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Pesticides in the
Environment
Dr. Ahmed Abdel-Fattah A. Abdel-
Megeed
PhD Hamburg University, Germany
Plant Protection Department
Pesticides Chemistry and Environmental Toxicology
Alexandria University
Our Environment
Everything around us – air, soil,
water, plants, houses, oceans
Goals of responsible pesticide users
follow good practices that achieve:
effective pest control
little risk to environment
Responsible pesticide applicators should
follow good management practices that
result in effective pest control with little risk
to the environment.
Protecting the environment starts with reading
the pesticide label.
Each product label has a section on possible
environmental hazards.
Pesticide Movement
Air (drift)
particles, droplets
vapors (fumigants, non fumigants)
Water
drift, leaching, runoff
spills, leaks
improper disposal
too much water – rain, irrigation, etc.
On plants, animals, objects
contaminated clothing
high residues, over tolerances
Once applied, not all pesticides act the same.
Nontarget organisms harmed
by pesticides in two ways:
1. Immediate or direct injury
2. Long-term consequences of environmental
pollution
How Pesticides Get Into
Groundwater
Practices of users
Water (or lack of) on site surfaces
Chemical nature of pesticide
Type of soil at release site
Location of groundwater
distance from surface
geological formation above it
Groundwater Contaminations
Due to Practices of Pesticide
Users
Not following label directions
Overdosing (it’s illegal!)
Application method
Back-siphoning
Storage close to water*
Mixing/cleaning sites*
Improper disposal
*100 feet – See State Laws
Groundwater Contamination Due
to Pesticide Factors
Solubility
Adsorption
Persistence
Low adsorption of pesticides to soil
particles allows movement through
the soil.
Persistent pesticides are present for longer
periods of time, increasing their chance for
leaching into the groundwater
Groundwater Contamination Due
to Soil Factors
Texture – sand, silt, clay
Permeability – how fast water moves
Organic Matter – holds pesticides
Groundwater Contamination
Due to Geology
(location of water, etc.)
Water depth from surface*
Permeability of soil layers
bad: gravel, limestond
Sinkholes
*varies due to rain, snow, evaporation, plant uptake, frozen
ground, amount withdrawn
Endangered Species
The Fish and Wildlife Service Lists
Over 300 animals
Over 200 plants
Review Section Four
Pesticides in the Environment
Harmful Effects
Protective Equipment
Pesticides – Harm to Humans
Hazard – risk of harmful effects due to:
Toxicity – ability to cause harm
Exposure – Contact of the chemical with the
body
Hazard = Toxicity X Exposure
Risk =
Toxicity x Exposure
Label Signal Words –
(Toxicity to Humans)
DANGER* - Highly toxic
WARNING – Moderately
toxic
CAUTION – Slightly toxic
*with POISON/skull/crossbones – high
acute toxicity
Without Poison/skull/crossbones – high
skin & eye irritation potential
Routes of Exposure to
Pesticides
Oral – mouth
Dermal – skin
Inhalation – nose (breathing)
Ocular - eyes
Types of Toxicity to
Pesticides
Acute – usually immediate, obvious,
reversible
Delayed – “chronic”, usually from repeated
doses
Allergic – immune system response to
chemicals
Acute Effects
Oral – examples: burned mouth, sore throat,
upset stomach
Inhalation – examples: pain or tightness in
chest
Dermal (skin) – examples: itching, blisters,
rash
Ocular (eyes) – examples: irritation,
temporary or permanent blindness
Delayed (Chronic) Effects
May appear long after exposure:
Tumors
Gene effects
Miscarriage
Impotence
Birth defects
Infertility
Sterility
Nervous system disorders
Types of Allergic Effects
Systemic – as asthma, shock
Skin irritation – rash, blisters, sores
Eye and nose – itchy/watery eyes, sneezing
Will occur with every exposure to the
offending chemical
Anatomy
Forearm
Palm of hand
Ball of feet
Abdomen
Scalp
Forehead
Ear canal
Scrotum
% Absorption
8.6
11.8
13.5
18.4
32.1
36.3
46.5
100.0
Insecticide
Temik
Thimet
Cygon
Pydrin
Malathion
Table salt
Oral LD50(mg/kg)
1
3
215
451
1000
3320
Common insecticides
Less toxic
Emergency Responses
First aid
Call physician/go to hospital
Take chemical or labeling
Call – Poison Control Center
*pesticide illness may be confused with heat stress, heat cramps,
or plants poisoning
First Aid - Skin
Drench with water
Remove clothes
Wash body with mild soap/water
Avoid chills/overheating
Burns: apply loose, clean, dry covering
No ointments (unless prescribed)
First Aid - Eyes
Wash quickly (eye wash or water)
Rinse eye with cool, clean water 15 for more
minutes
No chemicals/drugs in rinse
First Aid - Inhalation
Get to fresh air
Loosen clothing
Artificial respiration (if needed)
First Aid – Mouth/Swallowed
Rinse mouth
Drink milk/water (up to 1 qt.)
Induce vomiting (if label says so)
place victim face down
spoon to back of throat (or)
give syrup of ipecac
First Aid – Mouth/Swallowed
Do NOT induce vomiting if:
unconscious/convulsions
corrosive poison swallowed
EC or oil solutions
label prohibits
Read the label to determine first aid measures
as whether you should or should not induce
vomiting.
Vomiting Procedures
Adult – two tablespoons of Syrup of Ipecac and
two glasses of water
Child – one tablespoon of Syrup of Ipecac and
one glass of water
Federal law requires that highly toxic pesticides
contain instructions for the physician on the
label in case of pesticide poisoning.
Poison Control Centers
West Alabama Poison Control Center
1-800-462-0800
Children’s Hospital
1-800-292-6678
Heat Stress
Occurs when body is subjected to
extreme heat.
May affect pesticide handlers working in
hot conditions.
Also avoid heat stress by adjusting work loads
and drinking a lot of fluids.
Review Section Five
Harmful Effects
Protective Equipment
Q & A
What are the four routes through which
pesticides can contact your body and cause
you to be exposed?
Q & A
Name four symptoms of
pesticide poisoning.
Q & A
What is the first ting you should do when you
or someone else is overexposed to
pesticides?
Q & A
What is heat stress?

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Pesticides and the Environment: Protecting Ourselves and Future Generations

  • 1. Pesticides in the Environment Dr. Ahmed Abdel-Fattah A. Abdel- Megeed PhD Hamburg University, Germany Plant Protection Department Pesticides Chemistry and Environmental Toxicology Alexandria University
  • 2. Our Environment Everything around us – air, soil, water, plants, houses, oceans Goals of responsible pesticide users follow good practices that achieve: effective pest control little risk to environment
  • 3. Responsible pesticide applicators should follow good management practices that result in effective pest control with little risk to the environment.
  • 4. Protecting the environment starts with reading the pesticide label. Each product label has a section on possible environmental hazards.
  • 5.
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  • 7.
  • 8.
  • 9. Pesticide Movement Air (drift) particles, droplets vapors (fumigants, non fumigants) Water drift, leaching, runoff spills, leaks improper disposal too much water – rain, irrigation, etc. On plants, animals, objects contaminated clothing high residues, over tolerances
  • 10.
  • 11.
  • 12.
  • 13. Once applied, not all pesticides act the same.
  • 14.
  • 15. Nontarget organisms harmed by pesticides in two ways: 1. Immediate or direct injury 2. Long-term consequences of environmental pollution
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  • 17.
  • 18.
  • 19. How Pesticides Get Into Groundwater Practices of users Water (or lack of) on site surfaces Chemical nature of pesticide Type of soil at release site Location of groundwater distance from surface geological formation above it
  • 20. Groundwater Contaminations Due to Practices of Pesticide Users Not following label directions Overdosing (it’s illegal!) Application method Back-siphoning Storage close to water* Mixing/cleaning sites* Improper disposal *100 feet – See State Laws
  • 21.
  • 22.
  • 23. Groundwater Contamination Due to Pesticide Factors Solubility Adsorption Persistence
  • 24.
  • 25. Low adsorption of pesticides to soil particles allows movement through the soil.
  • 26. Persistent pesticides are present for longer periods of time, increasing their chance for leaching into the groundwater
  • 27. Groundwater Contamination Due to Soil Factors Texture – sand, silt, clay Permeability – how fast water moves Organic Matter – holds pesticides
  • 28. Groundwater Contamination Due to Geology (location of water, etc.) Water depth from surface* Permeability of soil layers bad: gravel, limestond Sinkholes *varies due to rain, snow, evaporation, plant uptake, frozen ground, amount withdrawn
  • 29. Endangered Species The Fish and Wildlife Service Lists Over 300 animals Over 200 plants
  • 30.
  • 31.
  • 32. Review Section Four Pesticides in the Environment
  • 34.
  • 35. Pesticides – Harm to Humans Hazard – risk of harmful effects due to: Toxicity – ability to cause harm Exposure – Contact of the chemical with the body Hazard = Toxicity X Exposure
  • 36. Risk = Toxicity x Exposure
  • 37. Label Signal Words – (Toxicity to Humans) DANGER* - Highly toxic WARNING – Moderately toxic CAUTION – Slightly toxic *with POISON/skull/crossbones – high acute toxicity Without Poison/skull/crossbones – high skin & eye irritation potential
  • 38. Routes of Exposure to Pesticides Oral – mouth Dermal – skin Inhalation – nose (breathing) Ocular - eyes
  • 39. Types of Toxicity to Pesticides Acute – usually immediate, obvious, reversible Delayed – “chronic”, usually from repeated doses Allergic – immune system response to chemicals
  • 40. Acute Effects Oral – examples: burned mouth, sore throat, upset stomach Inhalation – examples: pain or tightness in chest Dermal (skin) – examples: itching, blisters, rash Ocular (eyes) – examples: irritation, temporary or permanent blindness
  • 41. Delayed (Chronic) Effects May appear long after exposure: Tumors Gene effects Miscarriage Impotence Birth defects Infertility Sterility Nervous system disorders
  • 42. Types of Allergic Effects Systemic – as asthma, shock Skin irritation – rash, blisters, sores Eye and nose – itchy/watery eyes, sneezing Will occur with every exposure to the offending chemical
  • 43. Anatomy Forearm Palm of hand Ball of feet Abdomen Scalp Forehead Ear canal Scrotum % Absorption 8.6 11.8 13.5 18.4 32.1 36.3 46.5 100.0
  • 45.
  • 46. Emergency Responses First aid Call physician/go to hospital Take chemical or labeling Call – Poison Control Center *pesticide illness may be confused with heat stress, heat cramps, or plants poisoning
  • 47. First Aid - Skin Drench with water Remove clothes Wash body with mild soap/water Avoid chills/overheating Burns: apply loose, clean, dry covering No ointments (unless prescribed)
  • 48.
  • 49. First Aid - Eyes Wash quickly (eye wash or water) Rinse eye with cool, clean water 15 for more minutes No chemicals/drugs in rinse
  • 50.
  • 51. First Aid - Inhalation Get to fresh air Loosen clothing Artificial respiration (if needed)
  • 52.
  • 53. First Aid – Mouth/Swallowed Rinse mouth Drink milk/water (up to 1 qt.) Induce vomiting (if label says so) place victim face down spoon to back of throat (or) give syrup of ipecac
  • 54. First Aid – Mouth/Swallowed Do NOT induce vomiting if: unconscious/convulsions corrosive poison swallowed EC or oil solutions label prohibits
  • 55.
  • 56. Read the label to determine first aid measures as whether you should or should not induce vomiting.
  • 57. Vomiting Procedures Adult – two tablespoons of Syrup of Ipecac and two glasses of water Child – one tablespoon of Syrup of Ipecac and one glass of water
  • 58. Federal law requires that highly toxic pesticides contain instructions for the physician on the label in case of pesticide poisoning.
  • 59.
  • 60. Poison Control Centers West Alabama Poison Control Center 1-800-462-0800 Children’s Hospital 1-800-292-6678
  • 61. Heat Stress Occurs when body is subjected to extreme heat. May affect pesticide handlers working in hot conditions.
  • 62. Also avoid heat stress by adjusting work loads and drinking a lot of fluids.
  • 63. Review Section Five Harmful Effects Protective Equipment
  • 64. Q & A What are the four routes through which pesticides can contact your body and cause you to be exposed?
  • 65. Q & A Name four symptoms of pesticide poisoning.
  • 66. Q & A What is the first ting you should do when you or someone else is overexposed to pesticides?
  • 67. Q & A What is heat stress?