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BIO 522
PRESENTED BY
PRINCELY, ORIOMOJOR
20143204
17th December, 2015
 Introduction
 Overview of MoS2
 Structure of MoS2
 Properties
 Nanotechnology Application of MoS2
 Advantages
 Other Nanotechnology applications of MoS2
 Conclusion
In the society today, producing fresh water is a great challenge. (Elimelech
and Phillip, 2011; Zhao et al., 2012; Shannon et al., 2008; Fritzmann et al.,
2007). Over the years reverse osmosis and electrodialysis has been use for
desalination of seawater. But these separation systems have the problem of
forming polarization films and by product that may generate bacteria and
fouling.(A. M'nif et al., 2007).
Because of this problems caused by this separation systems, alternatives
separation membrane technology such as single layer Molybdenum
disulphide nanopore has been experimented on for desalination of seawater.
1
Molybdenum disulphide is an inorganic compound with the formula
MoS2. It is a 100% "natural" material, it is taken out of the ground. They
also have a large active surface area and high reactivity (AZoNano,
c.2013)
MoS2 exhibits a lamellar or layer-like structure, with inter-lamellar
bonding between two adjacent layers of sulfur atoms. Van der Waals
forces between the layers is quite weak, meaning that the layers are easily
pulled apart.
2
3
http://www.rsc.org/chemistryworld/2014/01/2d-materials-graphene
MoS2
PHYSICAL PROPERTIES:
Density: 5.06 g/cm3
Molar mass: 160.07 g/mol
Melting point: 1,185˚c
Solubility in water: Insoluble
Solubility: Decomposes by aqua regia, hot sulphuric acid, nitric acid
insoluble in dilute acids (AZoNano, c.2013)
4
CHEMICAL DATA:
Chemical symbol: MoS2
Group: Molybdenum 6, Sulphur 16
Electronic Configuration: Molybdenum [Kr] 4d5 5s1, Sulfur [Ne] 3s2
3p4
CHEMICAL COMPOSITION:
Molybdenum 59.94 content %
Sulphur 40.05 content %(AZoNano, c.2013)
5
Advances in nanotechnology have led to the development of a
nanoporous membrane material for salt water purification. Due to this
advances, a single layer MoS2 nanopore membrane was seen as effective
and more energy efficient for seawater desalination. Latest trend by
engineers in university of Illinois USA.
6
Source: Heiranian, M. et al. Water desalination with a single-layer MoS2 nanopore
7
8
9
 The molybdenum in the center attracts water, then the
sulphur on the other side pushes the water away.
 The single layer sheet of MoS2 is ultra thin.
 It requires less energy
 It reduce operating cost
10
 Single-Layer Molybdenum Disulphide Nanopore is used for DNA
Detection(AB Farimani et al., 2015)
 MoS2 is also use in the field of energy storage in lithium ion
batteries.(T Stephenson et al., 2014)
 Single layer MoS2 is used as transistor/semiconductor in electronics.(B
Radisavljevic et al., 2011)
11
In this presentation we have shown that MoS2 nanopore is a promising
technology for rejection of salt and water purification. Therefore MoS2 is
potentially an efficient membrane for seawater desalination.
12
A single layer MoS2 nanopore is thick, and its made up of two
atoms molybdenum and sulphur. These two atoms together
exposed to DNA bases create opportunity for DNA
sequencing.
MoS2 is about 1nm thick, the thickness makes the material to
be higher to graphene in terms of signal/noise intensity for
DNA detection.
13
14
15
The unique properties of molybdenum disulphide engender a
versatility that has enabled its use in a wide range of scientific
fields. The application of MoS2 to the Field of energy storage
in lithium ion batteries is a promising technology, it
compensate for it intermediate insertion voltage with a high
reversible capacity and an excellent rate capability.
16
Molecular models of (a) 2H–MoS2. (b) Lithiated 2H–MoS2 showing a 5% lattice expansion in
the c-direction and a-direction due to intercalation. (c) Lithiated 1T–MoS2 showing lithium
ions occupying octahedral interstices. (d) 3R–MoS2 (e) Li2S
17
XRD scans of MoS2 electrode at various states of charge. (a) (Bottom) as received, and (top)
after discharge to 0.01 V. Peaks marked by *are from the copper current collector.172 (b) After
discharge to 0.01 V (c) After recharge to 3.0 V
18
A. M'nif, S. Bouguecha, B. Hamrouni, and M. Dhahbi, “Coupling of membrane
processes for brackish water desalination,” Desalination, vol. 203, no. 1–3, pp.
331–336, 2007. View at Publisher · View at Google Scholar · View at Scopus
Elimelech, M. & Phillip, W. A. The future of seawater desalination: energy,
Fritzmann, C., Lowenberg, J., Wintgens, T. & Melin, T. State-of-the-art of reverse
osmosis desalination. Desalination 216, 1–76 (2007).
http://www.azonano.com/article.aspx?ArticleID=3351
19
http://www.rsc.org/chemistryworld/2014/01/2d-materials-graphene
Radisavljevic, B., Radenovic, A., Brivio, J., Giacometti, V. & Kis, A. Single-layer
MoS2 transistors. Nature Nanotech. 6, 147–150 (2011).
Shannon, M. A. et al. Science and technology for water purification in the coming
decades. Nature 452, 301–310 (2008).
Technology, and the environment. Science 333, 712–717 (2011).
Zhao, S. F., Zou, L., Tang, C. Y. Y. & Mulcahy, D. Recent developments in
forward osmosis: opportunities and challenges. J. Membr. Sci. 396, 1–21 (2012).
20
21

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seawater desalination using MoS2 nanopore POWER POINT

  • 1. BIO 522 PRESENTED BY PRINCELY, ORIOMOJOR 20143204 17th December, 2015
  • 2.  Introduction  Overview of MoS2  Structure of MoS2  Properties  Nanotechnology Application of MoS2  Advantages  Other Nanotechnology applications of MoS2  Conclusion
  • 3. In the society today, producing fresh water is a great challenge. (Elimelech and Phillip, 2011; Zhao et al., 2012; Shannon et al., 2008; Fritzmann et al., 2007). Over the years reverse osmosis and electrodialysis has been use for desalination of seawater. But these separation systems have the problem of forming polarization films and by product that may generate bacteria and fouling.(A. M'nif et al., 2007). Because of this problems caused by this separation systems, alternatives separation membrane technology such as single layer Molybdenum disulphide nanopore has been experimented on for desalination of seawater. 1
  • 4. Molybdenum disulphide is an inorganic compound with the formula MoS2. It is a 100% "natural" material, it is taken out of the ground. They also have a large active surface area and high reactivity (AZoNano, c.2013) MoS2 exhibits a lamellar or layer-like structure, with inter-lamellar bonding between two adjacent layers of sulfur atoms. Van der Waals forces between the layers is quite weak, meaning that the layers are easily pulled apart. 2
  • 6. PHYSICAL PROPERTIES: Density: 5.06 g/cm3 Molar mass: 160.07 g/mol Melting point: 1,185˚c Solubility in water: Insoluble Solubility: Decomposes by aqua regia, hot sulphuric acid, nitric acid insoluble in dilute acids (AZoNano, c.2013) 4
  • 7. CHEMICAL DATA: Chemical symbol: MoS2 Group: Molybdenum 6, Sulphur 16 Electronic Configuration: Molybdenum [Kr] 4d5 5s1, Sulfur [Ne] 3s2 3p4 CHEMICAL COMPOSITION: Molybdenum 59.94 content % Sulphur 40.05 content %(AZoNano, c.2013) 5
  • 8. Advances in nanotechnology have led to the development of a nanoporous membrane material for salt water purification. Due to this advances, a single layer MoS2 nanopore membrane was seen as effective and more energy efficient for seawater desalination. Latest trend by engineers in university of Illinois USA. 6
  • 9. Source: Heiranian, M. et al. Water desalination with a single-layer MoS2 nanopore 7
  • 10. 8
  • 11. 9
  • 12.  The molybdenum in the center attracts water, then the sulphur on the other side pushes the water away.  The single layer sheet of MoS2 is ultra thin.  It requires less energy  It reduce operating cost 10
  • 13.  Single-Layer Molybdenum Disulphide Nanopore is used for DNA Detection(AB Farimani et al., 2015)  MoS2 is also use in the field of energy storage in lithium ion batteries.(T Stephenson et al., 2014)  Single layer MoS2 is used as transistor/semiconductor in electronics.(B Radisavljevic et al., 2011) 11
  • 14. In this presentation we have shown that MoS2 nanopore is a promising technology for rejection of salt and water purification. Therefore MoS2 is potentially an efficient membrane for seawater desalination. 12
  • 15. A single layer MoS2 nanopore is thick, and its made up of two atoms molybdenum and sulphur. These two atoms together exposed to DNA bases create opportunity for DNA sequencing. MoS2 is about 1nm thick, the thickness makes the material to be higher to graphene in terms of signal/noise intensity for DNA detection. 13
  • 16. 14
  • 17. 15
  • 18. The unique properties of molybdenum disulphide engender a versatility that has enabled its use in a wide range of scientific fields. The application of MoS2 to the Field of energy storage in lithium ion batteries is a promising technology, it compensate for it intermediate insertion voltage with a high reversible capacity and an excellent rate capability. 16
  • 19. Molecular models of (a) 2H–MoS2. (b) Lithiated 2H–MoS2 showing a 5% lattice expansion in the c-direction and a-direction due to intercalation. (c) Lithiated 1T–MoS2 showing lithium ions occupying octahedral interstices. (d) 3R–MoS2 (e) Li2S 17
  • 20. XRD scans of MoS2 electrode at various states of charge. (a) (Bottom) as received, and (top) after discharge to 0.01 V. Peaks marked by *are from the copper current collector.172 (b) After discharge to 0.01 V (c) After recharge to 3.0 V 18
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