when subjected to heat. Aldrin Dieldrin DDT Benzene hexachloride (BHC) Chlordane Lindane Methoxychlor 37
  • 38. APPENDIX 2: ACCIDENT REPORTS The Department of Labour investigated, over a typical 6-month period, accidents where hot work had been undertaken on containers holding flammable or combustible materials. Brief details of those accidents are given below: • An engineer was killed when a 6000-litre tank exploded when he lit a welding torch to repair a seam in the tank. The tank was moved 30 metres in the explosion, and an observer who was standing 2 metres away was thrown to the ground by the blast. The tank had been flushed with water for three days prior to the explosion but this did not remove all the explosive substances. • A worker was attempting to remove the lid of a 200-litre container that had previously contained lacquer thinners. The drum, which had both bungs in place when the worker applied heat to the lid, hit the roof of the building 6 metres up. The worker received bruising to his hand. • While removing a cleaning bung from a 70-litre stainless steel boat fuel tank, a worker passed a heated soldering iron over the bung hole. The petrol fumes ignited, throwing the worker on the floor. • A worker, who had a few moments spare time, 38
  • 39. began cutting a 200-litre drum to makes a barbecue. He was unaware of the contents of the drum, which exploded when the torch began the cut. He received minor injuries in the incident. • A worker passed a gas torch to his colleague over the open lid of a bitumen tank, causing an explosion. The worker, who was on top of the tank, received 10% burns to his face and left hand and his leg was broken in three places. The worker on the other side of the tank escaped injury. • A welding contractor was attempting to fit a tap into a 5000 litre tank. A cut had been started in one end of the tank when it exploded. The tank was turned around and flipped over. The opposite end of the tank was blown approximately 42 metres, soaring over a stand of trees 12 metres high and landing in a vacant section. The contractor received cracked ribs, a dislocated shoulder, injuries to his collar bone and severe bruising all oyer the body. There has been no let-up in accidents and many more examples could be given. Remember, all accidents of this type are potentially fatal. Don’t let it happen to you! 39