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Dr. SURENDRAN PARAMBADATH
           (M.Sc, M.Phil, M.Tech)



  Formerly: Post Doctoral Research Associate,
Nano-Information Materials Research Laboratory,
 Pusan National University, Busan-South Korea

         Currently: Assistant Professor
   Govt. Polytechnic College, Perinthalmanna
Air Pollution

                           Water Pollution

                            Soil Pollution
Environmental Pollution
                           Voice or Sound
                              Pollution

                          Thermal Pollution

                            Radioactive
                             Pollution
Pollution:  It   is   defined  as   the
consequence of excessive discharge or
addition of unwanted constituents to
the air, water or land, which adversely
change the quality of environment.



Pollutant: The substances which will
cause pollution is called pollutant.
Categorization of Pollution
The subject of pollution is broadly
classified in to,
1.Air Pollution
2.Water Pollution
3.Land or soil Pollution
4.Noise pollution
5.Thermal Pollution
6.Radioactive pollution
Air Pollution
It is the excessive discharge of undesired foreign
substances into the atmospheric air.
1) Primary Pollutants: Theses are harmful chemical substances
   that directly enter the air as a result of natural events and human
   activities.
Carbon Monoxide, Carbon dioxide, Nitrogen oxide, Sulphur
oxide, Hydrogen sulphide, Ammonia

1) Secondary Pollutants: Theses are harmful chemicals formed
   in the air due to a chemical reaction between two or more
   components or primary pollutants and one or more air
   components.

SO2, NO2, O3, Aldehydes, Ketones etc…
Sources of air Pollutants

1) Chemical    industries and
  thermal power stations
2) Automobiles
3) Domestic and other sources.
Control of air pollution
A. Reduction of contaminates from the source
 1 Use appropriate materials or suitably change the raw materials
 2 Select proper site for industrial units, far away from residential
     area,
 3 Prevent or lessen, as far as possible, the smoke emitted during
     combustion of fuel by, correct method, admitting correct
     quantities of air, maintaining high temperature for complete
     combustion and feeding the fuel continuously.
 4 Use catalytic converters to eliminate pollutants from exhaust
     gases before discharging in to the atmosphere.
 5 Pass gases or vapors through towers packed with coke to
     remove chemicals and acid fumes, while applying a counter
     current of water from the top.
 6   Grow more trees to increase photosynthesis rate and for better
     deposition of particulates.
B. Reduction of contaminants by modification
1 Modifications of internal combustion engines to
  reduce the amount of pollutants, with better design,
  suitable catalysts in the fuel, mixing and burning
  exhaust gases with more air and improving the
  quality of gasoline.

2 Developing substitute fuel to lower concentration of
  pollutants
3 Using alternative power sources, such as electricity,
  nuclear power geothermal power and solar power for
  domestic and industrial purposes.
The heating of the earth due to trapped radiations
is called Green House Effect or Global Warming.
Green house gases: CO2, CFC, Water vapor, Methane, Ozone,
Nitrogen Oxide etc.



                     Heat re-emitted by earth
                     and absorbed by gases      Heat radiated
                                                back to earth
1 Summer will be longer and hotter. Winter will be shorter
    and warmer.
2   Total amount of global rainfall will increase but some region
    will receive less rainfall.
3   The number of days having intense shower and high
    temperature both will increase.
4   The problem of desertification, drought and soil erosion will
    become more worse.
5   Ocean will get warm up, sea level would rise flooding low
    lying regions.
6   Increase in green house effect will cause cooling of the
    stratosphere.
7   Tropical storms, hurricanes will be stronger and more frequent
    and cause devastation
8   Tropics may become wetter, and dry subtropics drier.
Smoke + Fog = Smog

There are two types of smog:
1) Chemical Smog: It is formed by condensation of smoke dust
   particles and fog containing SO2 from polluted air.

2) Photochemical smog: It is formed by the combustion of smoke
    dust particles and fog containing the secondary air pollutants
    resulting from a series of photochemical reactions between
    NO, O2, H2O with hydrocarbons from exhaust, under the
    influence of sunlight.
Harmful effect of photochemical Smog
It causes irritation to eyes, nose and throat, leading
to several chronic diseases of eyes.
The O3 and PAN composites are toxic and affect
the respiratory tract and result in coughing,
sneezing and bronchial constrictions.
It affects human comfort and health.
It damages vegetation, affect plant growth, and
reduce crop production. PAN attacks younger
leaves and causes bronzing and glazing of their
surfaces.
Ozone attacks rubber, cracks it and makes it aged.
Acid Rain

Acid rain means the presence of excessive acid
in rain water.

Acid rain is a mixture of the acids HNO3 and
H2SO4 dissolved in water.

The oxides (SO2 and NO2 are highly water soluble
and under humid conditions of air react with
water vapour to form H2SO4 and HNO3. These
acids combine with HCl generates acid
precipitation which is commonly known as acid
rain.
Harmful effect of Acid Rain

 1. Causes irritation to the eyes and mucus
    membrane dangerous ti living organisms as it
    can destroy life.
 2. Causes damage of fresh water life.
 3. In mist form, it causes direct damage to plant
    leaves, leaf bleaching. Collapse of leaves and
    narcosis.
 4. Animals consuming vegetation affected by
    acid rains, lose their hunger.
 5. Presence of acid accelerates the rate of
    corrosion of metals, causes damage to
    buildings, statues, lime stone, marbles etc.
Ozone Layer
       Depletion of ozone and consequences
Ozone is formed by the decomposition of atmospheric oxygen
by UV radiation from the sun.

 1. This may be due to natural process. The N2O in the
    stratosphere can remove excited oxygen atoms required
    for formation of O3.

 2. Freons, ie Chlorofluoro compounds CFCl3, CFCl2 and
    CFCl etc. have certain special properties and are used as
    industrial solvents, refrigerants, fast food packing
    materials, plastic foams etc. At stratosphere theses
    undergo photolysis into chlorine atoms which act upon
    ozone and destroy it.
Consequences of Ozone depletion


1. Most important consequence is the serious threat
   to mankind resulting in skin cancer, due to
   exposure to sun’s UV rays which freely reach the
   earth.
2. UV rays may damage immune system which may
   lead to increased viral infection.
3. UV radiations will damage marine plants, marine
   animals and fish which form an important part of
   human food.
4. These may damage the land’s plants and crops.
5. Excess unused freons trap the warmth of the
   sun, disturb green house effect, leading to high
   temperature, which could further damage crops
   and by increased melting of ice, pose dangers to
REMEDY

1.Control the production and use of
 freons which are proved to be
 harmful to ozone.

2.Replace freons by compounds
 having      their   advantageous
 properties, but with a lesser
 destructive effect.
Water pollution may be defined as any
change in the physical, chemical and
biological properties of water as well as
contamination      with    any    foreign
substance.
Sources of Water Pollution
1. Faulty sewage system:
2. Agriculture wastes:
3. Oil Pollution:
4. Industrial effluents:
Effect of Impurities in Water
1. Presence of disease causing bacteria result in several
   water borne diseases. Typhoid fever, cholera, viral
   fever, bacterial fever etc.
2. Industrial waste lead to damage of property through
   corrosive attack.
3. Pollution of natural water due to organic waste, under the
   influenec of bacterial action, reduce the dissolved oxygen
   content in water.
4.     Presence      of     agricultural  waste    such    as
   pesticides, weedicides, herbicides as well detergents and
   disinfectants and other toxic substances kill animals and
   micro organisms.
5. Polluted water affects soil fertility by killing soil
   microorganisms.
6. Presence of heavy metals, like Hg, Cr, Pb, Cu, Zn etc. are
   toxic to animals and plants and micro organisms.
7. Suspended solid, coloring matter, floated oils and greases
   make water unsuitable for use.
Control of Water Pollution

1.Control over unhygienic practices.
Educate peoples, Dispose waste water
properly, control usage of insecticides.
2. Industrial Waste
Dispose waste safely.
3. Heavy metal removal
Dialysis, ion exchange, reverse osmosis,
chemical precipitation, adsorption.
4. Sewage treatment
Purify properly.
Sewage Water Treatment
It aims the transfer of harmful compounds in the
sewage to harmless compounds, before its
ultimate disposal either on land or dilution in
water.

Three stages of this process are,
1. Primary or mechanical treatment
2. Secondary or biological treatment
3. Tertiary or advanced biological, physical and
   chemical treatment.
Soil or Land
 Pollution
It is the addition of certain
chemical substances in an
indefinite proportion to the soil
system as a result of which
the fertility of the soil change.
Impact of soil pollution

 1. Improper disposal of human and animal excreta.
 2. Domestic and industrial waste dumped on land.
 3. Chemicals like fertilizers, pesticides applied to plants
    and soil.
 4. Dumping of waste from mineral and coal mining and
    metal smelting on land.
 5. Soil     erosion    due     to     deforestation,   over
    grazing, unplanned irrigation and defective agriculture
    practice.
 6. Removal of upper fertile layer of soil.
 7. Pollution from air and fall-out from smoke stacks of
    chemical works.
 8. Radioactive waste discharged from hospitals, industrial
    and research centers.
Control of Soil Pollution

1.Unwanted waste to be dumped using
  sanitary land filling
2.Industrial and sewage waste to be
  properly treated before disposal on land.
3.Natural soil micro-organisms to be used
  to increase crop fertility rather than
  using fertilizers and insecticides.
4.Forestation.
5.People should be trained regarding the
  sanitation habit.
6.Avoid negligent disposal of solid waste.
7.Ban toxic chemicals and pesticides.
Noise Pollution
It is a kind of pollution caused by unwanted noise
at a wrong time and a wrong place naturally or
artificially, which will be uncomfortable for
health.
Impact of Noise Pollution

1. It affects human health, comfort and
   efficiency, contract blood vessels and increase
   blood pressure.
2. Cause muscles to contract, leading to nervous
   break down, tension and even insanity.
3. The most immediate and acute effect is impact of
   hearing or even loss of hearing.
4. It affect efficiency and behavior, can cause damage
   to heart, brain etc.
5. It may be a reason for diseases like eosnophelia
   etc.
Prevention of Noise pollution

1. Industrial Noise: Industries should be
situated far away from cities or towns.
Cover noise producing machineries with
insulators.       Properly       maintain
machineries
2. Community noise control: Use cotton
plugs or ear muffles.
Thermal Pollution
Thermal pollution may be
defined as addition of
undesirable heat to water,
that makes it harmful to
man, animal or aquatic
life.
Radioactive Pollution
Hazards of Nuclear Radiators

1. Pathological damage:        Living organisms are
   damaged by the highly penetrating radioactive
   radiations.
2. Genetic Effects: Transmitted to future generations
   producing abnormalities in the offsprings which
   may be mild or deadly.
3. Nuclear radiations: It may reduce the effectiveness
   of enzymes and cause accumulation of certain
   dangerous elements in certain specific organs or
   tissue.
The chemistry aims the use of environmentally
friendly materials for chemical or biological
transformation.
Green Chemistry is in Action

1.Using CO2 and a detergent for dry
  cleaning instead of carcinogenic
  tetrachloroethane
2.Using H2O2 for bleaching of cloths in
  laundry instead of toxic chlorine.
3.Using H2O2 for bleaching paper in the
  place of toxic chlorine.
Keep Our Nature Beautifully…..
Love our hereditary…………
Observe Our Nature More and More
        It is Very Beautiful
Get the Speech Between
Sky and Land……
Find the Wild Beauty From Your
Vicinity……..
Get The Magic & Wonder Creation
of Nature
Find Beauty By Becoming Simple
Enjoy the painting of god
Environmental chemistry-Dr. Surendran Parambadath

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Environmental chemistry-Dr. Surendran Parambadath

  • 1.
  • 2. Dr. SURENDRAN PARAMBADATH (M.Sc, M.Phil, M.Tech) Formerly: Post Doctoral Research Associate, Nano-Information Materials Research Laboratory, Pusan National University, Busan-South Korea Currently: Assistant Professor Govt. Polytechnic College, Perinthalmanna
  • 3.
  • 4. Air Pollution Water Pollution Soil Pollution Environmental Pollution Voice or Sound Pollution Thermal Pollution Radioactive Pollution
  • 5. Pollution: It is defined as the consequence of excessive discharge or addition of unwanted constituents to the air, water or land, which adversely change the quality of environment. Pollutant: The substances which will cause pollution is called pollutant.
  • 6. Categorization of Pollution The subject of pollution is broadly classified in to, 1.Air Pollution 2.Water Pollution 3.Land or soil Pollution 4.Noise pollution 5.Thermal Pollution 6.Radioactive pollution
  • 7.
  • 8. Air Pollution It is the excessive discharge of undesired foreign substances into the atmospheric air. 1) Primary Pollutants: Theses are harmful chemical substances that directly enter the air as a result of natural events and human activities. Carbon Monoxide, Carbon dioxide, Nitrogen oxide, Sulphur oxide, Hydrogen sulphide, Ammonia 1) Secondary Pollutants: Theses are harmful chemicals formed in the air due to a chemical reaction between two or more components or primary pollutants and one or more air components. SO2, NO2, O3, Aldehydes, Ketones etc…
  • 9. Sources of air Pollutants 1) Chemical industries and thermal power stations 2) Automobiles 3) Domestic and other sources.
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  • 12. Control of air pollution A. Reduction of contaminates from the source 1 Use appropriate materials or suitably change the raw materials 2 Select proper site for industrial units, far away from residential area, 3 Prevent or lessen, as far as possible, the smoke emitted during combustion of fuel by, correct method, admitting correct quantities of air, maintaining high temperature for complete combustion and feeding the fuel continuously. 4 Use catalytic converters to eliminate pollutants from exhaust gases before discharging in to the atmosphere. 5 Pass gases or vapors through towers packed with coke to remove chemicals and acid fumes, while applying a counter current of water from the top. 6 Grow more trees to increase photosynthesis rate and for better deposition of particulates.
  • 13. B. Reduction of contaminants by modification 1 Modifications of internal combustion engines to reduce the amount of pollutants, with better design, suitable catalysts in the fuel, mixing and burning exhaust gases with more air and improving the quality of gasoline. 2 Developing substitute fuel to lower concentration of pollutants 3 Using alternative power sources, such as electricity, nuclear power geothermal power and solar power for domestic and industrial purposes.
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  • 15. The heating of the earth due to trapped radiations is called Green House Effect or Global Warming. Green house gases: CO2, CFC, Water vapor, Methane, Ozone, Nitrogen Oxide etc. Heat re-emitted by earth and absorbed by gases Heat radiated back to earth
  • 16.
  • 17. 1 Summer will be longer and hotter. Winter will be shorter and warmer. 2 Total amount of global rainfall will increase but some region will receive less rainfall. 3 The number of days having intense shower and high temperature both will increase. 4 The problem of desertification, drought and soil erosion will become more worse. 5 Ocean will get warm up, sea level would rise flooding low lying regions. 6 Increase in green house effect will cause cooling of the stratosphere. 7 Tropical storms, hurricanes will be stronger and more frequent and cause devastation 8 Tropics may become wetter, and dry subtropics drier.
  • 18. Smoke + Fog = Smog There are two types of smog: 1) Chemical Smog: It is formed by condensation of smoke dust particles and fog containing SO2 from polluted air. 2) Photochemical smog: It is formed by the combustion of smoke dust particles and fog containing the secondary air pollutants resulting from a series of photochemical reactions between NO, O2, H2O with hydrocarbons from exhaust, under the influence of sunlight.
  • 19.
  • 20. Harmful effect of photochemical Smog It causes irritation to eyes, nose and throat, leading to several chronic diseases of eyes. The O3 and PAN composites are toxic and affect the respiratory tract and result in coughing, sneezing and bronchial constrictions. It affects human comfort and health. It damages vegetation, affect plant growth, and reduce crop production. PAN attacks younger leaves and causes bronzing and glazing of their surfaces. Ozone attacks rubber, cracks it and makes it aged.
  • 21. Acid Rain Acid rain means the presence of excessive acid in rain water. Acid rain is a mixture of the acids HNO3 and H2SO4 dissolved in water. The oxides (SO2 and NO2 are highly water soluble and under humid conditions of air react with water vapour to form H2SO4 and HNO3. These acids combine with HCl generates acid precipitation which is commonly known as acid rain.
  • 22. Harmful effect of Acid Rain 1. Causes irritation to the eyes and mucus membrane dangerous ti living organisms as it can destroy life. 2. Causes damage of fresh water life. 3. In mist form, it causes direct damage to plant leaves, leaf bleaching. Collapse of leaves and narcosis. 4. Animals consuming vegetation affected by acid rains, lose their hunger. 5. Presence of acid accelerates the rate of corrosion of metals, causes damage to buildings, statues, lime stone, marbles etc.
  • 23. Ozone Layer Depletion of ozone and consequences Ozone is formed by the decomposition of atmospheric oxygen by UV radiation from the sun. 1. This may be due to natural process. The N2O in the stratosphere can remove excited oxygen atoms required for formation of O3. 2. Freons, ie Chlorofluoro compounds CFCl3, CFCl2 and CFCl etc. have certain special properties and are used as industrial solvents, refrigerants, fast food packing materials, plastic foams etc. At stratosphere theses undergo photolysis into chlorine atoms which act upon ozone and destroy it.
  • 24. Consequences of Ozone depletion 1. Most important consequence is the serious threat to mankind resulting in skin cancer, due to exposure to sun’s UV rays which freely reach the earth. 2. UV rays may damage immune system which may lead to increased viral infection. 3. UV radiations will damage marine plants, marine animals and fish which form an important part of human food. 4. These may damage the land’s plants and crops. 5. Excess unused freons trap the warmth of the sun, disturb green house effect, leading to high temperature, which could further damage crops and by increased melting of ice, pose dangers to
  • 25. REMEDY 1.Control the production and use of freons which are proved to be harmful to ozone. 2.Replace freons by compounds having their advantageous properties, but with a lesser destructive effect.
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  • 28. Water pollution may be defined as any change in the physical, chemical and biological properties of water as well as contamination with any foreign substance.
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  • 30. Sources of Water Pollution 1. Faulty sewage system:
  • 34. Effect of Impurities in Water 1. Presence of disease causing bacteria result in several water borne diseases. Typhoid fever, cholera, viral fever, bacterial fever etc. 2. Industrial waste lead to damage of property through corrosive attack. 3. Pollution of natural water due to organic waste, under the influenec of bacterial action, reduce the dissolved oxygen content in water. 4. Presence of agricultural waste such as pesticides, weedicides, herbicides as well detergents and disinfectants and other toxic substances kill animals and micro organisms. 5. Polluted water affects soil fertility by killing soil microorganisms. 6. Presence of heavy metals, like Hg, Cr, Pb, Cu, Zn etc. are toxic to animals and plants and micro organisms. 7. Suspended solid, coloring matter, floated oils and greases make water unsuitable for use.
  • 35. Control of Water Pollution 1.Control over unhygienic practices. Educate peoples, Dispose waste water properly, control usage of insecticides. 2. Industrial Waste Dispose waste safely. 3. Heavy metal removal Dialysis, ion exchange, reverse osmosis, chemical precipitation, adsorption. 4. Sewage treatment Purify properly.
  • 36. Sewage Water Treatment It aims the transfer of harmful compounds in the sewage to harmless compounds, before its ultimate disposal either on land or dilution in water. Three stages of this process are, 1. Primary or mechanical treatment 2. Secondary or biological treatment 3. Tertiary or advanced biological, physical and chemical treatment.
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  • 44.
  • 45. Soil or Land Pollution
  • 46. It is the addition of certain chemical substances in an indefinite proportion to the soil system as a result of which the fertility of the soil change.
  • 47. Impact of soil pollution 1. Improper disposal of human and animal excreta. 2. Domestic and industrial waste dumped on land. 3. Chemicals like fertilizers, pesticides applied to plants and soil. 4. Dumping of waste from mineral and coal mining and metal smelting on land. 5. Soil erosion due to deforestation, over grazing, unplanned irrigation and defective agriculture practice. 6. Removal of upper fertile layer of soil. 7. Pollution from air and fall-out from smoke stacks of chemical works. 8. Radioactive waste discharged from hospitals, industrial and research centers.
  • 48. Control of Soil Pollution 1.Unwanted waste to be dumped using sanitary land filling 2.Industrial and sewage waste to be properly treated before disposal on land. 3.Natural soil micro-organisms to be used to increase crop fertility rather than using fertilizers and insecticides. 4.Forestation. 5.People should be trained regarding the sanitation habit. 6.Avoid negligent disposal of solid waste. 7.Ban toxic chemicals and pesticides.
  • 49.
  • 50. Noise Pollution It is a kind of pollution caused by unwanted noise at a wrong time and a wrong place naturally or artificially, which will be uncomfortable for health.
  • 51.
  • 52. Impact of Noise Pollution 1. It affects human health, comfort and efficiency, contract blood vessels and increase blood pressure. 2. Cause muscles to contract, leading to nervous break down, tension and even insanity. 3. The most immediate and acute effect is impact of hearing or even loss of hearing. 4. It affect efficiency and behavior, can cause damage to heart, brain etc. 5. It may be a reason for diseases like eosnophelia etc.
  • 53.
  • 54. Prevention of Noise pollution 1. Industrial Noise: Industries should be situated far away from cities or towns. Cover noise producing machineries with insulators. Properly maintain machineries 2. Community noise control: Use cotton plugs or ear muffles.
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  • 57. Thermal pollution may be defined as addition of undesirable heat to water, that makes it harmful to man, animal or aquatic life.
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  • 65. Hazards of Nuclear Radiators 1. Pathological damage: Living organisms are damaged by the highly penetrating radioactive radiations. 2. Genetic Effects: Transmitted to future generations producing abnormalities in the offsprings which may be mild or deadly. 3. Nuclear radiations: It may reduce the effectiveness of enzymes and cause accumulation of certain dangerous elements in certain specific organs or tissue.
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  • 68. The chemistry aims the use of environmentally friendly materials for chemical or biological transformation.
  • 69. Green Chemistry is in Action 1.Using CO2 and a detergent for dry cleaning instead of carcinogenic tetrachloroethane 2.Using H2O2 for bleaching of cloths in laundry instead of toxic chlorine. 3.Using H2O2 for bleaching paper in the place of toxic chlorine.
  • 70. Keep Our Nature Beautifully…..
  • 72. Observe Our Nature More and More It is Very Beautiful
  • 73. Get the Speech Between Sky and Land……
  • 74. Find the Wild Beauty From Your Vicinity……..
  • 75. Get The Magic & Wonder Creation of Nature
  • 76. Find Beauty By Becoming Simple