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MISS KRISHNAMAYEE SETHI, ASSISTANT PROFESSOR OF AGRONOMY
INTRODUCTION TO FERTILIZERS
• In the same way that humans need to eat properly to stay
healthy, so plants need certain nutrients to grow properly.
• Fertilizer is a substance added to soil to improve plant’s
growth and yield. Basically it is a chemical or natural substance
is added to soil or land to increase its fertility.
• Fertilizers are food supplements for plants and need 16
nutrients to be healthy.
WHAT IS A FERTILIZER ?
A fertilizer is any material of natural or
synthetic origin that is applied to soils
or to plant tissues to supply one or
more plant nutrients essential to the
growth of plants.
COMPLETE VS. INCOMPLETE
• Complete has all three primary nutrients-nitrogen
phosphorous & potassium
• Examples: 10-10-10, 15-30-15, 20-5-20
• Incomplete DOES NOT have all three primary
nutrients
• Examples: 20-0-0, 0-20-0, 12-0-44
BASIC FORMS OF FERTILIZERS:
• Granular- designed to be scratched into the soil
and water soluble.
• Powdered- designed to be dissolved in water for
liquid feeding to soil and foliage.
• Liquid- usually a concentrated form to be mixed
with water.
CLASSIFICATION OF
FERTILISERS
Fertilizers
Straight Complex Mixed
• Straight fertilizers are
those which supply
only one primary
plant nutrient (N, P &
K).
• E.g. Urea,
Ammonium sulphate,
Potassium chloride
and Potassium
sulphate.
• Complex fertilizers
contain 2 or 3
primary plant
nutrients of which
two primary nutrients
are in chemical
combination.
• Usually produced in
granular form.
• Diammonium
phosphate,
Nitrophosphates,
Ammonium
phosphate
• Mixed fertilizers
are physical
mixtures of
straight fertilisers.
• They contain two
or three primary
plant nutrients.
• made by
thoroughly mixing
the ingredients
either
mechanically or
manually.
BASED ON CONCENTRATION OF
PRIMARY PLANT NUTRIENTS (N, P &
K) IN FERTILISERS:
LOW ANALYSIS
FERTILISERS
• Fertilisers contain less than
25% of primary nutrients.
• Example-
 SSP(16% P₂O₅)
 Sodium nitrate (16% N)
HIGH ANALYSIS
FERTILISERS
• Total content of primary
nutrients is above 25%.
• Example-
 Urea (46% N)
 Anhydrous ammonia (82.2%
N)
Ammonium phosphate (20% N
+20% P₂O₅)
CLASSIFICATION BASED ON
PHYSICAL FORM:
SOLID
FERTILIZERS
• Powder (single
superphosphate)
• Crystals (Ammonium sulphate)
• Prills (Urea, Diammonium
phosphate, superphosphate)
• Granules (Holland granules)
• Supergranules (Urea
supergranules)
• Briquettes (Urea briquettes)
LIQUID
FERTILIZERS
• Liquid form fertilizers are
applied with irrigation water or
for direct application.
• 2 types-
• 1- clear liquid fertilisers (when
the fertilisers are completely
dissolved in water)
• 2- Suspension liquid fertilisers
(when fertilisers are suspended
as fine particles in water)
BASED ON THE NATURE OF
FERTILISERS:
Acid Forming Fertilisers
• Fertilisers which leave an acid
residue in the soil.
• Apply acid forming fertilisers to
alkaline soil.
• The amount of calcium carbonate
required to neutralize the acid
residue is called its Acid
equivalent.
Alkaline Forming Fertilisers
Or Basic Fertilisers
• Fertilisers which leave an
alkaline residue in the soil.
• Apply acid forming
fertilisers to alkaline soil.
Fertiliser Acid equivalent
Ammonium chloride 128
Ammonium sulphate 110
Ammonium sulphate
nitrate
93
Ammonium phosphate 86
Urea 80
Fertilisers Equivalent basicity
Sodium nitrate 29
Calcium nitrate 21
Calcium cynaide 63
Dicalcium phosphate 25
FERTILIZER GRADE:
• Fertiliser grade refers to the minimum percentage of
nitrogen(N), Phosphorus(P₂O₅) & Potash(K₂O) present
in fertilizer material.
• Fertilizer analysis expresses weight as a percent of
nitrogen, phosphorus and potassium
Fertilizer Analysis
For Example
A 100 kg bag of fertilizer has an grade of 15-5-18.
• Nitrogen: 100 X 15%=15 Kg
• Phosphorus: 100 X 5%=5 Kg
• Potassium: 100 X 18%=18 Kg
• The fertilizer materials containing nitrogen are called
nitrogenous fertilisers.
• They may contain secondary nutrients like Calcium and
Sulphur.
NITRATE
FERTILIZERS
1. They are highly mobile in soil
therefore suitable for top
dressing.
2. Highly soluble subjected and
to leaching.
3. Subjected to denitrification in
waterlogged soils.
4. Increase alkalinity as they are
basic in their residual effect.
• Sodium nitrate
(NaNO₃)
• Calcium nitrate
(Ca(NO₃)₂)
AMMONIACAL
FERTILISERS
• Easily available to the plants as
they are readily soluble in water.
• Leaching losses are less as
ammonium ions are adsorbed on
clay complex.
• Reduce alkalinity as they are
acidic in their residual effect on
the soils.
• Well suited to submerged soils.
• Ammonium
sulphate
((NH₄)₂SO₄)
• Ammonium
chloride (NH₄Cl)
• Anhydrous
ammonia (NH₃)
NITRATE &
AMMONIACAL
FERTILISERS • Easily available to the plants as
they are readily soluble in water.
• Leaching losses are less.
• Reduce alkalinity as they are
acidic in their residual effect on
the soils.
• Ammonium nitrate
(NH₄NO₃)
• CaNH₄NO₃ -
Calcium
ammonium nitrate
(CAN)
AMIDE FERTILISERS OR ORGANIC
FERTILIZERS
• Urea (CO(NH)₂)
• Calcium cyanide (CaCN₂)
Fertilizers Forms of nutrient N% Others Nature
KNO₃ Nitrate 13.85 K₂O-46-47 Basic
Ca(NO₃)₂ Nitrate 15.5 Ca-19.4 Basic
NaNO₃ Nitrate 16 Basic
(NH₄)₂SO₄ Ammoniacal 20.6-21 S-24.5 Acidic
NH₄Cl Ammoniacal 25.5-26 Cl-66 Acidic
(NH₄)₂SO₄ .
NH₄NO₃
Ammoniacal 26 S-15 Acidic
CAN Ammoniacal and
Nitrate
25-28 Neutral
NH₄NO₃
(Highly
hygroscopic)
50%- Ammonium
50%- Nitrate
33-35 Acidic
Anhydrous
ammonia
Ammoniacal 80-82 Highly Acidic
Urea
[CO(NH₂)₂]
Amide 46 Acidic
CaCN₂ Amide 20.6-21 Basic
Phosphorus content in fertilizers is expressed in
oxidized form (P₂O₅).
In soil and plant phosphorus is expressed in elemental
form.
The conversion factors:
P→ P₂O₅ = 2.29
P₂O₅ →P = 0.43
CLASSIFICATION OF PHOSPHATIC
FERTILIZERS:
N P₂O₅ Others
SSP - 16-20 Ca-19.5,
S-12.5
DSP - 32 -
TSP - 46-48 -
MAP 11-12 48 -
DAP 18 46 -
• Mostly suitable for
neutral and alkaline soil.
• They form insoluble iron
and aluminium
phosphates in acid soils.
• Mostly used in short
duration crops like
Wheat, Sorghum and
Pulses.
A: WATER SOLUBLE PHOSPHORIC ACID
CLASSIFICATION OF PHOSPHATIC
FERTILIZERS:
P₂O₅
%
DCP
(Dicalcium
phosphate)
34-39
Basic slag 14-18
• They are basic in reaction
so suitable for acid soil.
• Mostly suitable for long
duration crops like Sugar
cane, Tapioca, Tea,
Coffee, Low land rice.
B: CITRIC ACID SOLUBLE PHOSPHORIC ACID
CLASSIFICATION OF PHOSPHATIC
FERTILIZERS:
P₂O₅
%
Rock phosphate 20-40
Raw bone meal 2-2.5
Steamed bone meal 22
• Mostly suitable for
strongly acidic and
organic soil.
• Suitable for plantation
crops like tea, coffee,
rubber, cocoa and
coconut.
C: CITRIC ACID & WATER INSOLUBLE
PHOSPHORIC ACID
Potash content in fertilizers is expressed in oxidized
form (K₂O).
In soil and plant phosphorus is expressed in elemental
form.
The conversion factors:
K→ K₂O = 1.2
K₂O →K = 0.83
CLASSIFICATION OF POTASSIC
FERTILIZERS:
K₂O
(%)
MOP (Muriate
of Potash) or
POTASSIUM
CHLORIDE
(KCl)
58-60
• Fertiliser is suitable for acidic
and heavy soils but not suitable
for alkaline soil.
• Presence of chloride in the
fertlisers make it unsuitable for
sugar crops, tobacco and potato.
A: CHLORIDE FORM
CLASSIFICATION OF POTASSIC
FERTILIZERS:
K₂O
(%)
POTASSIUM
SULPHATE
48-50 S-17.5
POTASSIUM
MAGNESIUM
SULPHATE
22 Mg-11
S-22
POTASSIUM
NITRATE or
SALT PETRE or
NITRE
44 N-13
• KNO₃ is an
excellent source of
potassium and
nitrogen.
• It is mainly used
for fruit trees and
crops such as
tobacco and
vegetables.
B: NON-CHLORIDE FORM
CALCIUM, MAGNESIUM AND SULPHUR
FERTILISERS:
• Calcium, Magnesium and Sulphur are applied to
the plants incidentally by the application of N, P
& K fertilizers.
• These fertilizers are not manufactured to supply
these nutrients.
Calcium, magnesium and sulphur contents
of different fertilizers materials:
FERTILISERS NUTRIENT CONTENT (%)
Ca Mg S Others
Calcium nitrate 19.4 - - -
Gypsum 29.2 - 18.6 -
Rock phosphate 33.1 - - 25.2 (P₂O₅)
Single superphosphate 19.5 - 12.5 16.0 (P₂O₅)
Triple superphosphate 14.0 - 1.0 43.5 (P₂O₅)
Epsom salt - 9.6 13.0 -
Potassium magnesium sulphate - 11.1 22.3 31 (K₂O)
Potassium sulphate - 17.5 48 (K₂O)
Calcium, magnesium and sulphur contents
of different fertilizers materials:
FERTILISERS NUTRIENT CONTENT (%)
Ca Mg S Others
Ammonium sulphate - - 24.2 21 (N)
Ammonium sulphate nitrate - - 12.1 26 (N)
Basic slag - - 3.0 15.6 (P₂O₅)
Copper sulphate - - 11.4 21 (Cu)
Ferrous ammonium sulphate - - 16.0 6 (N), 16 (Fe)
Ferrous sulphate - - 18.8 32.8 (Fe)
Elemental sulphur - - 100.0 -
Zinc sulphate - - 17.8 36.4 (Zn)
RANGE OF MICRONUTRIENTS
CONCENTRATIONS FOR NORMAL PLANT
GROWTH:
Trace element Concentration (ppm)
IRON 0.5- 5.0
MANGANESE 0.1-0.5
BORON 0.1-1.0
ZINC 0.02-0.2
COPPER 0.01-0.05
MOLYBDENUM 0.01-0.05
MICRONUTRIENTS
• Several micronutrients salts are highly reactive and soluble
make them unavailable to plants.
• Therefore micronutrients are applied into the soil in the form
of frits and metal chelates.
• FRITS: Micronutrients salts are fused with special type of
glass and shattered into small bits which are called frits.
• When the frits are applied to the soil, the glass slowly
dissolves and releases the nutrient salts.
• Frits extend period of nutrient availability by reducing the
reactivity and solubility.
• Examples: Borosilicate glass, manganese ammonium frits,
zinc frits and copper frits
MICRONUTRIENTS
• Metal chelates: Micronutrients are also available in
chelated form which have the ability to chelate or loosly
hold metallic ions in their cyclic structure and these
metal-organic complexes are called Metal chelates.
• Metal chelates are soluble in water but they do not ionize
in soil solution.
• Organic compounds like EDTA (Ethylene diamine tetra
acetic acid), DTPA (Diethylene triamine penta acetic
acid) have the ability to chelate metallic ions.
• Iron, Copper, zinc and manganese fertilisers are available
in chelated forms.
IRON
FERTILISERS
SOURCE IRON
CONTENT (%)
Ferrous sulphate 19
Ferric sulphate 23
Ferrous oxide 77
Ferric oxide 69
Ferrous ammonium
phosphate
29
Ferrous ammonium
sulphate
14
Iron ammonium
polyphosphate
22
Iron chelates 14
Iron frits 22
• Ferrous sulphate is the
most commonly used
fertiliser.
• When it is applied to soil,
it is oxidized to ferric
sulphate which is not
readily available to
plants.
• To overcome this
problem, iron chelates
are used both for soil and
foliar application.
MANGANESE FERTILISERS
SOURCE
MANGANESE
CONTENT (%)
Manganese sulphate 26
Manganous oxide 41
Manganese oxide 63
Manganese chelates 12
Manganese frits 10
ZINC
FERTILISERS
Source Zinc (%)
Zinc sulphate
monohydrate
35
Zinc sulphate hepta
hydrate
23
Basic Zinc sulphate 55
Zinc oxide 78
Zinc sulphide 67
Zinc phosphate 51
Zinc chelate 14
• Zinc sulphate is the
most commonly
used zinc fertiliser.
• It is applied both to
soil (@ 30-50
kg/ha) and plant
(0.5 % as spray).
BORON FERTILISERS
Source Boron
(%)
Borax 11
Sodium
pentaborate
18
Sodium tetraborate 14
Boric acid 17
Solubor 20
Borosilicate glass 6
• Borax is the most commonly used
boron fertiliser.
• Because of its high solubility in
water, it is lost by leaching to
avoid this loss, boron frits are
developed.
• Borosilicate glass can be apply in
sandy soil under high rainfall
conditions.
• Boric acid and solubor are used
for foliar application
COPPER FERTILISERS
Source Copper
(%)
Both for soil and foliar
application
Copper sulphate 21
Both for soil and foliar
application
Copper ammonium
phosphate
30
Foliar application Copper chelates
(Cu EDTA)
Varying
MOLYBDENUM FERTILISERS
• Molybdenum fertilisers are ammonium molybdate,
sodium molybdate and molybdate trioxide.
• Molybdenum fertilisers can be mixed with N P K
fertilisers and applied to the soil.
• It is also applied as foliar spray.
Fertilizer and its classification

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Fertilizer and its classification

  • 1. MISS KRISHNAMAYEE SETHI, ASSISTANT PROFESSOR OF AGRONOMY
  • 2. INTRODUCTION TO FERTILIZERS • In the same way that humans need to eat properly to stay healthy, so plants need certain nutrients to grow properly. • Fertilizer is a substance added to soil to improve plant’s growth and yield. Basically it is a chemical or natural substance is added to soil or land to increase its fertility. • Fertilizers are food supplements for plants and need 16 nutrients to be healthy.
  • 3. WHAT IS A FERTILIZER ? A fertilizer is any material of natural or synthetic origin that is applied to soils or to plant tissues to supply one or more plant nutrients essential to the growth of plants.
  • 4. COMPLETE VS. INCOMPLETE • Complete has all three primary nutrients-nitrogen phosphorous & potassium • Examples: 10-10-10, 15-30-15, 20-5-20 • Incomplete DOES NOT have all three primary nutrients • Examples: 20-0-0, 0-20-0, 12-0-44
  • 5. BASIC FORMS OF FERTILIZERS: • Granular- designed to be scratched into the soil and water soluble. • Powdered- designed to be dissolved in water for liquid feeding to soil and foliage. • Liquid- usually a concentrated form to be mixed with water.
  • 8. • Straight fertilizers are those which supply only one primary plant nutrient (N, P & K). • E.g. Urea, Ammonium sulphate, Potassium chloride and Potassium sulphate. • Complex fertilizers contain 2 or 3 primary plant nutrients of which two primary nutrients are in chemical combination. • Usually produced in granular form. • Diammonium phosphate, Nitrophosphates, Ammonium phosphate • Mixed fertilizers are physical mixtures of straight fertilisers. • They contain two or three primary plant nutrients. • made by thoroughly mixing the ingredients either mechanically or manually.
  • 9. BASED ON CONCENTRATION OF PRIMARY PLANT NUTRIENTS (N, P & K) IN FERTILISERS: LOW ANALYSIS FERTILISERS • Fertilisers contain less than 25% of primary nutrients. • Example-  SSP(16% P₂O₅)  Sodium nitrate (16% N) HIGH ANALYSIS FERTILISERS • Total content of primary nutrients is above 25%. • Example-  Urea (46% N)  Anhydrous ammonia (82.2% N) Ammonium phosphate (20% N +20% P₂O₅)
  • 10. CLASSIFICATION BASED ON PHYSICAL FORM: SOLID FERTILIZERS • Powder (single superphosphate) • Crystals (Ammonium sulphate) • Prills (Urea, Diammonium phosphate, superphosphate) • Granules (Holland granules) • Supergranules (Urea supergranules) • Briquettes (Urea briquettes) LIQUID FERTILIZERS • Liquid form fertilizers are applied with irrigation water or for direct application. • 2 types- • 1- clear liquid fertilisers (when the fertilisers are completely dissolved in water) • 2- Suspension liquid fertilisers (when fertilisers are suspended as fine particles in water)
  • 11. BASED ON THE NATURE OF FERTILISERS: Acid Forming Fertilisers • Fertilisers which leave an acid residue in the soil. • Apply acid forming fertilisers to alkaline soil. • The amount of calcium carbonate required to neutralize the acid residue is called its Acid equivalent. Alkaline Forming Fertilisers Or Basic Fertilisers • Fertilisers which leave an alkaline residue in the soil. • Apply acid forming fertilisers to alkaline soil.
  • 12. Fertiliser Acid equivalent Ammonium chloride 128 Ammonium sulphate 110 Ammonium sulphate nitrate 93 Ammonium phosphate 86 Urea 80
  • 13. Fertilisers Equivalent basicity Sodium nitrate 29 Calcium nitrate 21 Calcium cynaide 63 Dicalcium phosphate 25
  • 14. FERTILIZER GRADE: • Fertiliser grade refers to the minimum percentage of nitrogen(N), Phosphorus(P₂O₅) & Potash(K₂O) present in fertilizer material. • Fertilizer analysis expresses weight as a percent of nitrogen, phosphorus and potassium
  • 15. Fertilizer Analysis For Example A 100 kg bag of fertilizer has an grade of 15-5-18. • Nitrogen: 100 X 15%=15 Kg • Phosphorus: 100 X 5%=5 Kg • Potassium: 100 X 18%=18 Kg
  • 16. • The fertilizer materials containing nitrogen are called nitrogenous fertilisers. • They may contain secondary nutrients like Calcium and Sulphur.
  • 17. NITRATE FERTILIZERS 1. They are highly mobile in soil therefore suitable for top dressing. 2. Highly soluble subjected and to leaching. 3. Subjected to denitrification in waterlogged soils. 4. Increase alkalinity as they are basic in their residual effect. • Sodium nitrate (NaNO₃) • Calcium nitrate (Ca(NO₃)₂)
  • 18. AMMONIACAL FERTILISERS • Easily available to the plants as they are readily soluble in water. • Leaching losses are less as ammonium ions are adsorbed on clay complex. • Reduce alkalinity as they are acidic in their residual effect on the soils. • Well suited to submerged soils. • Ammonium sulphate ((NH₄)₂SO₄) • Ammonium chloride (NH₄Cl) • Anhydrous ammonia (NH₃)
  • 19. NITRATE & AMMONIACAL FERTILISERS • Easily available to the plants as they are readily soluble in water. • Leaching losses are less. • Reduce alkalinity as they are acidic in their residual effect on the soils. • Ammonium nitrate (NH₄NO₃) • CaNH₄NO₃ - Calcium ammonium nitrate (CAN)
  • 20. AMIDE FERTILISERS OR ORGANIC FERTILIZERS • Urea (CO(NH)₂) • Calcium cyanide (CaCN₂)
  • 21. Fertilizers Forms of nutrient N% Others Nature KNO₃ Nitrate 13.85 K₂O-46-47 Basic Ca(NO₃)₂ Nitrate 15.5 Ca-19.4 Basic NaNO₃ Nitrate 16 Basic (NH₄)₂SO₄ Ammoniacal 20.6-21 S-24.5 Acidic NH₄Cl Ammoniacal 25.5-26 Cl-66 Acidic (NH₄)₂SO₄ . NH₄NO₃ Ammoniacal 26 S-15 Acidic CAN Ammoniacal and Nitrate 25-28 Neutral NH₄NO₃ (Highly hygroscopic) 50%- Ammonium 50%- Nitrate 33-35 Acidic Anhydrous ammonia Ammoniacal 80-82 Highly Acidic Urea [CO(NH₂)₂] Amide 46 Acidic CaCN₂ Amide 20.6-21 Basic
  • 22. Phosphorus content in fertilizers is expressed in oxidized form (P₂O₅). In soil and plant phosphorus is expressed in elemental form. The conversion factors: P→ P₂O₅ = 2.29 P₂O₅ →P = 0.43
  • 23. CLASSIFICATION OF PHOSPHATIC FERTILIZERS: N P₂O₅ Others SSP - 16-20 Ca-19.5, S-12.5 DSP - 32 - TSP - 46-48 - MAP 11-12 48 - DAP 18 46 - • Mostly suitable for neutral and alkaline soil. • They form insoluble iron and aluminium phosphates in acid soils. • Mostly used in short duration crops like Wheat, Sorghum and Pulses. A: WATER SOLUBLE PHOSPHORIC ACID
  • 24. CLASSIFICATION OF PHOSPHATIC FERTILIZERS: P₂O₅ % DCP (Dicalcium phosphate) 34-39 Basic slag 14-18 • They are basic in reaction so suitable for acid soil. • Mostly suitable for long duration crops like Sugar cane, Tapioca, Tea, Coffee, Low land rice. B: CITRIC ACID SOLUBLE PHOSPHORIC ACID
  • 25. CLASSIFICATION OF PHOSPHATIC FERTILIZERS: P₂O₅ % Rock phosphate 20-40 Raw bone meal 2-2.5 Steamed bone meal 22 • Mostly suitable for strongly acidic and organic soil. • Suitable for plantation crops like tea, coffee, rubber, cocoa and coconut. C: CITRIC ACID & WATER INSOLUBLE PHOSPHORIC ACID
  • 26. Potash content in fertilizers is expressed in oxidized form (K₂O). In soil and plant phosphorus is expressed in elemental form. The conversion factors: K→ K₂O = 1.2 K₂O →K = 0.83
  • 27. CLASSIFICATION OF POTASSIC FERTILIZERS: K₂O (%) MOP (Muriate of Potash) or POTASSIUM CHLORIDE (KCl) 58-60 • Fertiliser is suitable for acidic and heavy soils but not suitable for alkaline soil. • Presence of chloride in the fertlisers make it unsuitable for sugar crops, tobacco and potato. A: CHLORIDE FORM
  • 28. CLASSIFICATION OF POTASSIC FERTILIZERS: K₂O (%) POTASSIUM SULPHATE 48-50 S-17.5 POTASSIUM MAGNESIUM SULPHATE 22 Mg-11 S-22 POTASSIUM NITRATE or SALT PETRE or NITRE 44 N-13 • KNO₃ is an excellent source of potassium and nitrogen. • It is mainly used for fruit trees and crops such as tobacco and vegetables. B: NON-CHLORIDE FORM
  • 29. CALCIUM, MAGNESIUM AND SULPHUR FERTILISERS: • Calcium, Magnesium and Sulphur are applied to the plants incidentally by the application of N, P & K fertilizers. • These fertilizers are not manufactured to supply these nutrients.
  • 30. Calcium, magnesium and sulphur contents of different fertilizers materials: FERTILISERS NUTRIENT CONTENT (%) Ca Mg S Others Calcium nitrate 19.4 - - - Gypsum 29.2 - 18.6 - Rock phosphate 33.1 - - 25.2 (P₂O₅) Single superphosphate 19.5 - 12.5 16.0 (P₂O₅) Triple superphosphate 14.0 - 1.0 43.5 (P₂O₅) Epsom salt - 9.6 13.0 - Potassium magnesium sulphate - 11.1 22.3 31 (K₂O) Potassium sulphate - 17.5 48 (K₂O)
  • 31. Calcium, magnesium and sulphur contents of different fertilizers materials: FERTILISERS NUTRIENT CONTENT (%) Ca Mg S Others Ammonium sulphate - - 24.2 21 (N) Ammonium sulphate nitrate - - 12.1 26 (N) Basic slag - - 3.0 15.6 (P₂O₅) Copper sulphate - - 11.4 21 (Cu) Ferrous ammonium sulphate - - 16.0 6 (N), 16 (Fe) Ferrous sulphate - - 18.8 32.8 (Fe) Elemental sulphur - - 100.0 - Zinc sulphate - - 17.8 36.4 (Zn)
  • 32. RANGE OF MICRONUTRIENTS CONCENTRATIONS FOR NORMAL PLANT GROWTH: Trace element Concentration (ppm) IRON 0.5- 5.0 MANGANESE 0.1-0.5 BORON 0.1-1.0 ZINC 0.02-0.2 COPPER 0.01-0.05 MOLYBDENUM 0.01-0.05
  • 33. MICRONUTRIENTS • Several micronutrients salts are highly reactive and soluble make them unavailable to plants. • Therefore micronutrients are applied into the soil in the form of frits and metal chelates. • FRITS: Micronutrients salts are fused with special type of glass and shattered into small bits which are called frits. • When the frits are applied to the soil, the glass slowly dissolves and releases the nutrient salts. • Frits extend period of nutrient availability by reducing the reactivity and solubility. • Examples: Borosilicate glass, manganese ammonium frits, zinc frits and copper frits
  • 34. MICRONUTRIENTS • Metal chelates: Micronutrients are also available in chelated form which have the ability to chelate or loosly hold metallic ions in their cyclic structure and these metal-organic complexes are called Metal chelates. • Metal chelates are soluble in water but they do not ionize in soil solution. • Organic compounds like EDTA (Ethylene diamine tetra acetic acid), DTPA (Diethylene triamine penta acetic acid) have the ability to chelate metallic ions. • Iron, Copper, zinc and manganese fertilisers are available in chelated forms.
  • 35. IRON FERTILISERS SOURCE IRON CONTENT (%) Ferrous sulphate 19 Ferric sulphate 23 Ferrous oxide 77 Ferric oxide 69 Ferrous ammonium phosphate 29 Ferrous ammonium sulphate 14 Iron ammonium polyphosphate 22 Iron chelates 14 Iron frits 22 • Ferrous sulphate is the most commonly used fertiliser. • When it is applied to soil, it is oxidized to ferric sulphate which is not readily available to plants. • To overcome this problem, iron chelates are used both for soil and foliar application.
  • 36. MANGANESE FERTILISERS SOURCE MANGANESE CONTENT (%) Manganese sulphate 26 Manganous oxide 41 Manganese oxide 63 Manganese chelates 12 Manganese frits 10
  • 37. ZINC FERTILISERS Source Zinc (%) Zinc sulphate monohydrate 35 Zinc sulphate hepta hydrate 23 Basic Zinc sulphate 55 Zinc oxide 78 Zinc sulphide 67 Zinc phosphate 51 Zinc chelate 14 • Zinc sulphate is the most commonly used zinc fertiliser. • It is applied both to soil (@ 30-50 kg/ha) and plant (0.5 % as spray).
  • 38. BORON FERTILISERS Source Boron (%) Borax 11 Sodium pentaborate 18 Sodium tetraborate 14 Boric acid 17 Solubor 20 Borosilicate glass 6 • Borax is the most commonly used boron fertiliser. • Because of its high solubility in water, it is lost by leaching to avoid this loss, boron frits are developed. • Borosilicate glass can be apply in sandy soil under high rainfall conditions. • Boric acid and solubor are used for foliar application
  • 39. COPPER FERTILISERS Source Copper (%) Both for soil and foliar application Copper sulphate 21 Both for soil and foliar application Copper ammonium phosphate 30 Foliar application Copper chelates (Cu EDTA) Varying
  • 40. MOLYBDENUM FERTILISERS • Molybdenum fertilisers are ammonium molybdate, sodium molybdate and molybdate trioxide. • Molybdenum fertilisers can be mixed with N P K fertilisers and applied to the soil. • It is also applied as foliar spray.