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International Journal of Engineering Research and Development
e-ISSN: 2278-067X, p-ISSN: 2278-800X, www.ijerd.com
Volume 8, Issue 2 (August 2013), PP. 99-104
99
Study of Decomposing Polymer Matrix Composites at
High Temperature Using FEA
Gudepu.Adinarayana1
, Kancharla.Bullibabu2
, Panasa.Nagasarveswararao3
1
Assoc.Prof, Department of Mechanical Department, GATE Engg College, Kodad, AP, INDIA
2
Assit.Prof, Department of Mechanical Department, KITS, Kammam. AP, INDIA
3
Assit.Prof, Department of Mechanical Department, GATE Engg College, Kodad, AP, INDIA
Abstract:- A three-dimensional model to describe the thermal behavior of polymer matrix composites (PMCs)
in fire is developed and implemented into commercial finite element package ANSYS. The model is employed
to predict the temperature and the internal pressure in one-sided heating tests for glass-talc/phenolic composites
and it is validated by comparing the predicted results with the measured data. The effect of porosity and
permeability on the temperature and the internal pressure is examined. In addition, an experimental technique
based on Vacuum Assisted Resin Transfer Molding (VARTM) is developed to manufacture PMCs with inserted
hypodermic needle for internal pressure measurement. One-sided heating tests are conducted on the glass/vinyl
ester composites to measure the pressure at different locations through thickness during the decomposition
process. The model is explored to simulate the heating process. Both predicted and measured results indicate
that the range of the internal pressure peak in the designed test is around 1.1-1.3 atmosphere pressure.
Keywords:- Polymer-matrix composites (PMCs); Finite element analysis; Resin transfer molding (RTM) &
(A4) is the model number used in ansys.
I. INTRODUCTION
Polymer matrix composites (PMCs) are widely used in a number of industrial and military areas, such
as bridges, wind turbine blades, industrial vessels, and submarine structures. Advantages of PMCs include their
high specific strength, long fatigue life, and excellent corrosion resistance. On the other hand, there are
challenging issues for PMC application, including low rigidity, poor impact resistance, high cost, and
difficulties in joining. In addition, one of the continuing concerns is the fire performance of PMCs. When the
composites are exposed to fire, there is thermal conduction for heat transfer inside the composites at the
beginning of the heating. As the temperature increases, the polymer matrix starts to decompose and gases are
generated by the decomposition reaction. A porous network in the heated composites is formed with the
continuing decomposition. Some gases carrying heat flow out of the composites and affect the temperature
distribution by heat convection. Others are trapped inside the pores and impede the heat conduction because of
their low thermal conductivity. Meanwhile, the gases held in the solid accumulate and build up the internal
pressure which may contribute to the eventual failure through processes such as delamination. A description of
this internal pressure is necessary for a better understanding of thermo-mechanical behavior of composites at
high temperature. In addition, the experimental measurements of this pressure are needed to validate the existing
models. Some models have been developed to consider the pressure effect on thermo- mechanical response of
composites in fire. Henderson et al. presented a one- dimensional transient thermal model including the
combined effects of thermo-chemical expansion and storage of the decomposition gases. The model was further
developed in by relaxing the assumption of local thermal equilibrium existing between the solid matrix and
decomposition gases within the porous network of the composites.
II. MODELING AND ANALYSIS USING ANSYS
Fig.1 Generated model in ANSYS Fig.2 Meshed model
Study of Decomposing Polymer Matrix Composites at High…
100
III. RESULTS & DISCUSSION
Table.1 Global temperature results table
Fig.3 Global minimum temprature graph Fig.4 Global maximum temprature graph
Fig.5 Transient Heat flux Fig.6 Transient Heat flux graph
Study of Decomposing Polymer Matrix Composites at High…
101
Table.2 Transient thermal results
Fig.7 Transient thermal graph
Study of Decomposing Polymer Matrix Composites at High…
102
Fig.8 Transient thermal total heat flux
Fig.9 Transient thermal total heat flux graph Table.3 Transient thermal total heat flux results
Fig.10 Directional heat flux
Study of Decomposing Polymer Matrix Composites at High…
103
Fig.11 Directional heat flux graph Table.4 Directional heat flux results
IV. CONCLUSION
A three-dimensional model to describe the thermal behavior of composites in fire was developed and
implemented into the finite element commercial software ANSYS by user subroutine UMATHT. The model
was used to simulate the one-sided heating tests conducted for glass-talc/phenolic composites by the overlaid
element technique. The predicted temperatures and pressures at different locations were compared to the
calculated results and measured data from and it is found they have good agreement. The effect of porosity and
permeability on thermal response of composites was studied by comparing the temperature, pressure,
decomposition factor, and mass flux calculated from the model using different sets of property inputs.
Temperature is insensitive to permeability; however, permeability has a strong influence on pressure. The peak
of pressure increases by about three times with permeability reduced by one order of magnitude. The influence
of porosity on both temperature and pressure is apparent. Smaller porosity facilitates the heat transfer through
composites. In order to investigate the internal pressure of glass/vinyl ester composites and overcome the
leakage issue of previous experimental technique for pressure measurement, a manufacturing procedure based
on VARTM was proposed and executed to make the glass/vinyl ester composite panel with inserted hypodermic
needle. The one-sided heating tests for the sample with inserted needle were set up to measure the internal
pressure at mid-surface and the location of one quarter thickness from the exposed surface. In addition, the
three-dimensional model was employed to analyze the heating tests for glass/vinyl ester composites with
measured temperatures on the exposed and unexposed surfaces as thermal boundary condition. The predicted
pressures can capture the trend of the measured pressure history curves and both the measured and predicted
results indicate a pressure peak in the range of 1.1-1.3 atmosphere pressure for glass/vinyl ester systems in the
conducted heating tests. The good match between the predicted results and measured data for two different
material systems validates the generality of the model.
REFERENCES
[1]. Brown, J.R. and Z. Mathys, Reinforcement and Matrix Effects on the Combustion Properties of Glass
Reinforced Polymer Composites. Composites Part A: Applied Science and Manufacturing, 1997. 28(7):
p. 675-681.
[2]. Sorathia, U., et al., Fire Safety of Marine Composites, in 45th International SAMPE Symposium and
Exhibition. 2000, SAMPE, Covina, CA, United States: Long Beach, CA, USA. p. II/-.
[3]. Lyon, R.E., et al., Fire-Resistant Aluminosilicate Composites. Fire and Materials, 1997. 21(2): p. 67-
73.
[4]. Sastri, S.B., J.P. Armistead, and T.M. Keller, Phthalonitrile-Carbon Fiber Composites. Polymer
Composites, 1996. 17(6): p. 816-822.
[5]. Sorathia, U. and C. Beck, Fire Protection of Glass/Vinyl Ester Composites for Structural Applications,
in 41st International SAMPE Symposium and Exhibition. 1996, SAMPE, Covina, CA, United States:
Anaheim, CA, USA. p. 687-697.
[6]. Brown, J.R., et al., Fire-Retardant Performance of Some Surface Coatings for Naval Ship Interior
Applications. Fire and Materials, 1995. 19(3): p. 109-118.
[7]. Ohlemiller, T., T. Cleary, and J. Shields, Effect of Ignition Conditions on Upward Flame Spread on a
Study of Decomposing Polymer Matrix Composites at High…
104
Composite Material in a Corner Configuration, in 41st
International SAMPE Symposium and
Exhibition. 1996, SAMPE, Covina, CA, United States: Anaheim, CA, USA. p. 734-747.
[8]. Henderson, J.B., et al., Characterization of the High-Temperature Behaviour of a Glass-Filled Polymer
Composite. Composites, 1987. 18(3): p. 205-215.
[9]. Henderson, J.B. and M.R. Tant, Measurement of Thermal and Kinetic Propertiesof a Glass-filled
Polymer Composite to High Temperatures, in 9th EuropeanConference on Thermophysical Properties.
1986: Manchester, UK. p. 17-28.

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International Journal of Engineering Research and Development (IJERD)

  • 1. International Journal of Engineering Research and Development e-ISSN: 2278-067X, p-ISSN: 2278-800X, www.ijerd.com Volume 8, Issue 2 (August 2013), PP. 99-104 99 Study of Decomposing Polymer Matrix Composites at High Temperature Using FEA Gudepu.Adinarayana1 , Kancharla.Bullibabu2 , Panasa.Nagasarveswararao3 1 Assoc.Prof, Department of Mechanical Department, GATE Engg College, Kodad, AP, INDIA 2 Assit.Prof, Department of Mechanical Department, KITS, Kammam. AP, INDIA 3 Assit.Prof, Department of Mechanical Department, GATE Engg College, Kodad, AP, INDIA Abstract:- A three-dimensional model to describe the thermal behavior of polymer matrix composites (PMCs) in fire is developed and implemented into commercial finite element package ANSYS. The model is employed to predict the temperature and the internal pressure in one-sided heating tests for glass-talc/phenolic composites and it is validated by comparing the predicted results with the measured data. The effect of porosity and permeability on the temperature and the internal pressure is examined. In addition, an experimental technique based on Vacuum Assisted Resin Transfer Molding (VARTM) is developed to manufacture PMCs with inserted hypodermic needle for internal pressure measurement. One-sided heating tests are conducted on the glass/vinyl ester composites to measure the pressure at different locations through thickness during the decomposition process. The model is explored to simulate the heating process. Both predicted and measured results indicate that the range of the internal pressure peak in the designed test is around 1.1-1.3 atmosphere pressure. Keywords:- Polymer-matrix composites (PMCs); Finite element analysis; Resin transfer molding (RTM) & (A4) is the model number used in ansys. I. INTRODUCTION Polymer matrix composites (PMCs) are widely used in a number of industrial and military areas, such as bridges, wind turbine blades, industrial vessels, and submarine structures. Advantages of PMCs include their high specific strength, long fatigue life, and excellent corrosion resistance. On the other hand, there are challenging issues for PMC application, including low rigidity, poor impact resistance, high cost, and difficulties in joining. In addition, one of the continuing concerns is the fire performance of PMCs. When the composites are exposed to fire, there is thermal conduction for heat transfer inside the composites at the beginning of the heating. As the temperature increases, the polymer matrix starts to decompose and gases are generated by the decomposition reaction. A porous network in the heated composites is formed with the continuing decomposition. Some gases carrying heat flow out of the composites and affect the temperature distribution by heat convection. Others are trapped inside the pores and impede the heat conduction because of their low thermal conductivity. Meanwhile, the gases held in the solid accumulate and build up the internal pressure which may contribute to the eventual failure through processes such as delamination. A description of this internal pressure is necessary for a better understanding of thermo-mechanical behavior of composites at high temperature. In addition, the experimental measurements of this pressure are needed to validate the existing models. Some models have been developed to consider the pressure effect on thermo- mechanical response of composites in fire. Henderson et al. presented a one- dimensional transient thermal model including the combined effects of thermo-chemical expansion and storage of the decomposition gases. The model was further developed in by relaxing the assumption of local thermal equilibrium existing between the solid matrix and decomposition gases within the porous network of the composites. II. MODELING AND ANALYSIS USING ANSYS Fig.1 Generated model in ANSYS Fig.2 Meshed model
  • 2. Study of Decomposing Polymer Matrix Composites at High… 100 III. RESULTS & DISCUSSION Table.1 Global temperature results table Fig.3 Global minimum temprature graph Fig.4 Global maximum temprature graph Fig.5 Transient Heat flux Fig.6 Transient Heat flux graph
  • 3. Study of Decomposing Polymer Matrix Composites at High… 101 Table.2 Transient thermal results Fig.7 Transient thermal graph
  • 4. Study of Decomposing Polymer Matrix Composites at High… 102 Fig.8 Transient thermal total heat flux Fig.9 Transient thermal total heat flux graph Table.3 Transient thermal total heat flux results Fig.10 Directional heat flux
  • 5. Study of Decomposing Polymer Matrix Composites at High… 103 Fig.11 Directional heat flux graph Table.4 Directional heat flux results IV. CONCLUSION A three-dimensional model to describe the thermal behavior of composites in fire was developed and implemented into the finite element commercial software ANSYS by user subroutine UMATHT. The model was used to simulate the one-sided heating tests conducted for glass-talc/phenolic composites by the overlaid element technique. The predicted temperatures and pressures at different locations were compared to the calculated results and measured data from and it is found they have good agreement. The effect of porosity and permeability on thermal response of composites was studied by comparing the temperature, pressure, decomposition factor, and mass flux calculated from the model using different sets of property inputs. Temperature is insensitive to permeability; however, permeability has a strong influence on pressure. The peak of pressure increases by about three times with permeability reduced by one order of magnitude. The influence of porosity on both temperature and pressure is apparent. Smaller porosity facilitates the heat transfer through composites. In order to investigate the internal pressure of glass/vinyl ester composites and overcome the leakage issue of previous experimental technique for pressure measurement, a manufacturing procedure based on VARTM was proposed and executed to make the glass/vinyl ester composite panel with inserted hypodermic needle. The one-sided heating tests for the sample with inserted needle were set up to measure the internal pressure at mid-surface and the location of one quarter thickness from the exposed surface. In addition, the three-dimensional model was employed to analyze the heating tests for glass/vinyl ester composites with measured temperatures on the exposed and unexposed surfaces as thermal boundary condition. The predicted pressures can capture the trend of the measured pressure history curves and both the measured and predicted results indicate a pressure peak in the range of 1.1-1.3 atmosphere pressure for glass/vinyl ester systems in the conducted heating tests. The good match between the predicted results and measured data for two different material systems validates the generality of the model. REFERENCES [1]. Brown, J.R. and Z. Mathys, Reinforcement and Matrix Effects on the Combustion Properties of Glass Reinforced Polymer Composites. Composites Part A: Applied Science and Manufacturing, 1997. 28(7): p. 675-681. [2]. Sorathia, U., et al., Fire Safety of Marine Composites, in 45th International SAMPE Symposium and Exhibition. 2000, SAMPE, Covina, CA, United States: Long Beach, CA, USA. p. II/-. [3]. Lyon, R.E., et al., Fire-Resistant Aluminosilicate Composites. Fire and Materials, 1997. 21(2): p. 67- 73. [4]. Sastri, S.B., J.P. Armistead, and T.M. Keller, Phthalonitrile-Carbon Fiber Composites. Polymer Composites, 1996. 17(6): p. 816-822. [5]. Sorathia, U. and C. Beck, Fire Protection of Glass/Vinyl Ester Composites for Structural Applications, in 41st International SAMPE Symposium and Exhibition. 1996, SAMPE, Covina, CA, United States: Anaheim, CA, USA. p. 687-697. [6]. Brown, J.R., et al., Fire-Retardant Performance of Some Surface Coatings for Naval Ship Interior Applications. Fire and Materials, 1995. 19(3): p. 109-118. [7]. Ohlemiller, T., T. Cleary, and J. Shields, Effect of Ignition Conditions on Upward Flame Spread on a
  • 6. Study of Decomposing Polymer Matrix Composites at High… 104 Composite Material in a Corner Configuration, in 41st International SAMPE Symposium and Exhibition. 1996, SAMPE, Covina, CA, United States: Anaheim, CA, USA. p. 734-747. [8]. Henderson, J.B., et al., Characterization of the High-Temperature Behaviour of a Glass-Filled Polymer Composite. Composites, 1987. 18(3): p. 205-215. [9]. Henderson, J.B. and M.R. Tant, Measurement of Thermal and Kinetic Propertiesof a Glass-filled Polymer Composite to High Temperatures, in 9th EuropeanConference on Thermophysical Properties. 1986: Manchester, UK. p. 17-28.